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Volume 29
Main Index

Issue 1


Utility of the semiempirical INDO/1 method for the calculation of the geometries of second-row transition-metal species
Wayne P. Anderson, Thomas R. Cundari, Russell S. Drago, and Michael C. Zerner
pp 1 - 3; DOI:
10.1021/ic00326a001
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Isolation and characterization of chloro(.eta.2-dihydrogen)dihydridobis(triisopropylphosphine)iridium: a neutral dihydrogen complex of iridium
Mario Mediati, Glen N. Tachibana, and Craig M. Jensen
pp 3 - 5; DOI:
10.1021/ic00326a002
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Potentiometry and NMR studies of 1,5,9-triazacyclododecane-N,N',N''-triacetic acid and its metal ion complexes
S. Cortes, E. Brucher, C. F. G. C. Geraldes, and A. D. Sherry
pp 5 - 9; DOI:
10.1021/ic00326a003
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Electron transfer in organouranium and transuranium systems
David C. Eisenberg, Andrew Streitwieser, and Wing K. Kot
pp 10 - 14; DOI:
10.1021/ic00326a004
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Conversion of tetrathioxomolybdate(2-) to bis(disulfido)di-.mu.-thioxodithioxodimolybdate(2-) by organic disulfides: the mechanism of an induced redox reaction
C. L. Coyle, M. A. Harmer, G. N. George, M. Daage, and E. I. Stiefel
pp 14 - 19; DOI:
10.1021/ic00326a005
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Linkage isomerization of (formamide-N)- and (acetamide-N)pentaamminecobalt(III) ions in water, dimethyl sulfoxide, and sulfolane
Robert L. Angel, David P. Fairlie, and W. Gregory Jackson
pp 20 - 28; DOI:
10.1021/ic00326a006
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Solvolysis of platinum complexes with substituted ethylenediamines in dimethyl sulfoxide
Francesco P. Fanizzi, Francesco P. Intini, Luciana Maresca, Giovanni Natile, and Gloria Uccello-Barretta
pp 29 - 33; DOI:
10.1021/ic00326a007
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Examination of the reactivity of bis(trifluoromethyl)tellurium: oxidative trifluoromethylations and ligand exchanges with Group 5A and 6A (15 and 16) elements and their halides
E. A. Ganja and J. A. Morrison
pp 33 - 38; DOI:
10.1021/ic00326a008
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Synthesis and characterization of the thermally stable copolymer of tetrakis(salicylaldehydato-O,O')zirconium(IV) and 3,3'-diaminobenzidine
Ronald D. Archer and Bing Wang
pp 39 - 43; DOI:
10.1021/ic00326a009
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Variable-temperature proton NMR spectra and T1 measurements on the dinuclear octahydride complexes octahydridotetrakis(phosphine)dirhenium (phosphine = PPh3, PEt2Ph, PMe2Ph, PMe3) and the monohydride complexes bis(cyclopentadienyl)hydridorhenium and bis[bis(diphenylphosphino)methane]dicarbonyltrichlorohydridodirhenium
F. Albert Cotton, Rudy L. Luck, Dawn R. Root, and Richard A. Walton
pp 43 - 47; DOI:
10.1021/ic00326a010
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Bonding in clusters. 11. Gas-phase photoelectron spectra of the 12-apex closo systems 1,12-B12H10(CO)2, 1,2- and 1,7-C2B10H12, and related main Group V and VI heteroboranes and -carboranes. The electronic structure of B12H122-
Paul Brint, Benchang Sangchakr, Marguerite McGrath, Trevor R. Spalding, and Roger J. Suffolk
pp 47 - 52; DOI:
10.1021/ic00326a011
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Asymmetric distortion of bis(.mu.-oxo)bis(oxotungstate(V)) complexes. Crystal structure of bis(.mu.-oxo)(.mu.-N,N'-(R)-propylenediaminetetraacetato)bis(oxotungstate(V))
Shinji Ikari, Yoichi Sasaki, and Tasuku Ito
pp 53 - 56; DOI:
10.1021/ic00326a012
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trans-Dihalogenotitanium(IV) porphyrins, cis-disubstituted analogs, and titanium(III) derivatives. Characterization and structural investigations combining x-ray crystallography and difference EXAFS spectroscopy
Jean Claude Marchon, Jean Marc Latour, Andre Grand, Michel Belakhovsky, Michel Loos, and Jose Goulon
pp 57 - 67; DOI:
10.1021/ic00326a013
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Syntheses and characterization of three tris complexes of the ligand 5,6-dihydro-1,4-dithiin-2,3-dithiolate. Crystal structure of [(C6H5)4As]2[Ti(DDDT)3]
Jane Hanna Welch, Robert D. Bereman, and Phirtu Singh
pp 68 - 73; DOI:
10.1021/ic00326a014
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Synthesis and crystal and molecular structures of potassium bis(.mu.-hydroxo)bis[dinitritoplatinate(II)] sesquihydrate and potassium cyclo-tris(.mu.3-oxo-1:2:4;1:3:4;2:3:4)tris[dinitritoplatinate(II)]trinitritoplatinate(IV) trihydrate
D. Min, R. D. Larsen, K. Emerson, and E. H. Abbott
pp 73 - 76; DOI:
10.1021/ic00326a015
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Detection of covalency in cyclopentadienyl complexes of the alkaline-earth and f elements: statistical evaluation of structural data
S. Craig Sockwell and Timothy P. Hanusa
pp 76 - 80; DOI:
10.1021/ic00326a016
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Electron delocalization in mixed-valence biferrocenium salts: nuclear magnetic resonance contact shift studies
Teng Yuan Dong, Ming Yhu Hwang, Tsui Ling Hsu, Chi Chang Schei, and Show Kei Yeh
pp 80 - 84; DOI:
10.1021/ic00326a017
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Magneto-structural correlations and ESR spectra of dinuclear copper(II) complexes of thiophenophane ligands containing thioether donor atoms
C. Robert Lucas, Shuang Liu, and Laurence K. Thompson
pp 85 - 88; DOI:
10.1021/ic00326a018
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Synthesis, spectroscopy, and structural characterization of neutral seven-coordinate technetium xanthate complexes. X-ray structure of [Tc(PPh3)(S2COC4H9)3], a capped octahedral technetium(III) complex
Terrence Nicholson, John Thornback, Lynne O'Connell, Gillian Morgan, Alan Davison, and Alun G. Jones
pp 89 - 92; DOI:
10.1021/ic00326a019
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Reactivity of coordinated phosphate esters: pentaamminecobalt(III) complexes
Philip Hendry and Alan M. Sargeson
pp 92 - 97; DOI:
10.1021/ic00326a020
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Intramolecular attack of amido ion on phosphate esters coordinated to the pentaammineiridium(III) moiety
Philip Hendry and Alan M. Sargeson
pp 97 - 104; DOI:
10.1021/ic00326a021
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Coordination of aquated cis-platinum(II) diamines to purine nucleosides. Kinetics of complex formation
Jorma Arpalahti and Bernhard Lippert
pp 104 - 110; DOI:
10.1021/ic00326a022
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Copper(I) hemocyanin models: variable coordination number and distorted geometries in benzimidazole chelates
Marianne G. Patch, Hok Kin Choi, David R. Chapman, Robert Bau, Vickie McKee, and Christopher A. Reed
pp 110 - 119; DOI:
10.1021/ic00326a023
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Equilibrium constants for the binding of aluminum to human serum transferrin
Wesley R. Harris and Jan Sheldon
pp 119 - 124; DOI:
10.1021/ic00326a024
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EXAFS investigation on the iron(III) binding sites of hen phosvitin
S. Mangani, P. Orioli, A. Scozzafava, L. Messori, and E. A. Stern
pp 124 - 127; DOI:
10.1021/ic00326a025
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Synthesis and reactivity of a heterometallic carbon dioxide complex
Eric G. Lundquist, John C. Huffman, Kirsten Folting, Brian E. Mann, and Kenneth G. Caulton
pp 128 - 134; DOI:
10.1021/ic00326a026
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(Phthalocyaninato)osmium(II) and bisaxially coordinated (phthalocyaninato)osmium(II) compounds
Michael Hanack and Petra Vermehren
pp 134 - 136; DOI:
10.1021/ic00326a027
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Mixed-ligand complexes of tetravalent metal ions with amine-N-polycarboxylates and fluoride
Akio Yuchi, Tokihito Ban, Hiroko Wada, and Genkichi Nakagawa
pp 136 - 138; DOI:
10.1021/ic00326a028
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Pressure and temperature effects on the coordination equilibrium of a cobalt(III) [Co(N)4Cl] system
Jiro Matsuda and Kazuo Kojima
pp 138 - 140; DOI:
10.1021/ic00326a029
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Amination of coordinated nitriles: synthesis of metal complexes of amidines and guanidines
David P. Fairlie and W. Gregory Jackson
pp 140 - 143; DOI:
10.1021/ic00326a030
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Synthesis, crystal and molecular structure, and magnetic properties of bis[tris(.mu.-3,5-diamino-1,2,4-triazole-N1,N2)tris(thiocyanato-N)nickel(II)]nickel(II) hexahydrate
L. Antolini, A. C. Fabretti, D. Gatteschi, A. Giusti, and R. Sessoli
pp 143 - 145; DOI:
10.1021/ic00326a031
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Kinetics and mechanism of the reactions of a perchloratorhodium(I) complex with nitriles
Chong Shik Chin, Sung Nak Choi, and Kye Duck Kim
pp 145 - 146; DOI:
10.1021/ic00326a032
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Complexation of lithium and sodium ions with o-phenylenediaminetetraacetate in aqueous solutions
Noriyuki Nakasuka, Yoshihiro Natsume, and Motoharu Tanaka
pp 147 - 149; DOI:
10.1021/ic00326a033
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A new type of macrocycle incorporating closo- and nido-carborane cages: molecular structures of 1,2-(1,10-dithia-4,7-dioxadecane-1,10-diyl)-1,2-dicarba-closo-dodecaborane and sodium 7,8-(1,13-dithia-4,7,10-trioxatridecane-1,13-diyl)-7,8-dicarbanido-undecaborate(12)
F. Teixidor, C. Vinas, J. Rius, C. Miravitlles, and J. Casabo
pp 149 - 152; DOI:
10.1021/ic00326a034
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Issue 2


Theoretical refinement of the pentaborane (B5H11) structure. Application of IGLO chemical shift calculations
Paul v. R. Schleyer, Michael Buehl, Ulrich Fleischer, and Wolfram Koch
pp 153 - 155; DOI:
10.1021/ic00327a001
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Thermal control of photoreactivity: room-temperature photosubstitution vs. 150 K electron transfer in bis(3-bromopyridine)bis(4,4'-dimethyl-2,2'-bipyridine)ruthenium(2+) hexafluorophosphate
David W. Wright and Russell H. Schmehl
pp 155 - 157; DOI:
10.1021/ic00327a002
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Synthesis and structural characterization of (octaoxobis(phosphato)molybdate(2-)), [(MoO)4O4(PO4)2]2-: a new, layered oxide produced by hydrothermal synthesis
Edward W. Corcoran
pp 157 - 158; DOI:
10.1021/ic00327a003
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Molecular structure of nido-7,9-(dimethyl)-7,9-undecahydrodicarbadodecaborate(1-): the kinetic product formed by protonation of [nido-(CH3)2C2B10H10]2-
Thomas D. Getman, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 158 - 160; DOI:
10.1021/ic00327a004
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Structure and water-oxidizing capabilities of dimeric ruthenium EDTA complex ions
Jinzhong Zhou, Wu Xi, and James K. Hurst
pp 160 - 167; DOI:
10.1021/ic00327a005
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Multimetallic ruthenium(II) complexes based on biimidazole and bibenzimidazole: effect of dianionic bridging ligands on redox and spectral properties
D. Paul Rillema, Ram Sahai, Philomina Matthews, A. Kirk Edwards, Randy J. Shaver, and Larry Morgan
pp 167 - 175; DOI:
10.1021/ic00327a006
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Transition-metal complexes with sulfur ligands. 45. Model reactions for oxidoreductases with metal-sulfur centers: proton-induced triphenylphosphine/hydrochloric acid exchange in [Ru(PPh3)2(L)] and properties of the resulting HCl complexes [Ru(ClH)(PPh3)(L)] (L = 1,2-bis((2-mercaptophenyl)thio)ethanato(2-); 1,2-bis((3,5-di-tert-butyl-2-mercaptophenyl)thio)ethanato(2-))
Dieter Sellmann, Isabella Barth, and Matthias Moll
pp 176 - 181; DOI:
10.1021/ic00327a007
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Instability of the nitrite/iron(III) porphyrinate system
Michael G. Finnegan, A. G. Lappin, and W. Robert Scheidt
pp 181 - 185; DOI:
10.1021/ic00327a008
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Use of protected binding sites for nitrite binding in iron(III) porphyrinates. Crystal structure of the bis(nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)iron(III) anion
Habib Nasri, John A. Goodwin, and W. Robert Scheidt
pp 185 - 191; DOI:
10.1021/ic00327a009
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Binucleating, macrocyclic [14]N4 ligands and their complexes. Synthesis of the free ligand 2,3-dioxo-5,6:13,14-dibenzo-9,10-(4',5'-dimethylbenzo)-1,4,8,11-tetraazacyclotetradeca-7,11-diene (L) and of the 7,12-Me2-L metal complexes and derivatives. Crystal structures and properties of the [M'][M(7,12-Me2-L)] complexes (M = Ni(II); M = Co(II); M' = ZnCl2, M = Ni(II); M' = [Na(5-crown-15)]+, M = Ni(II); M' = [(C2H5)4N]+, M = Ni(II))
D. Christodoulou, M. G. Kanatzidis, and D. Coucouvanis
pp 191 - 201; DOI:
10.1021/ic00327a010
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Interaction of phosphate and pyrophosphate with cobalt(II) carboxypeptidase
Ivano Bertini, Antonio Donaire, Luigi Messori, and Jose Moratal
pp 202 - 205; DOI:
10.1021/ic00327a011
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Synthesis and characterization of copper(II)-acetazolamide (5-acetamido-1,3,4-thiadiazole-2-sulfonamide) complexes. Crystal structure of dimeric [Cu(Acm)(NH3)2(OH2)]2.cntdot.2H2O
S. Ferrer, J. Borras, C. Miratvilles, and A. Fuertes
pp 206 - 210; DOI:
10.1021/ic00327a012
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Mono- and dinuclear palladium(II) complexes of uracil and thymine model nucleobases and the x-ray structure of [(bpy)Pd(1-MeT)2Pd(bpy)](NO3)2.cntdot.5.5H2O (head-head)
Wolfgang Micklitz, William S. Sheldrick, and Bernhard Lippert
pp 211 - 216; DOI:
10.1021/ic00327a013
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Reversibility of binding of cisplatin-methionine in proteins by diethyldithiocarbamate or thiourea: a study with model adducts
Edwin L. M. Lempers and Jan Reedijk
pp 217 - 222; DOI:
10.1021/ic00327a014
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Structural and charge transport properties of bis[(5,10,15,20-tetramethylporphyrinato)nickel(II)] perrhenate, [Ni(tmp)]2[ReO4]
Timothy P. Newcomb, Martin R. Godfrey, Brian M. Hoffman, and James A. Ibers
pp 223 - 228; DOI:
10.1021/ic00327a015
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Proton, carbon-13, and platinum-195 nuclear magnetic resonance spectroscopy of hydroxypyridinate-bridged dinuclear platinum(III) complexes. Equilibria and mechanism of bridging ligand rearrangement
E. S. Peterson, D. P. Bancroft, D. Min, F. A. Cotton, and E. H. Abbott
pp 229 - 232; DOI:
10.1021/ic00327a016
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Base-induced cleavage of oxo-bridged chromium(III) dimers. Kinetic and chromatographic studies of diacido-.mu.-oxobis[tris(2-pyridylmethyl)amine]chromium(2+) (acido = isolthiocyanato, isocyanato, cyano) hydrolysis reactions in alkaline media
Boyd G. Gafford and Robert A. Holwerda
pp 233 - 238; DOI:
10.1021/ic00327a017
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Synthesis and electrochemistry of 2,2'-bipyridyl complexes of dioxorhenium(V)
M. S. Ram, Christopher S. Johnson, Robert L. Blackbourn, and Joseph T. Hupp
pp 238 - 244; DOI:
10.1021/ic00327a018
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Kinetics of electron-transfer reactions involving the hexacyanoruthenate(4-/3-) couple in aqueous media
J. Mark A. Hoddenbagh and Donal H. Macartney
pp 245 - 251; DOI:
10.1021/ic00327a019
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Kinetics of spin-state interconversion in iron(II) complexes in solution as a function of pressure: activation volumes for the 1A1 .dblharw. 5T2 spin change
John J. McGarvey, Ian Lawthers, Karel Heremans, and Hans Toftlund
pp 252 - 256; DOI:
10.1021/ic00327a020
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Electronic structure study of the formal oxidation states of thallium, lead, and bismuth in the ASr2Can-1CunO2n+3 superconductors (A = Tl0.5Pb0.5, Tl0.5Bi0.5)
D. B. Kang, D. Jung, and M. H. Whangbo
pp 257 - 259; DOI:
10.1021/ic00327a021
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Uranium(IV) hydrolysis constants and solubility product of UO2.cntdot.xH2O(am)
Dhanpat Rai, A. R. Felmy, and J. L. Ryan
pp 260 - 264; DOI:
10.1021/ic00327a022
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Open-chain polyamine ligands with more rigid double connecting bridges. Study of their metal ion selectivities by molecular mechanics calculation, crystallography, and thermodynamics
Robert D. Hancock, M. Patrick Ngwenya, Ann Evers, Peter W. Wade, Jan C. A. Boeyens, and Susan M. Dobson
pp 264 - 270; DOI:
10.1021/ic00327a023
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The first nitrogen-only-bonded metal derivatives of cyclenphosphorane. Formation of cyclenPH.cntdot.MCl2 and cyclenPH.cntdot.HMCl3 (M = zinc, cadmium)
Dilip V. Khasnis, Michael Lattman, and Upali Siriwardane
pp 271 - 274; DOI:
10.1021/ic00327a024
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Hexakis(triethylphosphine)hexathioxohexairon(+): extension of stabilization of the basket core topology to the [Fe6S6]+ oxidation level
Barry S. Snyder and R. H. Holm
pp 274 - 279; DOI:
10.1021/ic00327a025
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Coupling of thionitrosyls and nitrosyls on rhenium fragments: a molecular orbital analysis
Meinolf Kersting and Roald Hoffmann
pp 279 - 284; DOI:
10.1021/ic00327a026
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Exchange and other reactions associated with zinc(II) dithiocarbamate oxidation and reduction processes observed at mercury and platinum electrodes in dichloromethane
Alan M. Bond and A. F. Hollenkamp
pp 284 - 289; DOI:
10.1021/ic00327a027
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Boron-nitrogen compounds. 123. Preparation and reactions of bis(aminoboryl) oxides
M. Komorowska, K. Niedenzu, and W. Weber
pp 289 - 294; DOI:
10.1021/ic00327a028
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Synthesis and reactivity studies of the small carborane closo-2,3-Et2C2B5H5
Jeffrey S. Beck and Larry G. Sneddon
pp 295 - 302; DOI:
10.1021/ic00327a029
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Synthesis and characterization of amine-alkylcyanoboranes
Wyatt J. Mills, Christopher H. Sutton, Eduardo Libby, and Lee J. Todd
pp 302 - 308; DOI:
10.1021/ic00327a030
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Synthesis of acetylhydrazines through chloramination reactions of amides and urethanes
Awni A. Khatib and Harry H. Sisler
pp 309 - 312; DOI:
10.1021/ic00327a031
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Phosphine complexes of trivalent early transition metals. X-ray crystal structure of the d1-d1 (1,2-bis(diisopropylphosphino)ethane)trichlorotitanium dimer and synthesis of the alkyl (1,2-bis(diisopropylphosphino)ethane)dichloro(methyl)(THF)chromium
Ann R. Hermes and Gregory S. Girolami
pp 313 - 317; DOI:
10.1021/ic00327a032
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Molecular hydrogen complexes. Preparation and reactivity of new ruthenium(II) and osmium(II) derivatives and a comparison along the iron triad
Paola Amendola, Stefano Antoniutti, Gabriele Albertin, and Emilio Bordignon
pp 318 - 324; DOI:
10.1021/ic00327a033
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Electrophilic addition reactions of silver(1+) with octakis(triphenylphosphinegold)platinum(2+) and carbonyloctakis(triphenylphosphinegold)platinum(2+). Crystal structures of [Pt(AgNO3)(AuPPh3)8](NO3)2 and [Pt(CO)(AgNO3)(AuPPh3)8](NO3)2
R. P. F. Kanters, P. P. J. Schlebos, J. J. Bour, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 324 - 328; DOI:
10.1021/ic00327a034
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Substituent effects in cluster species. 6. Photoelectron spectra of 5- and 5,6-substituted 2,4-dicarba-closo-heptaborane(7)
G. A. Beltram, C. Jasperse, M. A. Cavanaugh, and T. P. Fehlner
pp 329 - 335; DOI:
10.1021/ic00327a035
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Correlation of experimentally obtained isomer stability data with MNDO and ab initio MO calculations for closo-2,4-dicarbaheptaborane derivative isomer sets
Thomas Onak, Eileen O'Gorman, Tereso Banuelos, Catherine Alfonso, and Marian Yu
pp 335 - 340; DOI:
10.1021/ic00327a036
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Radiolytic study of the reactions of hydroxyl radical with cobalt(III), iron(II), and ruthenium(II) complexes containing 2,2'-bipyridyl and cyano ligands
A. C. Maliyackel, W. L. Waltz, J. Lilie, and R. J. Woods
pp 340 - 348; DOI:
10.1021/ic00327a037
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Preparation and crystal structure of (NEt4)[Fe2(CO)8(.mu.-AuPPh3)]
Oriol Rossell, Miquel Seco, and Peter G. Jones
pp 348 - 350; DOI:
10.1021/ic00327a038
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Model systems for initial stages in oxidative-addition reactions. Theoretical investigation of .eta.1 and .eta.2 coordination of difluorine and dihydrogen to tetrachloroplatinate(2-) and chromium pentacarbonyl
F. M. Bickelhaupt, E. J. Baerends, and W. Ravenek
pp 350 - 354; DOI:
10.1021/ic00327a039
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Photoreduction of methylviologen catalyzed by phthalocyanine complexes of yttrium(III) and lanthanoid(III) metals
Kuninobu Kasuga, Seiji Takahashi, Keiichi Tsukahara, and Takeshi Ohno
pp 354 - 356; DOI:
10.1021/ic00327a040
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Effect of steric crowding on the rates of reactions of a nickel(I) tetraaza macrocycle with organic halides and hydroperoxides [Erratum to document cited in CA111(18):161380z]
Novelette Sadler, Susannah L. Scott, Andreja Baker, James H. Espenson, and M. S. Ram
pp 356 - 356; DOI:
10.1021/ic00327a041
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Investigation of lithium-water interactions in acetonitrile solutions using proton nuclear magnetic resonance, Raman, and infrared spectroscopies and extended Hueckel molecular orbital calculations [Erratum to document cited in CA111(6):46020v]
R. Gerald Keil, David W. Johnson, Mark A. Fryling, and James F. O'Brien
pp 356 - 356; DOI:
10.1021/ic00327a042
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Issue 3


Formation and characterization of a mononuclear (acylperoxo)copper(II) complex
Nobumasa Kitajima, Kiyoshi Fujisawa, and Yoshihiko Moro-oka
pp 357 - 358; DOI:
10.1021/ic00328a001
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Soluble and volatile alkoxides of bismuth. The first structurally characterized bismuth trialkoxide: [Bi(.mu.-.eta.1-OCH2CH2OMe)2(.eta.1-OCH2OMe)].infin.
Michael A. Matchett, Michael Y. Chiang, and William E. Buhro
pp 358 - 360; DOI:
10.1021/ic00328a002
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Molecular identities in first-principles self-consistent-field band electronic structures of the organic superconducting salts .beta.-(BEDT-TTF)2X (X- = triodide, I3-, gold diiodide, AuI2-, iododibromide, IBr2-)
Robert V. Kasowski and Myung Hwan Whangbo
pp 360 - 362; DOI:
10.1021/ic00328a003
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Syntheses, electrochemistry, and spectroscopic and magnetic properties of new mononuclear and binuclear complexes of vanadium(III), -(IV, and -(V) containing the tridentate macrocycle 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of [L2V2(acac)2(.mu.-O)]I2.2H2O, [L2V2O4(.mu.-O)].14H2O, and [L2V2O2(OH)2(.mu.-O)](ClO4)2
Petra Knopp, Karl Wieghardt, Bernhard Nuber, Johannes Weiss, and William S. Sheldrick
pp 363 - 371; DOI:
10.1021/ic00328a004
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Orthophosphate complexes of cobalt(III). trans-[Co(en)2(OH2)(OPO3H)]ClO4.cntdot.1/2H2O and its properties in aqueous solution
Nicola E. Brasch, David A. Buckingham, Jim Simpson, and Ian Stewart
pp 371 - 377; DOI:
10.1021/ic00328a005
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Redox-responsive crown ethers containing a conjugated link between the ferrocene moiety and a benzo crown ether
Paul D. Beer, Christopher Blackburn, Jerome F. McAleer, and Harrison Sikanyika
pp 378 - 381; DOI:
10.1021/ic00328a006
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Enthalpies of ligand exchange for the complexes [(NH3)5Co-L]3+ (L = water, dimethyl sulfoxide, N,N-dimethylformamide, and pyridine)
J. L. Uzice and R. Lopez de la Vega
pp 382 - 384; DOI:
10.1021/ic00328a007
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Pressure dependence of the rate of electron transfer between tris(ethylenediamine)cobalt(II) and -(III) in water
William H. Jolley, Donald R. Stranks, and Thomas W. Swaddle
pp 385 - 389; DOI:
10.1021/ic00328a008
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Electrochemical polymerization of 4-methyl-4'-vinyl-2,2'-bipyridine-containing metal complexes: polymer structure and mechanism of formation
C. Michael Elliott, Christopher J. Baldy, Lydia M. Nuwaysir, and Charles L. Wilkins
pp 389 - 392; DOI:
10.1021/ic00328a009
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Inorganic exciplexes revealed by temperature-dependent quenching studies
Elizabeth M. Stacy and David R. McMillin
pp 393 - 396; DOI:
10.1021/ic00328a010
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Chemical properties and antitumor activity of complexes of platinum containing substituted sulfoxides [PtCl(R'R''SO)(diamine)]NO3. Chirality and leaving-group ability of sulfoxide affecting biological activity
Nicholas Farrell, Donna M. Kiley, Wendy Schmidt, and Miles P. Hacker
pp 397 - 403; DOI:
10.1021/ic00328a011
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Biphasic kinetics of aurothionein formation from gold sodium thiomalate: a novel metallochromic technique to probe zinc(2+) and cadmium(2+) displacement from metallothionein
C. Frank Shaw, James E. Laib, M. Meral Savas, and David H. Petering
pp 403 - 408; DOI:
10.1021/ic00328a012
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Aluminum citrate: isolation and structural characterization of a stable trinuclear complex
Timothy L. Feng, Patrick L. Gurian, Matthew D. Healy, and Andrew R. Barron
pp 408 - 411; DOI:
10.1021/ic00328a013
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Synthesis and characterization of tetrasulfidomolybdenum(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate and the x-ray crystal structure of {HB(3,5-Me2C3N2H)3}MoCl(S4).cntdot.0.5Et2O
Charles G. Young, Ian P. McInerney, Michael A. Bruck, and John H. Enemark
pp 412 - 416; DOI:
10.1021/ic00328a014
PDF
Poly(pyrazolyl) borate complexes of terbium, samarium, and erbium. X-ray crystal structure of {[.eta.3-HB(pz)3]2Sm(.mu.-O2CPh)}2 (pz = pyrazolyl ring)
Daniel L. Reger, Steven J. Knox, Jeffrey A. Lindeman, and Lukasz Lebioda
pp 416 - 419; DOI:
10.1021/ic00328a015
PDF
Synthesis of yttrium and lanthanide silyloxy complexes from anhydrous nitrate and oxo alkoxide precursors and the x-ray crystal structure of [Ce(OSiPh3)3(THF)3](THF)
Peter S. Gradeff, Kenan Yunlu, Timothy J. Deming, Jeffrey M. Olofson, Robert J. Doedens, and William J. Evans
pp 420 - 424; DOI:
10.1021/ic00328a016
PDF
Phosphole complexes of gold(I) halides: comparison of solution and solid-state structures by a combination of solution and CP/MAS phosphorus-31 NMR spectroscopy and x-ray crystallography
Saeed Attar, William H. Bearden, Nathaniel W. Alcock, Elmer C. Alyea, and John H. Nelson
pp 425 - 433; DOI:
10.1021/ic00328a017
PDF
An oxo-bridged binuclear vanadium(III) 2,2'-bipyridine complex and its vanadium(IV) and vanadium(V) oxidation products
Stephen G. Brand, Norman Edelstein, Clifford J. Hawkins, George Shalimoff, Michael R. Snow, and Edward R. T. Tiekink
pp 434 - 438; DOI:
10.1021/ic00328a018
PDF
Synthesis of molybdenum and tungsten silylimido complexes. Structure of a five-coordinate bis(silylimido) complex
Joseph D. Lichtenhan, Susan C. Critchlow, and Nancy M. Doherty
pp 439 - 442; DOI:
10.1021/ic00328a019
PDF
Synthesis, structure, and characterization of ((2-aminophenyl)imido)dichlorobis(diethyldithiocarbamato)molybdenum(VI)
Martin Minelli, Mark R. Carson, Donald W. Whisenhunt, and John L. Hubbard
pp 442 - 445; DOI:
10.1021/ic00328a020
PDF
Synthesis and characterization of cobalt(III) complexes containing .alpha.-diamine and carbinolamine derived from .alpha.-aminomalonate and ethylenediamine
Takahiko Kojima, Takeshi Usui, Tomoaki Tanase, Morio Yashiro, Sadao Yoshikawa, Reiko Kuroda, Shigenobu Yano, and Masanobu Hidai
pp 446 - 450; DOI:
10.1021/ic00328a021
PDF
Electrophilic attack on a cluster-coordinated nitrosyl ligand: crystal and molecular structure of Ru3(NOCH3)(CO)10 and observation of an O-H to M-H tautomerization
Robert E. Stevens, Robert D. Guettler, and Wayne L. Gladfelter
pp 451 - 456; DOI:
10.1021/ic00328a022
PDF
Reactions of the rhenium dicarbonyl complexes Re2X4(dppm)2(CO)2 (X = Cl, Br) and the mixed carbonyl-isocyanide complexes Re2Cl4(dppm)2(CO)(CNR) (R = tert-Bu, xylyl) with trimethylphosphine and trialkyl phosphite ligands. Structural characterization of the complexes [Re2Cl3(.mu.-dppm)2(CO)2L]PF6 (L = PMe3, P(OEt)3) that contain an unsymmetrical carbonyl bridge
Ju Sheng Qi, Phillip E. Fanwick, and Richard A. Walton
pp 457 - 462; DOI:
10.1021/ic00328a023
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Reactions of [Cp(CO)2Fe:CHAr]+ (Ar = p-C6H4OMe) with O:N-Ar'(Ar' = C6H5, p-C6H4NMe2) and PhN:NPh
Wei Jun Peng, A. S. Gamble, Joseph L. Templeton, and M. Brookhart
pp 463 - 467; DOI:
10.1021/ic00328a024
PDF
Synthesis of salts of the hydrogen dichloride anion in aromatic solvents. 2. Syntheses and crystal structures of [K.cntdot.18-crown-6][Cl-H-Cl], [Mg.cntdot.18-crown-6][Cl-H-Cl]2, [H3O.cntdot.18-crown-6][Cl-H-Cl], and the related [H3O.cntdot.18-crown-6][Br-H-Br]
Jerry L. Atwood, Simon G. Bott, C. Mitchell Means, Anthony W. Coleman, Hongming Zhang, and Michael T. May
pp 467 - 470; DOI:
10.1021/ic00328a025
PDF
Homo- and heterobimetallic .mu.(.eta.1-O:.eta.1-O') formate complexes (M-OCHO-M')+PF6-[M,M' = (.eta.5-C5H5)(CO)(NO)Re, (.eta.5-C5H5)(CO)3W, and (.eta.5-C5H5)(CO)2Fe]: their synthesis, solution lability, and reactivity toward hydride donors
Chung C. Tso and Alan R. Cutler
pp 471 - 475; DOI:
10.1021/ic00328a026
PDF
Synthesis and properties of chiral rhenium ether complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(OR2)]+ X-
Sename K. Agbossou, Jesus M. Fernandez, and John A. Gladysz
pp 476 - 480; DOI:
10.1021/ic00328a027
PDF
Synthesis and spectroscopic characterization of (triethylphosphine)gold(I) complexes AuX(PEt3) (X = Cl, Br, CN, SCN), [AuL(PEt3)+] (L = SMe2, SC(NH2)2, H2O), and (.mu.-S)[Au(PEt3)]2
M. M. El-Etri and William M. Scovell
pp 480 - 484; DOI:
10.1021/ic00328a028
PDF
NMR relaxation and .pi. bonding in group 6 transition-metal hexacarbonyls
S. P. Wang, P. Yuan, and Martin Schwartz
pp 484 - 487; DOI:
10.1021/ic00328a029
PDF
Molecular orbital investigation of ruthenium-oxo-catalyzed epoxidations
Thomas R. Cundari and R. S. Drago
pp 487 - 493; DOI:
10.1021/ic00328a030
PDF
Cation effect on the quenching of the photoexcited state of tetrakis(.mu.-pyrophosphito-P,P')diplatinate(II) by octacyanomolybdate(IV) in aqueous solution
Tadashi Yamaguchi and Yoichi Sasaki
pp 493 - 495; DOI:
10.1021/ic00328a031
PDF
Mononuclear, dinuclear, and trinuclear ruthenium(II) complexes of a tris(bipyridine) bridging ligand: syntheses, absorption spectra, redox potentials, and photophysical properties
Luisa De Cola, Peter Belser, Frank Ebmeyer, Francesco Barigelletti, Fritz Voegtle, Alex Von Zelewsky, and Vincenzo Balzani
pp 495 - 499; DOI:
10.1021/ic00328a032
PDF
Solvatochromism of dinuclear complexes: an alternative explanation
Elaine S. Dodsworth and A. B. P. Lever
pp 499 - 503; DOI:
10.1021/ic00328a033
PDF
Binuclear bis(.mu.-oxo)dimanganese(III,IV) and -(IV,IV) complexes with N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine
Patricia A. Goodson, Joergen Glerup, Derek J. Hodgson, Kirsten Michelsen, and Erik Pedersen
pp 503 - 508; DOI:
10.1021/ic00328a034
PDF
New niobium complexes with alkynes. 1. Mono- and dinuclear complexes
F. Albert Cotton and M. Shang
pp 508 - 514; DOI:
10.1021/ic00328a035
PDF
Multiply bonded dimetal fluoroalkoxides. 1. Pentafluorophenoxides of dimolybdenum and ditungsten
Ronald G. Abbott, F. Albert Cotton, and Larry R. Falvello
pp 514 - 521; DOI:
10.1021/ic00328a036
PDF
Transition-metal derivatives of phosphinophosphazenes: x-ray crystal structures of N3P3Cl4PhPPh2, N3P3Cl4PhPPh2.cntdot.Cr(CO)5, and N3P3Cl4PhPPh2.cntdot.Ru3(CO)11
Harry R. Allcock, Ian Manners, Michael N. Mang, and Masood Parvez
pp 522 - 529; DOI:
10.1021/ic00328a037
PDF
Synthesis, spectroscopic studies, and structure of an unusual dirhenium complex with a bridging hydride ligand
S. J. Chen and K. R. Dunbar
pp 529 - 534; DOI:
10.1021/ic00328a038
PDF
Synthesis and characterization of tetrakis(2,5-diisocyano-2,5-dimethylhexane)dihydridodiiridium(2+) tetraphenylborate.cntdot.toluene
David C. Smith, Richard E. Marsh, William P. Schaefer, Thomas M. Loehr, and Harry B. Gray
pp 534 - 538; DOI:
10.1021/ic00328a039
PDF
Boron-nitrogen compounds. 124. Pyrazole derivatives of 9-borabicyclo[3.3.1]nonane
L. Komorowski, A. Meller, and Kurt Niedenzu
pp 538 - 541; DOI:
10.1021/ic00328a040
PDF
Cadmium-113 shelding tensors of cadmium compounds. 5. Single-crystal studies of the dimer of diaquobis(2-hydroxybenzoato)cadmium(II) and tetrakis(4-picoline)nitrato-O,O')(nitrato-O)cadmium(II)
Michael A. Kennedy and Paul D. Ellis
pp 541 - 549; DOI:
10.1021/ic00328a041
PDF
Cadmium-113 shielding tensors of cadmium compounds. 6. Single-crystal NMR study of the cadmium chloride-crown (CdCl2.cntdot.18-crown-6) complex
Michael A. Kennedy, Paul D. Ellis, and Hans J. Jakobsen
pp 550 - 552; DOI:
10.1021/ic00328a042
PDF
Synthesis and characterization of the unsymmetrical trinuclear oxothiomolybdate anion, Mo3O2S82-
Xinquan Xin, Guoxin Jin, Boyi Wang, and Michael T. Pope
pp 553 - 554; DOI:
10.1021/ic00328a043
PDF
Synthesis and characterization of derivatives of pyridine-borane adducts
M. Mittakanti and Karen W. Morse
pp 554 - 556; DOI:
10.1021/ic00328a044
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Convenient small-scale method for the insertion of iron into porphyrins
Marie Landergren and Lars Baltzer
pp 556 - 557; DOI:
10.1021/ic00328a045
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Electronic energy transfer from zerovalent binuclear tungsten carbonyl complexes to organic triplet states
Mthembeni M. Zulu and Alistair J. Lees
pp 557 - 560; DOI:
10.1021/ic00328a046
PDF
Crystal structure and magnetic properties of a novel hetero tetranuclear zinc-copper-copper-zinc complex
Yan Zang, Zhanfeng Yin, Guoxiong Wang, Cheng Zeng, Anbang Dai, and Zhongyuan Zhou
pp 560 - 563; DOI:
10.1021/ic00328a047
PDF
Reaction of lithium pentacarbonyl(diphenylphosphido)tungstate(1-) with (dichlorobis(cyclooctadiene)dirhodium: unexpected synthesis of the linear trimetallic complex (CO)4W(.mu.-PPh2)2 Rh(.mu.-CO)2Rh(C8H12)
Marine Cazanoue, Francoise Dahan, and Rene Mathieu
pp 563 - 565; DOI:
10.1021/ic00328a048
PDF
Photochemical reactions of the binuclear platinum(II) diphosphite complex Pt2(P2O5H2)44- with disubstituted silanes
Y. Huang and Bruce E. Eichinger
pp 565 - 567; DOI:
10.1021/ic00328a049
PDF
Crystal structure and pyrolysis of decaammine (.eta.2:.eta.2-.mu.-benzene)diosmium(4+): evidence for the formation of a stable .eta.2:.eta.6-.mu.-arene complex
W. Dean Harman, Matthew Gebhard, and Henry Taube
pp 567 - 569; DOI:
10.1021/ic00328a050
PDF
Bis(trimethylphosphine)-diborane(4) as a reagent for borane framework expansion
Christopher P. Jock, Mitsuaki Kameda, and Goji Kodama
pp 570 - 571; DOI:
10.1021/ic00328a051
PDF
Secondary (polyfluoroalkyl)chloroamines: precursors to fluoroazaalkenes
Ghulam Sarwar, Robert L. Kirchmeier, and Jeanne M. Shreeve
pp 571 - 572; DOI:
10.1021/ic00328a052
PDF
Structure of manganese complex Mn(H2dapd)Cl2 (manganese acetylpyridine oxime). Corrigendum
Richard E. Marsh
pp 572 - 573; DOI:
10.1021/ic00328a053
PDF
Trifluoroamine oxide: reactions with phosphorus compounds and selected elements
O. D. Gupta, Robert L. Kirchmeier, and Jeanne M. Shreeve
pp 573 - 574; DOI:
10.1021/ic00328a054
PDF
A newly proposed cycle for the water gas shift reaction homogeneously catalyzed by platinum and tin chloride
Mitsuru Kubota
pp 574 - 576; DOI:
10.1021/ic00328a055
PDF

Issue 4


Iron-catalyzed oxidation of bis(imidazol-2-yl)methane into bis(imidazol-2-yl) ketone
G. Guillot, E. Mulliez, P. Leduc, and J. C. Chottard
pp 577 - 579; DOI:
10.1021/ic00329a001
PDF
X-ray absorption spectroscopic evidence for binding of the competitive inhibitor 2-mercaptoethanol to the nickel sites of Jack bean urease. A new nickel-nickel interaction in the inhibited enzyme
Patrick A. Clark, Dean E. Wilcox, and Robert A. Scott
pp 579 - 581; DOI:
10.1021/ic00329a002
PDF
Comparing the acidity of hydride and .eta.2-dihydrogen complexes of transition metals
Guochen Jia and Robert H. Morris
pp 581 - 582; DOI:
10.1021/ic00329a003
PDF
A new ortho-metalated dichloro-bridged complex of iridium(III) with 2,2'-bipyridine: [{Ir(bpy-C3,N')(bpy-N,N')Cl}2][Cl]2
Fred O. Garces and Richard J. Watts
pp 582 - 584; DOI:
10.1021/ic00329a004
PDF
Soluble niobium polysulfide complexes from the reaction of (tert-BuC5H4)2NbH3, (C5Me5)2NbBH4, and (C5Me5)Nb(CO)4 with sulfur
Henri Brunner, Ulrich Klement, Joachim Wachter, Mitsukimi Tsunoda, Jean Claude Leblanc, and Claude Moise
pp 584 - 585; DOI:
10.1021/ic00329a005
PDF
Structure and photoluminescence of a heterodinuclear d10-d8 complex, bis[.mu.-bis(diphenylphosphino)methane]carbonylchlorogoldiridium(1+) hexafluorophosphate
Alan L. Balch, Vincent J. Catalano, and Marilyn M. Olmstead
pp 585 - 586; DOI:
10.1021/ic00329a006
PDF
Protonation of dihydrido[tris(dimethylphosphinopropyl)phosphine]iron with alcohols to form FeP(CH2CH2CH2PMe2)3H(.eta.2-H2)+
Nick Bampos and Leslie D. Field
pp 587 - 588; DOI:
10.1021/ic00329a007
PDF
Synthesis and characterization of Rh2(O2CCH3)3[{C6H2(OMe)3}2P{C6H2(OMe)2O}](MeOH) with a novel tridentate ligand derived from tris(2,4,6-trimethoxyphenyl)phosphine
S. J. Chen and K. R. Dunbar
pp 588 - 590; DOI:
10.1021/ic00329a008
PDF
Synthesis of dicarbonylbis(tetraselenido)ruthenate(2-). A stable anionic Ru2+ polychalcogenide complex
M. Draganjac, Sandeep Dhingra, Song Ping Huang, and Mercouri G. Kanatzidis
pp 590 - 591; DOI:
10.1021/ic00329a009
PDF
Carbon monoxide ligand substitutional processes involving anionic Group 6 metal carboxylates and their relevance to decarboxylation mechanisms
Donald J. Darensbourg and Holly Pickner Wiegreffe
pp 592 - 597; DOI:
10.1021/ic00329a010
PDF
Octahedral metal carbonyls. 69. Kinetics studies of the formation of (NBD)Mo(CO)4 (NBD = norbornadiene) after flash photolysis of molybdenum hexacarbonyl/NBD solutions
Shulin Zhang and Gerard R. Dobson
pp 598 - 602; DOI:
10.1021/ic00329a011
PDF
Aggregated structures of the cadmium thiolato compounds Cd(SC6H4X-4)2 in DMF solution
Ian G. Dance, Robert G. Garbutt, and Trevor D. Bailey
pp 603 - 608; DOI:
10.1021/ic00329a012
PDF
Two-electron oxidation of cobalt phthalocyanines by thionyl chloride. Implications for lithium/thionyl chloride batteries
P. A. Bernstein and A. B. P. Lever
pp 608 - 616; DOI:
10.1021/ic00329a013
PDF
Lacunar cyclidene complexes of nickel(II) and cobalt(II) containing a misoriented pendant base: synthesis and characterization of a new T-form hemoglobin model
Harrell E. Tweedy, Nathaniel W. Alcock, Naohide Matsumoto, Peter A. Padolik, Neil A. Stephenson, and Daryle H. Busch
pp 616 - 626; DOI:
10.1021/ic00329a014
PDF
Axial ligand orientation in iron(II) porphyrinates. Preparation and characterization of low-spin bis(imidazole)(tetraphenylporphyrinato)iron(II) complexes
Martin K. Safo, W. Robert Scheidt, and Govind P. Gupta
pp 626 - 633; DOI:
10.1021/ic00329a015
PDF
Synthesis and electrochemistry of pterins coordinated to tetraammineruthenium(II)
Angel Abelleira, Roy D. Galang, and Michael J. Clarke
pp 633 - 639; DOI:
10.1021/ic00329a016
PDF
Synthesis and characterization of technetium(III) and technetium(II) complexes with mixed phosphine, chloride, and nitrogen-donor ligands. X-ray crystal structure of (2,2'-bipyridine)trichloro(triphenylphosphine)technetium
Anne I. Breikss, Terrence Nicholson, Alun G. Jones, and Alan Davison
pp 640 - 645; DOI:
10.1021/ic00329a017
PDF
(Malonato)bis[sulfinylbis[methane]-S]platinum(II) compounds: versatile synthons for a new general synthesis of antitumor symmetrical and dissymmetrical (malonato)platinum(II) complexes
Panayota Bitha, George O. Morton, Theresa S. Dunne, Eugenia F. Delos Santos, Yang I Lin, Steven R. Boone, R. Curtis Haltiwanger, and Cortlandt G. Pierpont
pp 645 - 652; DOI:
10.1021/ic00329a018
PDF
Efficient catalytic systems for electron transfer from an NADH model compound to dioxygen
Shunichi Fukuzumi, Seiji Mochizuki, and Toshio Tanaka
pp 653 - 659; DOI:
10.1021/ic00329a019
PDF
Aqueous shift reagents for high-resolution cation NMR spectroscopy. 4. [o-Bis((3-tripolyphosphato)propyloxy)benzene(-)]dysprosate(5-)
Janio Szklaruk, James F. Marecek, Amy L. Springer, and Charles S. Springer
pp 660 - 667; DOI:
10.1021/ic00329a020
PDF
Solution chemistry of gallium and indium 3-hydroxy-4-pyridinone complexes in vitro and in vivo
David J. Clevette, Donald M. Lyster, William O. Nelson, Terri Rihela, Gordon A. Webb, and Chris Orvig
pp 667 - 672; DOI:
10.1021/ic00329a021
PDF
A novel hexachelating amino-thiol ligand and its complex with gallium(III)
Dennis A. Moore, Phillip E. Fanwick, and Michael J. Welch
pp 672 - 676; DOI:
10.1021/ic00329a022
PDF
Reactions of the polyhydride complex ReH7(PPh3)2 with pyridinecarboxylic acids, 2-hydroxypyridine, 2-hydroxy-6-methylpyridine, and acetylacetone. Monohydrido complexes of rhenium(III) and their oxidation to the corresponding rhenium(IV) derivatives
Phillip E. Fanwick, Malee Leeaphon, and Richard A. Walton
pp 676 - 682; DOI:
10.1021/ic00329a023
PDF
Planar tricoordinate oxygens in a mixed aqua(tetrahydrofuran)iridium complex: x-ray crystal and molecular structure of [IrH2(THF)(H2O)(PPh3)2]SbF6.cntdot.THF
Xiao Liang Luo, Gayle K. Schulte, and Robert H. Crabtree
pp 682 - 686; DOI:
10.1021/ic00329a024
PDF
Hydride abstraction. The reaction of [bis(diphenylphosphino)ethane]carbonylhaloiridium with bis(cyclopentadienyl)trihydridotantalum
Paul P. Deutsch, John A. Maguire, William D. Jones, and Richard Eisenberg
pp 686 - 690; DOI:
10.1021/ic00329a025
PDF
Synthesis, characterization, and reactivity of platinum(II) complexes of a mesocyclic ligand, 5-phenyl-1-thia-5-phosphacyclooctane
Susan D. Toto, Marilyn M. Olmstead, Brian W. Arbuckle, Parimal K. Bharadwaj, and W. Kenneth Musker
pp 691 - 699; DOI:
10.1021/ic00329a026
PDF
Synthesis and properties of seven-coordinate isocyanide complexes of molybdenum(II) and tungsten(II) containing carbonyl and trimethylphosphine ligands. X-ray structure of MoCl2(CNBu-tert)(CO)(PMe3)3
Ernesto Carmona, Leopoldo Contreras, Enrique Gutierrez-Puebla, Angeles Monge, and Luis Sanchez
pp 700 - 706; DOI:
10.1021/ic00329a027
PDF
Molybdenum and tungsten complexes with unusual coordination modes of a dibenzotetraaza[14]annulene ligand. From bidentate to tridentate scorpiand coordination by reaction with acetonitrile and from bidentate to tetradentate coordination via electrochemistry
Jean Marc Giraudon, Dominique Mandon, Jean Sala-Pala, Jacques E. Guerchais, Jean Michel Kerbaol, Yves Le Mest, and Paul L'Haridon
pp 707 - 713; DOI:
10.1021/ic00329a028
PDF
Synthesis and characterization by proton, carbon-13 and fluorine-19 NMR of (CH3CN)n(CO)4-n(NO)W(.mu.-F)BF3 and [(CH3CN)n+1(CO)4-n(NO)W][BF4] (n = 0-2), tungsten mononitrosyl carbonyl cations with labile acetonitrile and [(.mu.-F)BF3]-ligands
William H. Hersh
pp 713 - 722; DOI:
10.1021/ic00329a029
PDF
Activated molybdenum-molybdenum quadruple bonds. Synthesis, structure, and properties of bis(acetato)tetrakis(ethylenediamine)dimolybdenum(2+) bis(acetate).ethylenediamine: a solid-state model for a solvent-shared ion pair
Bryan W. Eichhorn, Michael C. Kerby, Robert C. Haushalter, and K. Peter C. Vollhardt
pp 723 - 728; DOI:
10.1021/ic00329a030
PDF
Synthesis, structure, and properties of hexacarbonyl(.eta.'-ditellurido)telluridodiferrate(2-) containing the unusual .mu.2-.eta.1-Te22- ligand
Bryan W. Eichhorn, Robert C. Haushalter, and Joseph S. Merola
pp 728 - 731; DOI:
10.1021/ic00329a031
PDF
Synthesis and multinuclear NMR studies of [M{o-C6H4(TeMe)2}X2] (M = Pd, Pt; X = Cl, Br, I). The presence of a characteristic ring contribution to tellurium-125 NMR chemical shifts
Tim Kemmitt and William Levason
pp 731 - 735; DOI:
10.1021/ic00329a032
PDF
Redox conduction in electropolymerized films of transition-metal complexes of osmium, ruthenium, iron, and cobalt
Helen C. Hurrell and Hector D. Abruna
pp 736 - 741; DOI:
10.1021/ic00329a033
PDF
Rotation of the cyclopentadienyl ligand in bis(.mu.-carbonyl)bis(carbonylcyclopentadienyliron)(Fe-Fe) in the solid state as determined from solid-state deuterium NMR spectroscopy
Maria I. Altbach, Yukio Hiyama, Richard J. Wittebort, and Leslie G. Butler
pp 741 - 747; DOI:
10.1021/ic00329a034
PDF
Dynamics of molecular hydrogen in the complex trans-[bis[bis(diphenylphosphino)ethane]](.eta.2-dihydrogen)hydridoiron(1+) tetrafluoroborate(1-) in the solid state as revealed by neutron-scattering experiments
Juergen Eckert, Herma Blank, Maria T. Bautista, and Robert H. Morris
pp 747 - 750; DOI:
10.1021/ic00329a035
PDF
Solid-state structures of platinum phosphine, (R3P)2PtX2 complexes as determined by a combination of carbon-13{proton} and phosphorus-31{proton} NMR spectroscopy
Jeffrey A. Rahn, Laima Baltusis, and John H. Nelson
pp 750 - 755; DOI:
10.1021/ic00329a036
PDF
Iron trichloride-phosphine adducts with tetrahedral geometry and their reaction with ethanol. Structure and magnetic properties of [PH(tert-Bu)3]2[Fe2(.mu.-OEt)2Cl6]
J. David Walker and Rinaldo Poli
pp 756 - 761; DOI:
10.1021/ic00329a037
PDF
Crystal structure and magnetic properties of potassium bis(dithiooxalato)nitrosylferrate(2-), a compound with a sulfur-bridged iron dimer
Lingqian Qian, Phirtu Singh, HyeKyeong Ro, and William E. Hatfield
pp 761 - 763; DOI:
10.1021/ic00329a038
PDF
Molecular models of the superconducting chevrel phases: syntheses and structures of [Mo6X8(PEt3)6] and [PPN][Mo6X8(PEt3)6] (X = S, Se; PPN = (Ph3P)2N)
Taro Saito, Naohiro Yamamoto, Toshimi Nagase, Toshio Tsuboi, Kazuyo Kobayashi, Tsuneaki Yamagata, Hideo Imoto, and Kei Unoura
pp 764 - 770; DOI:
10.1021/ic00329a039
PDF
Structural and magnetic properties of a bis(nitroxyl) binuclear copper(II) complex
Marc Drillon, Andre Grand, and Paul Rey
pp 771 - 774; DOI:
10.1021/ic00329a040
PDF
Coordination modes of the squarate ligand: syntheses and crystal structures of six copper(II) squarate complexes
Xavier Solans, Magdalena Aguilo, Alain Gleizes, Juan Faus, Miguel Julve, and Michel Verdaguer
pp 775 - 784; DOI:
10.1021/ic00329a041
PDF
Synthesis and characterization of O-methyl and O-ethyl dithiocarbonate (xanthate) derivatives of dimethyl- and diphenylgermane. Crystal structure of Ph2Ge[S2COMe]2
John E. Drake, Anil B. Sarkar, and Maria L. Y. Wong
pp 785 - 788; DOI:
10.1021/ic00329a042
PDF
Synthesis and structural studies of sodium complexes of sym-dibenzo-14-crown-4 ionizable lariat ethers
John H. Burns and Richard A. Sachleben
pp 788 - 795; DOI:
10.1021/ic00329a043
PDF
Synthesis and single-crystal x-ray structural investigation of 1,1-bis(pentacarbonylmanganio)-3,4-dimethylgermacyclopent-3-ene and bis[1-(tetracarbonylferrio)-3,4-dimethylgermacyclopent-3-ene]: the first evidence for a puckered ground-state conformation in germacyclopent-3-enes
Deqing Lei, Mark J. Hampden-Smith, Eileen N. Duesler, and John C. Huffman
pp 795 - 798; DOI:
10.1021/ic00329a044
PDF
Arsenic-sulfur heterocycle formation via metal coordination. Synthesis and molecular structure of cyclo-(CH3AsS)n (n = 3, 4), [(CO)3Mo][.eta.3-cyclo-(CH3As)6S3], and the triple-decker-sandwich complex [.eta.5-(C5H5)2Mo2(.eta.2,.mu.-As3)(.eta.2,.mu.-AsS)]
Anthony J. DiMaio and Arnold L. Rheingold
pp 798 - 804; DOI:
10.1021/ic00329a045
PDF
Synthesis of icosahedral boranes containing bismuth
John L. Little, Michael A. Whitesell, John G. Kester, Kirsten Folting, and Lee J. Todd
pp 804 - 808; DOI:
10.1021/ic00329a046
PDF
Phosphoranimine phosphines and arsines as heterodifunctional coordinating ligands. Synthesis and characterization of new palladium(II) metallacycles RN=PPh2(CH2)nEPh2PdCl2 (R = SiMe3, GeMe3, H; n = 1, 2; E = P, As) and the crystal and molecular structure of HN = PPh2CH2PPh2PdCl2, the first structural example of a phosphoranimine phosphine complex
K. V. Katti, R. G. Cavell, R. J. Batchelor, and F. W. B. Einstein
pp 808 - 814; DOI:
10.1021/ic00329a047
PDF
Syntheses and properties of bis{bis(trimethylphosphine)tetrahydrodiboron}copper(1+) halide (halide = chloride, iodide) and x-ray crystal structure of the iodide
Mamoru Shimoi, Kinji Katoh, Hiromi Tobita, and Hiroshi Ogino
pp 814 - 817; DOI:
10.1021/ic00329a048
PDF
Reaction of dimethyl sulfide-triborane(7) with dimethyl sulfide. A formation reaction of pentaborane(9)
Minoru Ishii and Goji Kodama
pp 817 - 820; DOI:
10.1021/ic00329a049
PDF
Single-crystal polarized spectra in the near-infrared region: a local-mode analysis of the spectra of barium chloride dihydrate
Paul J. McCarthy and Ian M. Walker
pp 820 - 824; DOI:
10.1021/ic00329a050
PDF
Synthesis, isomer separation, and metal complexation studies of aza- and oxaphosphands, a class of hard/soft dinucleating phosphine macrocycles
Liwen Wei, Andrew Bell, Kwang Hyun Ahn, Mark M. Holl, Steve Warner, Ian D. Williams, and Stephen J. Lippard
pp 825 - 837; DOI:
10.1021/ic00329a051
PDF
Infrared matrix isolation studies of molecular interactions: complexes of trichlorosilane, HSiCl3, with selected bases
Mei Lee H. Jeng and Bruce S. Ault
pp 837 - 842; DOI:
10.1021/ic00329a052
PDF
Magnetic properties of hexaamminecobalt(3+) hexachloroferrate(3-): a quasi-ideal fcc structure with antiferromagnetic ordering
M. Carmen Moron, Fernando Palacio, Rafael Navarro, Josefina Pons, Jaime Casabo, and Richard L. Carlin
pp 842 - 845; DOI:
10.1021/ic00329a053
PDF
Electrochemistry and electrochromism of vanadium hexacyanoferrate
Michael K. Carpenter, Robert S. Conell, and Steven J. Simko
pp 845 - 850; DOI:
10.1021/ic00329a054
PDF
Relationship of the ruby spectrum to the geometry of the chromium(III) environment
Kyu Wang Lee and Patrick E. Hoggard
pp 850 - 854; DOI:
10.1021/ic00329a055
PDF
Ruthenium complexes with 1,4,5,8-tetraazaphenanthrene. Unusual photophysical behavior of the tris-homoleptic compound
A. Masschelein, L. Jacquet, A. Kirsch-De Mesmaeker, and J. Nasielski
pp 855 - 860; DOI:
10.1021/ic00329a056
PDF
Pseudopotential investigations on the molecules, copper silicides and stannides
W. Plass, A. Savin, H. Stoll, H. Preuss, R. Nesper, and H. G. Von Schnering
pp 860 - 868; DOI:
10.1021/ic00329a057
PDF
Ferric iodide as a nonexistent compound
K. B. Yoon and J. K. Kochi
pp 869 - 874; DOI:
10.1021/ic00329a058
PDF
EPR study of manganese(II) in single crystals of the spin-crossover complex tris[2-(aminomethyl)pyridine]iron(2+) dichloride ethanolate, evidence for domains in transition
Peter E. Doan and Bruce R. McGarvey
pp 874 - 876; DOI:
10.1021/ic00329a059
PDF
Synthesis of rhodium-containing heterobimetallic hydride complexes
Charles P. Casey and Gregory T. Whiteker
pp 876 - 879; DOI:
10.1021/ic00329a060
PDF
P10Fe, a phosphorus analog ferrocene?
Jose A. Chamizo, Marina Ruiz-Mazon, Roberto Salcedo, and Ruben A. Toscano
pp 879 - 880; DOI:
10.1021/ic00329a061
PDF
Reactions of 4-acetylpyridine with [(RH)W(CO)5] intermediates (RH = cyclohexane, methylcyclohexane) produced via pulsed laser flash photolysis
Gerard R. Dobson and Michael D. Spradling
pp 880 - 882; DOI:
10.1021/ic00329a062
PDF
Ruthenium-99 NMR spectroscopy of ruthenium(II) polypyridyl complexes
Guillermo Orellana, Andree Kirsch-De Mesmaeker, and Nicholas J. Turro
pp 882 - 885; DOI:
10.1021/ic00329a063
PDF
Adducts of 1-vinylimidazole, 1-benzylimidazole, and 1,2,4-triazole with tin(II) chloride
S. V. Vasnin, J. Cetrullo, R. A. Geanangel, and I. Bernal
pp 885 - 888; DOI:
10.1021/ic00329a064
PDF
Generation and characterization of alkyl- and aryl-bridged dinuclear iron(III) porphyrin complexes
Koo Shin, Byung Soo Yu, and Harold M. Goff
pp 889 - 890; DOI:
10.1021/ic00329a065
PDF

Issue 5


Molybdenum dithiooxamide complexes: is the ligand oxidized or reduced?
Keith R. Barnard, Anthony G. Wedd, and Edward R. T. Tiekink
pp 891 - 892; DOI:
10.1021/ic00330a001
PDF
Interaction of the antitumor drug streptonigrin with palladium(II) ions. Evidence of the formation of a superoxo-palladium(II)-streptonigrin complex
M. M. L. Fiallo and A. Garnier-Suillerot
pp 893 - 897; DOI:
10.1021/ic00330a002
PDF
Mechanism of catalase activity in aqueous solutions of dimanganese(III,IV) ethylenediamine-N,N'-diacetate
James D. Rush and Zofia Maskos
pp 897 - 905; DOI:
10.1021/ic00330a003
PDF
Photochemical carbon dioxide reduction catalyzed by bis(2,2'-bipyridine)dicarbonylruthenium(2+) using triethanolamine and 1-benzyl-1,4-dihydronicotinamide as an electron donor
Hitoshi Ishida, Tohru Terada, Koji Tanaka, and Toshio Tanaka
pp 905 - 911; DOI:
10.1021/ic00330a004
PDF
Vanadium-mediated oxygen atom transfer reactions
Yiping Zhang and Richard H. Holm
pp 911 - 917; DOI:
10.1021/ic00330a005
PDF
Terminal and new bridging coordination of methylguanidine, arginine, and canavanine to platinum(II). The first crystallographic study of bonding between a transition metal and a guanidine ligand
Eva Marie A. Ratilla, Brian K. Scott, Michael S. Moxness, and Nenad M. Kostic
pp 918 - 926; DOI:
10.1021/ic00330a006
PDF
Octanuclear heterometallic clusters with rhombic dodecahedral cores. The synthesis, structural characterization, and properties of the [Fe6S6(p-RPhO)6[M(CO3]2]n- clusters (M = Mo, n = 3, R = Me, OMe, N(Me2); M = W, n = 3, R = Me; M = Mo, n = 4, R = Me, OMe, COMe). Precursors for synthetic analogs for the Fe/Mo/S site in nitrogenase
S. A. Al-Ahmad, A. Salifoglou, M. G. Kanatzidis, W. R. Dunham, and D. Coucouvanis
pp 927 - 938; DOI:
10.1021/ic00330a007
PDF
Synthesis and coordination chemistry of the hexadentate ligands 1,4,7-tris(2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L1) and 1,4,7-tris(3-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L2). Crystal structures of [HL1CuII] and [L2FeIII]acacH
Ulf Auerbach, Uwe Eckert, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 938 - 944; DOI:
10.1021/ic00330a008
PDF
Monomeric and dimeric vanadium(IV) and -(V) complexes of N-(hydroxyalkyl)salicylideneamines: structures, magnetochemistry and reactivity
Carl J. Carrano, Christine M. Nunn, Roger Quan, Joseph A. Bonadies, and Vincent L. Pecoraro
pp 944 - 951; DOI:
10.1021/ic00330a009
PDF
Coordination chemistry of zirconium tetrachloride. Crystal structure of the 1:2 adduct with pinacolone
Bruno Galeffi, Michel Simard, and James D. Wuest
pp 951 - 954; DOI:
10.1021/ic00330a010
PDF
Multidentate Lewis acids. Synthesis, structure, and reactions of complexes of bidentate zirconium trichloride alkoxides
Bruno Galeffi, Michel Simard, and James D. Wuest
pp 955 - 958; DOI:
10.1021/ic00330a011
PDF
New low-dimensional zinc compounds containing zinc-oxygen-phosphorus frameworks: two-layered inorganic phosphites and a polymeric organic phosphinate
Minghuey Shieh, Kevin J. Martin, Philip J. Squattrito, and Abraham Clearfield
pp 958 - 963; DOI:
10.1021/ic00330a012
PDF
Oxalato and squarato ligands in nickel(II) complexes of tetraazacycloalkanes. Solution and solid-state studies. Crystal and molecular structures of (.mu.-oxalato)bis[(1,7-dimethyl-1,4,7,10-tetraazacyclododecane)nickel(II)] perchlorate dihydrate and of bis[diaquo(1,4,7,10-tetraazacyclododecane)nickel(II)] squarate diperchlorate
Andrea Bencini, Antonio Bianchi, Enrique Garcia-Espana, Yves Jeannin, Miguel Julve, Victor Marcelino, and Michele Philoche-Levisalles
pp 963 - 970; DOI:
10.1021/ic00330a013
PDF
Electronic and molecular structure of protonated fluoro isocyano krypton [FKrNCH]+. The question of hypervalent bonding
David A. Dixon and Anthony J. Arduengo
pp 970 - 975; DOI:
10.1021/ic00330a014
PDF
Electronic structure factors of silicon-hydrogen bond activation by transition metals. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiCl3 and (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiHPh2 (Me = CH3, Ph = C6H5)
Dennis L. Lichtenberger and Anjana Rai-Chaudhuri
pp 975 - 981; DOI:
10.1021/ic00330a015
PDF
Studies of mixed-valence linear-chain complexes crystallized at elevated pressures. Crystal structures of bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = bromo, iodo)
Jeffrey B. Weinrach, Scott A. Ekberg, Steven D. Conradson, Basil I. Swanson, and H. Dieter Hochheimer
pp 981 - 985; DOI:
10.1021/ic00330a016
PDF
Nuclear magnetic relaxation in aqueous solutions of the gadolinium-N-(2-hydroxyethyl)ethylenediamine triacetic acid complex
Griselda Hernandez, Harry G. Brittain, Michael F. Tweedle, and Robert G. Bryant
pp 985 - 988; DOI:
10.1021/ic00330a017
PDF
Ruthenium compounds containing pyridyltriazines with low-lying .pi.* orbitals
Ronald Hage, John H. Van Diemen, Grant Ehrlich, Jaap G. Haasnoot, Derk J. Stufkens, Theo L. Snoeck, Johannes G. Vos, and Jan Reedijk
pp 988 - 993; DOI:
10.1021/ic00330a018
PDF
Electrochemistry and spectroelectrochemistry of polynuclear rhenium(III) chloride cluster complexes and their one-electron-reduction products in a basic room-temperature chloroaluminate molten salt
Sandra K. D. Strubinger, I Wen Sun, Walter E. Cleland, and Charles L. Hussey
pp 993 - 999; DOI:
10.1021/ic00330a019
PDF
Electrochemical olefin epoxidation with manganese meso-tetraphenylporphyrin catalyst and hydrogen peroxide generation at polymer-coated electrodes
Hiroshi Nishihara, K. Pressprich, Royce W. Murray, and James P. Collman
pp 1000 - 1006; DOI:
10.1021/ic00330a020
PDF
Electrocatalytic olefin epoxidation using manganese Schiff-base complexes and dioxygen
Colin P. Horwitz, Stephen E. Creager, and Royce W. Murray
pp 1006 - 1011; DOI:
10.1021/ic00330a021
PDF
.eta.2 Coordination of RuII(hedta)- at the C-5-C-6 bonds of cytidine and uridine
Songsheng Zhang, Lori A. Holl, and Rex E. Shepherd
pp 1012 - 1022; DOI:
10.1021/ic00330a022
PDF
Schiff bases of pyridoxal 5'-phosphate and 5'-deoxypyridoxal with phenylglycine derivatives and their metal complexes
Venkatesh M. Shanbhag and Arthur E. Martell
pp 1023 - 1031; DOI:
10.1021/ic00330a023
PDF
ELectrochemical and spectroelectrochemical characterization of intermolecular nitrosyl transfer between iron and cobalt porphyrins
X. H. Mu and K. M. Kadish
pp 1031 - 1036; DOI:
10.1021/ic00330a024
PDF
Synthesis, x-ray structure, and characterization of [bis(diphenylphosphino)ethane]dichlorobis(octaethylporphyrinato)diiridium
Karl M. Kadish, Y. J. Deng, and J. D. Korp
pp 1036 - 1042; DOI:
10.1021/ic00330a025
PDF
Further evidence for quantitation of relationships among structure, NMR spectra and kinetics in B12 models containing planar N-donor ligands. Synthesis and structural characterization of 1,2-dimethylimidazole-alkylcobaloximes with alkyl = CCl2CN, CH2CN, Me, and iso-Pr
Nevenka Bresciani Pahor, Silvano Geremia, Concepcion Lopez, Lucio Randaccio, and Ennio Zangrando
pp 1043 - 1049; DOI:
10.1021/ic00330a026
PDF
Cadmium-113 shielding tensors of the cadmium complex of texaphyrin, a novel expanded porphyrin, and its pyridine and benzimidazole adducts
Michael A. Kennedy, Jonathan L. Sessler, Toshiaki Murai, and Paul D. Ellis
pp 1050 - 1054; DOI:
10.1021/ic00330a027
PDF
Chemical-ionization and electron-ionization mass spectra of dimethylglyoxime and its complexes with nickel(II), palladium(II), and platinum(II)
Steven M. Schildcrout and Lisa M. Besozzi
pp 1054 - 1057; DOI:
10.1021/ic00330a028
PDF
Synthesis, crystal structure and magnetic properties of a pyrazolate-bridged binuclear copper(II) complex
Thompson N. Doman, Donald E. Williams, J. Fred Banks, Robert M. Buchanan, Hsiu Rong Chang, Robert J. Webb, and David N. Hendrickson
pp 1058 - 1062; DOI:
10.1021/ic00330a029
PDF
Synthesis and characterization of a technetium(III) nitrosyl compound: Tc(NO)(Cl)(SC10H13)3
Nadine De Vries, Jessica Cook, Alan Davison, Terrence Nicholson, and Alun G. Jones
pp 1062 - 1064; DOI:
10.1021/ic00330a030
PDF
Formation of unexpected silicon alkoxide isomers in a rectangular planar chelating framework
B. De Ruiter, J. E. Benson, R. A. Jacobson, and John G. Verkade
pp 1065 - 1068; DOI:
10.1021/ic00330a031
PDF
Liquid-phase metal vapor chemistry: rotary reactors and electron-beam evaporation sources
G. A. Ozin, Mark P. Andrews, C. G. Francis, H. X. Huber, and K. Molnar
pp 1068 - 1073; DOI:
10.1021/ic00330a032
PDF
Oxidative substitution of pentacarbonylmanganese(1-) by 3,5-di-tert-butyl-1,2-benzoquinone. Synthesis and characterization of the unsaturated Mn(CO)3(DBCat)- anion
Frantisek Hartl, Antonin Vlcek, Lynn A. DeLearie, and Cortlandt G. Pierpont
pp 1073 - 1078; DOI:
10.1021/ic00330a033
PDF
Complex formation reactions of uranyl(VI) with neutral N-donors in dimethyl sulfoxide. Influence of small amounts of water
Alberto Cassol, Plinio Di Bernardo, Roberto Portanova, Marilena Tolazzi, Giuliana Tomat, and Pierluigi Zanonato
pp 1079 - 1084; DOI:
10.1021/ic00330a034
PDF
Redox interconversions and aqueous solution properties of the cuboidal complexes [Mo4S4(edta)2]m- (m = 4, 3, 2)
Paul W. Dimmock, Joseph McGinnis, Bee Lean Ooi, and A. Geoffrey Sykes
pp 1085 - 1089; DOI:
10.1021/ic00330a035
PDF
Kinetics and mechanism of the reduction of hydroxylamine-O-sulfonic acid by the hexaaquochromium(II) ion
Andreja Bakac, Joan L. Simunic, and James H. Espenson
pp 1090 - 1092; DOI:
10.1021/ic00330a036
PDF
Stability of metal ion unsubstituted and substituted monocarboxylate complexes in aqueous solutions
I. Filipovic, M. Tkalcec, and B. S. Grabaric
pp 1092 - 1097; DOI:
10.1021/ic00330a037
PDF
Synthesis of new carboxylate- and phosphinate-bridged ruthenium(I) dimers
D. Scott Bohle and Heinrich Vahrenkamp
pp 1097 - 1099; DOI:
10.1021/ic00330a038
PDF
Synthesis and structure of the trinuclear palladium cluster [Pd3(PEt3)3(.mu.2-NPh)2(.mu.2-NHPh)]Cl, containing bridging imido and amido ligands
Soon W. Lee and William C. Trogler
pp 1099 - 1102; DOI:
10.1021/ic00330a039
PDF
Preparation and study of diiron(+)-benzyne ion in the gas phase
Yongqing Huang and Ben S. Freiser
pp 1102 - 1104; DOI:
10.1021/ic00330a040
PDF
X-ray study of Ta(CHCMe3)(S-2,4,6-C6H2-iso-Pr3)3(SEt2) suggests why it is inactive for metathesis of ordinary olefins
Kevin C. Wallace, William M. Davis, and Richard R. Schrock
pp 1104 - 1106; DOI:
10.1021/ic00330a041
PDF
Formation of the dihydrogenphosphide-bis[tetraborane(8)] anion. Protic acid behavior of phosphine-tetraborane(8)
Christopher P. Jock and Goji Kodama
pp 1106 - 1108; DOI:
10.1021/ic00330a042
PDF
Magnetic properties of linear chromium(III) phenylphosphonium chalcogenide trimeric clusters: [(C6H5)4P]3[Cr3Te24] and [(C6H5)4P]3[Cr3Se24]
Jian H. Zhang, Walter A. Flomer, Joseph W. Kolis, and Charles J. O'Connor
pp 1108 - 1110; DOI:
10.1021/ic00330a043
PDF
Electron-transfer reactions in mixed solvents. An electrochemical probe of unsymmetrical selective solvation [Erratum to document cited in CA111(18):161383c]
Robert L. Blackbourn and Joseph T. Hupp
pp 1110 - 1110; DOI:
10.1021/ic00330a044
PDF

Issue 6


Coordination chemistry of the metal binding site of isopenicillin N synthase
Li June Ming, Lawrence Que, Aidas Kriauciunas, Charles A. Frolik, and Victor J. Chen
pp 1111 - 1112; DOI:
10.1021/ic00331a001
PDF
Cadmium-113 and carbon-13 NMR of cadmium(II) transferrins
Marco Sola
pp 1113 - 1116; DOI:
10.1021/ic00331a002
PDF
Thermodynamics and structure of isothiocyanato complexes of manganese(II), cobalt(II), and nickel(II) ions in N,N-dimethylformamide
Shinichi Ishiguro and Kazuhiko Ozutsumi
pp 1117 - 1123; DOI:
10.1021/ic00331a003
PDF
One-electron-transfer reactions of molybdenum(V) and manganese(III) porphyrins with solvated electrons and solvent radicals in 2-methyltetrahydrofuran
T. Suzuki, Taira Imamura, T. Sumiyoshi, M. Katayama, and M. Fujimoto
pp 1123 - 1129; DOI:
10.1021/ic00331a004
PDF
Electron self-exchange of the dicyclopentadienylnickel(II,III) couple in dichloromethane
Jacquelin D. Gribble and Scot Wherland
pp 1130 - 1132; DOI:
10.1021/ic00331a005
PDF
Aromatic sulfonation by sulfite and the reduction potential of the sulfite radical: oxidation of sulfite by the tetraammine(phenanthroline)ruthenium(II) cation
Rajeshuni Sarala, M. Ashraful Islam, Steven B. Rabin, and David M. Stanburg
pp 1133 - 1142; DOI:
10.1021/ic00331a006
PDF
Kinetic and thermodynamic study of the interactions of nickel(II) with nicotinamide adenine dinucleotide and nicotinamide adenine dinucleotide phosphate
Joseph P. Bidwell and John E. Stuehr
pp 1143 - 1147; DOI:
10.1021/ic00331a007
PDF
Structure-affinity relationships in the binding of unsubstituted iron phenolate complexes to human serum albumin. Molecular structure of iron(III) N, N'-bis(2-hydroxybenzyl)ethylenediamine-N,N'-diacetate
Scott K. Larsen, Bruce G. Jenkins, Nasim G. Memon, and Randall B. Lauffer
pp 1147 - 1152; DOI:
10.1021/ic00331a008
PDF
Structural changes associated with the spin transition in bis(isothiocyanato)bis(1,10-phenanthroline)iron: a single-crystal x-ray investigation
Bernard Gallois, Jose Antonio Real, Christian Hauw, and Jacqueline Zarembowitch
pp 1152 - 1158; DOI:
10.1021/ic00331a009
PDF
Excited state Raman spectroscopy of tetracarbonyl(.alpha.-diimine)tungsten complexes
Jing Huei Perng and Jeffrey I. Zink
pp 1158 - 1161; DOI:
10.1021/ic00331a010
PDF
Luminescence at high pressures and magnetic fields and the structure of single-crystal platinum(II) binuclear complexes Mx[Pt2(POP)4].cntdot.nH2O (Mx = Ba2, [NH4]4; POP = P2O5H22-)
Ludwig Baer, Helmut Englmeier, Guenter Gliemann, Ulrich Klement, and Klaus Juergen Range
pp 1162 - 1168; DOI:
10.1021/ic00331a011
PDF
Structural analysis of o-phenylenebis(diisopropylphosphine) complexes of nickel(II), palladium(II), and platinum(II)
Shiuh Tzung Liu, Jwu Ting Chen, Shie Ming Peng, Yu Ling Hsiao, and Ming Chu Cheng
pp 1169 - 1172; DOI:
10.1021/ic00331a012
PDF
Exchange interaction in multinuclear transition metal complexes. 14. Exchange interactions in a novel copper(II) linear-chain compound with ladderlike structure: Cu2(1,4-diazacycloheptane)2Cl4
B. Chiari, Olivo Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 1172 - 1176; DOI:
10.1021/ic00331a013
PDF
Liquid crystalline copper(II) complexes of N-salicylideneaniline derivatives. Mesomorphic properties and a crystal structure
Naomi Hoshino, Hikari Murakami, Yoshio Matsunaga, Tamotsu Inabe, and Yusei Maruyama
pp 1177 - 1181; DOI:
10.1021/ic00331a014
PDF
Stepwise synthesis and reactivity of bis(diphenylphosphino)methane-stabilized mixed-metal clusters containing three or four different metals
Pierre Braunstein, Claude De Meric de Bellefon, and Michel Ries
pp 1181 - 1186; DOI:
10.1021/ic00331a015
PDF
Preparation, characterization, and catalytic activity of a new solid acid catalyst system
Edward E. Getty and Russell S. Drago
pp 1186 - 1192; DOI:
10.1021/ic00331a016
PDF
Heteropolymetallic complexes of 1,1'-bis(diphenylphosphino)ferrocene (dppf). 5. Synthesis and characterization of the cationic complexes [M(dppf)2]+ (M = rhodium, iridium). Crystal and molecular structure of [Ir(dppf)2]B(C6H5)4
Umberto Casellato, Benedetto Corain, Rodolfo Graziani, Bruno Longato, and Giuseppe Pilloni
pp 1193 - 1198; DOI:
10.1021/ic00331a017
PDF
Products and kinetics of the direct, specific transmetalation of (.mu.4-O)N4Cu(Ni(H2O))3Cl6 (N = N,N-diethylnicotinamide) by M(NS)n reagents (NS = monoanionic S-methyl isopropylidenehydrazinecarbodithioate) in nitrobenzene: a relationship between precursor stabilities and product formation rates
Saad Al-Shehri, Geoffrey Davies, Mohamed A. El-Sayed, and Ahmed El-Toukhy
pp 1198 - 1205; DOI:
10.1021/ic00331a018
PDF
Rate law variations in the specific monotransmetalation of (.mu.4-O)(N,py)4Cu4-xMxX6 complexes with Zn(NS)2 in nitrobenzene
Saad Al-Shehri, Geoffrey Davies, Mohamed A. El-Sayed, and Ahmed El-Toukhy
pp 1206 - 1210; DOI:
10.1021/ic00331a019
PDF
Thermal isomerization of regiospecifically boron-10-labeled icosahedral carboranes
Gary M. Edvenson and Donald F. Gaines
pp 1210 - 1216; DOI:
10.1021/ic00331a020
PDF
A new route to alkoxysilanes and alkoxysiloxanes of use for the preparation of ceramics by the sol-gel technique
George B. Goodwin and Malcolm E. Kenney
pp 1216 - 1220; DOI:
10.1021/ic00331a021
PDF
Theoretical study on the metal NMR chemical shift. Molybdenum complexes
H. Nakatsuji and M. Sugimoto
pp 1221 - 1225; DOI:
10.1021/ic00331a022
PDF
Kinetics of oxidation of tetracyanonickelate(II) by chlorine monoxide, chlorine, and hypochlorous acid and kinetics of chlorine monoxide formation
Mark W. Beach and Dale W. Margerum
pp 1225 - 1232; DOI:
10.1021/ic00331a023
PDF
Metal-metal bonds involving vanadium atoms. A facile synthesis of a novel divanadium tetrakis(dithioacetate) that contains two .mu.-.eta.2-S2 bridges from bis(benzene)vanadium(0) and dithioacetic acid
Stan A. Duraj, Maria T. Andras, and Piotr A. Kibala
pp 1232 - 1234; DOI:
10.1021/ic00331a024
PDF
Single-crystal x-ray structures of the polyoxotungstate salts K8.3Na1.7[Cu4(H2O)2(PW9O34)2].cntdot.24H2O and Na14Cu[Cu4(H2O)2(P2W15O56)2].cntdot.53H2O
Timothy J. R. Weakley and Richard G. Finke
pp 1235 - 1241; DOI:
10.1021/ic00331a025
PDF
Synthesis and structure studies of sulfido/molybdenum/late-transition-metal clusters with a general formula Cp2Mo2M'2-3S2-4(CO)n
Ping Li and M. David Curtis
pp 1242 - 1248; DOI:
10.1021/ic00331a026
PDF
Redox chemistry of diphenyl diselenide and its chemistry in the presence of protons, hydroxide, water, and hydrogen peroxide
Andrzej Sobkowiak and Donald T. Sawyer
pp 1248 - 1251; DOI:
10.1021/ic00331a027
PDF
Reactions of tetrasulfur tetranitride and trichlorotrithiatriazene with selenium chlorides. The preparations and crystal structures of SeS2N2Cl2, (S5N5)(SeCl5), and the disordered materials (SexS3-xN2Cl)(SbCl6)
Ronald J. Gillespie, James P. Kent, and Jeffery F. Sawyer
pp 1251 - 1259; DOI:
10.1021/ic00331a028
PDF
Synthesis and reactivity of the metal-substituted borane (CO)4CoBH2.cntdot.THF. Preparation of the ambiphilic clusters (CO)9Co3C(CH2)nOH (n = 4,5)
John D. Basil, Allen A. Aradi, Nripendra K. Bhattacharyya, Nigam P. Rath, Charles Eigenbrot, and Thomas P. Fehlner
pp 1260 - 1270; DOI:
10.1021/ic00331a029
PDF
Electrochemical parametrization of metal complex redox potentials, using the ruthenium(III)/ruthenium(II) couple to generate a ligand electrochemical series
A. B. P. Lever
pp 1271 - 1285; DOI:
10.1021/ic00331a030
PDF
Coordinated benzyl radical derivatives: reaction of chromium(II) with complexes of pentaamminecobalt(III) and 4-cyano- and 4-carbamoylbenzyl bromide
P. Sharma and R. B. Jordan
pp 1286 - 1289; DOI:
10.1021/ic00331a031
PDF
Convenient synthesis of tris(tetrabutylammonium) hexacyanoruthenate(III): first access to a pure salt of a hexacyanoruthenate(III) anion and to a coordination polymer thereof
Stefan Eller and R. Dieter Fischer
pp 1289 - 1290; DOI:
10.1021/ic00331a032
PDF
Further studies on dirhenium complexes that contain the bridging ligand 2-(diphenylphosphino)pyridine. The isolation and characterization of cis-[Re2(O2CR)2X2(Ph2Ppy)2]n+ (R = CH3, C2H5; X = Cl, Br; n = 0, 1)
Paul W. Schrier, Daniel R. Derringer, Phillip E. Fanwick, and Richard A. Walton
pp 1290 - 1293; DOI:
10.1021/ic00331a033
PDF
Deprotonated amide nitrogen coordinating to the palladium(II) ion. Crystal and molecular structure of disodium bis(N-tosylglycinato-(N,O)palladate(II)
Ledi Menabue, Monica Saladini, and Marco Sola
pp 1293 - 1295; DOI:
10.1021/ic00331a034
PDF
A catenated dinickel-molybdenum species containing a molybdenacyclopentadiene unit linked to a dinickelatetrahedrane: an example of .eta.5-pentamethylcyclopentadienyl group lability
Michael J. Chetcuti, Laurie A. DeLiberato, Phillip E. Fanwick, and Brian E. Grant
pp 1295 - 1298; DOI:
10.1021/ic00331a035
PDF

Issue 7


Synthesis, structure, and properties of a novel heterobimetallic ironIIImanganeseII complex containing a septadentate polyimidazole ligand
Robert M. Buchanan, Mark S. Mashuta, John F. Richardson, Robert J. Webb, Kenneth J. Oberhausen, Mark A. Nanny, and David N. Hendrickson
pp 1299 - 1301; DOI:
10.1021/ic00332a001
PDF
Molecular mechanics of single bonds in tetrakis(carboxylato)dirhodium systems
Francoise M. O'Neill and Jan C. A. Boeyens
pp 1301 - 1302; DOI:
10.1021/ic00332a002
PDF
Novel vanadium(II) amine complexes: a facile entry in the chemistry of divalent vanadium. Synthesis and characterization of mononuclear L4VCl2 [L = amine, pyridine]: x-ray structures of trans-(TMEDA)2VCl2 [TMEDA = N,N,N',N'-tetramethylethylenediamine] and trans-Mz2V(py)2 [Mz = o-C6H4CH2N(CH3)2, py = pyridine]
Jilles J. H. Edema, Walter Stauthamer, Fre Van Bolhuis, Sandro Gambarotta, Wilberth J. J. Smeets, and Anthony L. Spek
pp 1302 - 1306; DOI:
10.1021/ic00332a003
PDF
Synthesis, characterization, and x-ray crystal structure of nitro(terpyridine)bis(trimethylphosphine)ruthenium(1+) perchlorate
Randolph A. Leising, Stephen A. Kubow, Melvyn Rowen Churchill, Lisa A. Buttrey, Joseph W. Ziller, and Kenneth J. Takeuchi
pp 1306 - 1312; DOI:
10.1021/ic00332a004
PDF
Synthesis and characterization of cationic gold-rhodium phosphite cluster complexes. X-ray crystal and molecular structure of {Au4Rh(H)2[P(O-iso-C3H7)3]2(PPh3)4}PF6
Bruce D. Alexander, Ann M. Mueting, and Louis H. Pignolet
pp 1313 - 1319; DOI:
10.1021/ic00332a005
PDF
Models for organometallic polymers. Zigzag chains of tetrakis(acetate)dimolybdenum units linked by bis(dimethylphosphine)ethane and tetramethylethylenediamine ligands
Michael C. Kerby, Bryan W. Eichhorn, J. Alan Creighton, and K. Peter C. Vollhardt
pp 1319 - 1323; DOI:
10.1021/ic00332a006
PDF
Structural and magnetic studies on macrocyclic dicopper(II) complexes. Influence of electron-withdrawing axial ligands on spin exchange
Sanat K. Mandal, Laurence K. Thompson, Michael J. Newlands, Eric J. Gabe, and Kamalaksha Nag
pp 1324 - 1327; DOI:
10.1021/ic00332a007
PDF
Tetrahalobis(diphosphine)dimolybdenum(II) compounds: .beta. isomers with seven-membered rings
F. Albert Cotton, Larry R. Falvello, Dawn R. Root, Thomas J. Smith, and K. Vidyasagar
pp 1328 - 1333; DOI:
10.1021/ic00332a008
PDF
Characterization of manganese(III) orthophosphate hydrate
Miguel A. G. Aranda and Sebastian Bruque
pp 1334 - 1337; DOI:
10.1021/ic00332a009
PDF
A primary molybdosulfenamide
Mark E. Noble
pp 1337 - 1342; DOI:
10.1021/ic00332a010
PDF
Characterization of peptide-coated cadmium-sulfide crystallites
Charles T. Dameron and Dennis R. Winge
pp 1343 - 1348; DOI:
10.1021/ic00332a011
PDF
Technetium nitrido complexes with amine and thiolate ligands: structural characterizations of nitridobis(1,1,2,2-tetramethylguanidine)bis(2,3,5,6-tetramethylbenzenethiolato)technetium, a complex with coordinatively bound 1,1,2,2-tetramethylguanidine
Nadine De Vries, Catherine E. Costello, Alun G. Jones, and Alan Davison
pp 1348 - 1352; DOI:
10.1021/ic00332a012
PDF
Molecular and crystal structures of a "platinblau" analog, bis(.mu.-acetamido)dichlorobis(dimethyl sulfoxide)diplatinum(II), and of cis-(acetonitrile)dichloro(dimethyl sulfoxide)platinum(II)
F. D. Rochon, P. C. Kong, and R. Melanson
pp 1352 - 1356; DOI:
10.1021/ic00332a013
PDF
Improved synthesis and isolation of a flexible linear NSNN tetradentate ligand and the crystal structure of its stereospecific dinitrocobalt(III) complex
Paul J. Toscano, Kimberly A. Belsky, Lutz M. Engelhardt, Kathy J. Fordon, and Allan H. White
pp 1357 - 1359; DOI:
10.1021/ic00332a014
PDF
(2,7-Dimethyloctadienediyl)ruthenium(IV) complexes: isomerism and solution equilibria for dichlorobis(.mu.-chloro)bis[(1-3-.eta.:6-8-.eta.)-2,7-dimethyloctadienediyl]diruthenium(IV) and related monomeric solvates
David N. Cox and Raymond Roulet
pp 1360 - 1365; DOI:
10.1021/ic00332a015
PDF
Cesium-133 NMR studies of crown ether-cesium(1+) complexes in high dielectric amide solvents
Lee Lin Soong, George E. Leroi, and Alexander I. Popov
pp 1366 - 1370; DOI:
10.1021/ic00332a016
PDF
Kinetics of dissociation of thorium(IV) bound to polymaleic acid and poly(methylvinylether) maleic acid
G. R. Choppin and W. Cacheris
pp 1370 - 1374; DOI:
10.1021/ic00332a017
PDF
Adducts of zirconium and hafnium tetrachlorides with neutral Lewis bases. 2. Kinetics and mechanism: a variable-temperature and -pressure proton NMR study
Marianne Turin-Rossier, Deirdre Hugi-Cleary, Urban Frey, and Andre E. Merbach
pp 1374 - 1379; DOI:
10.1021/ic00332a018
PDF
The role of one-parameter plots in a two-parameter world
Russell S. Drago
pp 1379 - 1382; DOI:
10.1021/ic00332a019
PDF
Resonance Raman spectroscopy of the one-electron-oxidized analogs of the dirhodium complexes Rh2(bridge)4.cntdot.2L: bridge = acetate, acetamidate, or trifluoroacetamidate; L = triphenylphosphine or triphenylarsine. Relationship between the rhodium-rhodium stretching frequency and bond order
Stephen P. Best, Robin J. H. Clark, and Andrew J. Nightingale
pp 1383 - 1387; DOI:
10.1021/ic00332a020
PDF
Magnetism and electronic structure of a series of encapsulated first-row transition metals
Lisandra L. Martin, Raymond L. Martin, Keith S. Murray, and Alan M. Sargeson
pp 1387 - 1394; DOI:
10.1021/ic00332a021
PDF
Apparent absence of electronic instability in the one-dimensional metal sodium copper sulfide (Na3Cu4S4)
Myung Hwan Whangbo and Enric Canadell
pp 1395 - 1397; DOI:
10.1021/ic00332a022
PDF
Semimetallic versus semiconducting properties of MX2 layer compounds containing d2 metal ions
Enric Canadell and Myung Hwan Whangbo
pp 1398 - 1401; DOI:
10.1021/ic00332a023
PDF
Comparison of the electronic structures of layered transition-metal trichalcogenides thallium triselenide, thallium trisulfide and niobium triselenide
E. Canadell, I. E. I. Rachidi, J. P. Pouget, P. Gressier, A. Meerschaut, J. Rouxel, D. Jung, M. Evain, and M. H. Whangbo
pp 1401 - 1407; DOI:
10.1021/ic00332a024
PDF
Reactivity of Rh4(CO)12 with halides or pseudohalides: synthesis of the pentanuclear carbonyl clusters [Rh5(CO)14X]n- (X = Cl, Br, I, SCN, n = 2; X = PPh3, n = 1). Crystal structures of [N(PPh3)2][Rh5(.mu.-CO)6(CO)8(PPh3)] and [N(PPh3)2]2[Rh5(.mu.-CO)6(CO)8(SCN)]
Alessandro Fumagalli, Secondo Martinengo, Daniele Galli, Claudio Allevi, Gianfranco Ciani, and Angelo Sironi
pp 1408 - 1413; DOI:
10.1021/ic00332a025
PDF
Structural origin of the electronic instability in titanium bronze Na0.25TiO2
Michel Evain, Myung Hwan Whangbo, Luc Brohan, and Rene Marchand
pp 1413 - 1416; DOI:
10.1021/ic00332a026
PDF
Platinum(II) binding to N7 and N1 of guanine and a model for a purine-N1,pyrimidine-N3 cross-link of cisplatin in the interior of a DNA duplex
Gudrun Frommer, Helmut Schoellhorn, Ulf Thewalt, and Bernhard Lippert
pp 1417 - 1422; DOI:
10.1021/ic00332a027
PDF
Reaction of hydroxide ion with manganese(III) tetramesitylporphyrin and the oxidation states of manganese tetramesitylporphyrins
Ramesh D. Arasasingham and Thomas C. Bruice
pp 1422 - 1427; DOI:
10.1021/ic00332a028
PDF
Reactivity of [1,4,7,10,13-pentaazacyclohexadecane-14,16-dionato(2-)]nickel(II) toward derivatives of methyl-coenzyme M
C. M. Drain, David B. Sable, and Barry B. Corden
pp 1428 - 1433; DOI:
10.1021/ic00332a029
PDF
Iron-porphyrin models of hemoprotein enzymes: mechanism of decomposition of the deuteroferriheme analogs of peroxidase enzyme intermediates
Ricardo E. Rodriguez, Fanny S. Woo, Dale A. Huckaby, and Henry C. Kelly
pp 1434 - 1438; DOI:
10.1021/ic00332a030
PDF
A comment on the proton NMR spectra of cobalt(II)-substituted superoxide dismutases with histidines deuteriated in the .epsilon.1-position
Lucia Banci, Ivano Bertini, Claudio Luchinat, and Maria Silvia Viezzoli
pp 1438 - 1440; DOI:
10.1021/ic00332a031
PDF
Cobalt carbonyl chemistry in wet ethereal solutions: [Co6(CO)15]2- and Co6(CO)16 cluster formation or stepwise water gas shift reaction
Tiziana Funaioli, Paolo Biagini, and Giuseppe Fachinetti
pp 1440 - 1442; DOI:
10.1021/ic00332a032
PDF
Dinuclear ruthenium complexes with bridging 1,4,5,8-tetraoxonaphthalene: redox properties and mixed-valence interactions
Andrea Dei, Dante Gatteschi, and Luca Pardi
pp 1442 - 1444; DOI:
10.1021/ic00332a033
PDF
Adducts of .pi.-acceptor ligands with copper(I) thiolates
Rajesh Kumar and Dennis G. Tuck
pp 1444 - 1446; DOI:
10.1021/ic00332a034
PDF
Atropisomerism in o-aryl-substituted borazines
Smail Allaoud, Touriya Zair, Abdallah Karim, and Bernard Frange
pp 1447 - 1449; DOI:
10.1021/ic00332a035
PDF
The crystal structure of chlorobis[dihydrobis(pyrazolyl)borato]gallium: corrigendum
Richard E. Marsh
pp 1449 - 1450; DOI:
10.1021/ic00332a036
PDF
Origin of the solvent effect on the photolysis of pentaamminebromocobalt(2+) at 254 nm in a water-acetonitrile solvent system
Cooper H. Langford and Elspeth Lindsay
pp 1450 - 1451; DOI:
10.1021/ic00332a037
PDF
Synthesis, x-ray crystal structure, and metal ion extraction from a nitrogen-sulfur "pendant arm" encapsulated complex of cobalt(III)
Lawrence R. Gahan, Therese M. Donlevy, and Trevor W. Hambley
pp 1451 - 1454; DOI:
10.1021/ic00332a038
PDF

Issue 8


Contrasting reactivities of ligand-to-metal charge transfer excited states in ammine and methylamine complexes of cobalt(III)
Scott K. Weit and Charles Kutal
pp 1455 - 1456; DOI:
10.1021/ic00333a001
PDF
Synthesis and structural characterization of a polyoxovanadate coordination complex with a hexametalate core: [(n-C4H9)4N]2[V6O13{O2NC(CH2O)3}2]
Qin Chen and Jon Zubieta
pp 1456 - 1458; DOI:
10.1021/ic00333a002
PDF
Crystal structure of lithium niobium ethoxide (LiNb(OCH2CH3)6: a precursor for lithium niobate ceramics
Dennis J. Eichorst, Kevin E. Howard, David A. Payne, and Scott R. Wilson
pp 1458 - 1459; DOI:
10.1021/ic00333a003
PDF
pKa of zinc-bound water and nucleophilicity of hydroxo-containing species. Ab initio calculations on models for zinc enzymes
Ivano Bertini, Claudio Luchinat, Marzio Rosi, Antonio Sgamellotti, and Francesco Tarantelli
pp 1460 - 1463; DOI:
10.1021/ic00333a004
PDF
Stabilities of trivalent metal complexes of phenolic ligands related to N,N'-bis(2-hydroxybenzyl)ethylenediamine-N,N'-diacetic acid (HBED)
Ramunas J. Motekaitis, Arthur E. Martell, and Michael J. Welch
pp 1463 - 1467; DOI:
10.1021/ic00333a005
PDF
Equilibrium studies and molecular recognition in the catechol- and TIRON-bridged binuclear cobalt(II) 1,4,7,13,16,19-hexaaza-10,22-dioxacyclotetracosane dioxygen complexes
Bruno Szpoganicz, Ramunas J. Motekaitis, and Arthur E. Martell
pp 1467 - 1474; DOI:
10.1021/ic00333a006
PDF
A new bifunctional chelate, N-(2-hydroxy-3,5-dimethylbenzyl)-N'-(2-hydroxy-5-(bromoacetamido)benzyl)ethylenediamine-N,N'-diacetic acid (BrMe2HBED): an effective conjugate for radiometals and antibodies
Carla J. Mathias, Yizhen Sun, Judith M. Connett, Gordon W. Philpott, Michael J. Welch, and Arthur E. Martell
pp 1475 - 1480; DOI:
10.1021/ic00333a007
PDF
Conformational changes in a single- and double-stranded nonanucleotide upon complexation of a monofunctional platinum compound as studied by proton NMR, phosphorus-31 NMR and CD methods.
Carla J. Van Garderen, Cornelis Altona, and Jan Reedijk
pp 1481 - 1487; DOI:
10.1021/ic00333a008
PDF
Gadolinium complexation by a new diethylenetriaminepentaacetic acid-amide ligand. Amide oxygen coordination
Mark S. Konings, William C. Dow, David B. Love, Kenneth N. Raymond, Steven C. Quay, and Scott M. Rocklage
pp 1488 - 1491; DOI:
10.1021/ic00333a009
PDF
Geometrical isomerism of mixed tris(amino carboxylato)cobalt(III) complexes containing glycinato and .beta.-alaninato ligands. Crystal structure of trans(O5)-(.beta.-alaninato)bis(glycinato)cobalt(III) trihydrate
N. Juranic, B. Prelesnik, L. Manojlovic-Muir, K. Andjelkovic, S. R. Niketic, and M. B. Celap
pp 1491 - 1495; DOI:
10.1021/ic00333a010
PDF
Formation of iron thiolates via complexes of molecular hydrogen
Sue E. Boyd, Leslie D. Field, Trevor W. Hambley, and David J. Young
pp 1496 - 1500; DOI:
10.1021/ic00333a011
PDF
Chemistry of organometalloid complexes with potential antidotes: structure of an organoarsenic(III) dithiolate ring
Earle Adams, David Jeter, A. Wallace Cordes, and Joseph W. Kolis
pp 1500 - 1503; DOI:
10.1021/ic00333a012
PDF
Syntheses and structures of K3MO4 (M = niobium, tantalum; Q = sulfur, selenium)
Michel Latroche and James A. Ibers
pp 1503 - 1505; DOI:
10.1021/ic00333a013
PDF
Preparation and characterization of rhodium pentamethylcyclopentadienyl isocyanide complexes, (C5Me5)Rh(CNR)2 and [(C5Me5)Rh(CNR)]2 complexes
William D. Jones, Robert P. Duttweiler, and Frank J. Feher
pp 1505 - 1511; DOI:
10.1021/ic00333a014
PDF
Reaction of heptahydridobis(triphenylphosphine)rhenium with silanes: preparation and characterization of the first silyl polyhydride complexes, ReH6(SiR3)(PPh3)2 (SiR3 = SiPh3, SiEt3, SiHEt2)
Xiao Liang Luo, Denise Baudry, Philip Boydell, Pierrette Charpin, Martine Nierlich, Michel Ephritikhine, and Robert H. Crabtree
pp 1511 - 1517; DOI:
10.1021/ic00333a015
PDF
Ammonolysis of tantalum alkyls: formation of cubic tantalum nitride and a trimeric nitride, [Cp*MeTaN]3 tris[(.eta.5-pentamethylcyclopentadienyl)(methyl)nitridotantalum]
Mark M. Banaszak Holl, Meinolf Kersting, Bradford D. Pendley, and Peter T. Wolczanski
pp 1518 - 1526; DOI:
10.1021/ic00333a016
PDF
Crystal and molecular structure and Raman and iodine-127 Moessbauer spectra of iodine(III) bis(fluorosulfate) iodide, I(OSO2F)2I
T. Birchall, G. Denes, R. Faggiani, Christopher S. Frampton, R. J. Gillespie, R. Kapoor, and J. E. Vekris
pp 1527 - 1530; DOI:
10.1021/ic00333a017
PDF
Electrochemistry and photoelectrochemistry of pillared-clay-modified electrodes
Daiting Rong, Yeong II Kim, and Thomas E. Mallouk
pp 1531 - 1535; DOI:
10.1021/ic00333a018
PDF
Modes of phosphate binding to copper(II): investigations of the electron spin echo envelope modulation of complexes on surfaces and in solutions
Wolfgang Moehl, Arthur Schweiger, and Herbert Motschi
pp 1536 - 1543; DOI:
10.1021/ic00333a019
PDF
Bis(phosphine)nickelacyclopentane: an investigation by local spin density theory
Andrea Peluso, Dennis R. Salahub, and Annick Goursot
pp 1544 - 1549; DOI:
10.1021/ic00333a020
PDF
Electron transfer from halide ions to uranyl(2+) excited-state ions in aqueous solution: formation and decay of dihalide radical anions
Hugh D. Burrows
pp 1549 - 1554; DOI:
10.1021/ic00333a021
PDF
Kinetics of formation and dissociation of the 1,4,7-triazacyclononane-N,N',N"-triacetate complexes of cerium(III), gadolinium(III), and erbium(III) ions
Erno Brucher and A. Dean Sherry
pp 1555 - 1559; DOI:
10.1021/ic00333a022
PDF
Nonmetal redox kinetics: reactions of iodine and triiodide with sulfite and hydrogen sulfite and the hydrolysis of iodosulfate
Boudin S. Yiin and Dale W. Margerum
pp 1559 - 1564; DOI:
10.1021/ic00333a023
PDF
Diphosphine-bridged heterobimetallic hydride and carbonyl complexes of rhodium and iridium. Structure of [RhIr(CO)3(Ph2PCH2PPh2)2], a complex containing an Ir(-I) .fwdarw. Rh(I) dative bond
Robert McDonald and Martin Cowie
pp 1564 - 1571; DOI:
10.1021/ic00333a024
PDF
A new three-dimensionally nonmolecular cadmium-sulfur lattice in crystalline bis(DMF)tetradeca(2-methylbenzenethiolato)heptacadmium
Ian G. Dance, Robert G. Garbutt, and Marcia L. Scudder
pp 1571 - 1575; DOI:
10.1021/ic00333a025
PDF
Synthesis and characterization of rhenium(I) complexes bound to the bridging ligand 2,3-bis(2-pyridyl)pyrazine
Ronald Ruminski and R. Thomas Cambron
pp 1575 - 1578; DOI:
10.1021/ic00333a026
PDF
Strategy for the synthesis of mixed phosphine-phosphine, phosphine-arsine and phosphine-stibine complexes of the types Re2H8(PR2Ph)2(EPh3)2 and Re2H8(PRPh2)3(EPh3) (R = Me, Et; E = phosphorus, arsenic, antimony)
Michael T. Costello, Gregory A. Moehring, and Richard A. Walton
pp 1578 - 1581; DOI:
10.1021/ic00333a027
PDF
Superexchange coupling mediated by carboxylate and hydrogen bridges in copper amino acid complexes
Patricia R. Levstein and Rafael Calvo
pp 1581 - 1583; DOI:
10.1021/ic00333a028
PDF
Ion pairing in [bis(trimethylsilyl)amido]potassium: The x-ray crystal structure of unsolvated [KN(SiMe3)2]2
Kris F. Tesh, Timothy P. Hanusa, and John C. Huffman
pp 1584 - 1586; DOI:
10.1021/ic00333a029
PDF
Formation and structure of the tris(catecholato)vanadate(IV) complex in aqueous solution
Mario Branca, Giovanni Micera, Alessandro Dessi, Daniele Sanna, and Kenneth N. Raymond
pp 1586 - 1589; DOI:
10.1021/ic00333a030
PDF
Helical heptacoordinate complexes of cobalt derived from 2,2':6',2'':6'',2''':6''',2''''-quinequepyridine derivatives
Kimberly A. Gheysen, Kevin T. Potts, Helen C. Hurrell, and Hector D. Abruna
pp 1589 - 1592; DOI:
10.1021/ic00333a031
PDF
A convenient synthesis of solvated and unsolvated anhydrous metal chlorides via dehydration of metal chloride hydrates with trimethylchlorosilane
Jeung Ho So and Philip Boudjouk
pp 1592 - 1593; DOI:
10.1021/ic00333a032
PDF
Nucleophilicities of the metal carbonyl anions: effects of ligands, solvent and countercation [Erratum to document cited in CA111(16):141547f]
Chung Kung Lai, William G. Feighery, Yueqian Zhen, and Jim D. Atwood
pp 1594 - 1594; DOI:
10.1021/ic00333a033
PDF
Similarities and differences in the structural and electronic properties of .kappa.-phase organic conducting and superconducting salts [Erratum to document cited in CA111(26):245668n]
D. Jung, M. Evain, J. J. Novoa, M. H. Whangbo, M. A. Beno, A. M. Kini, A. J. Schultz, J. M. Williams, and P. J. Nigrey
pp 1594 - 1594; DOI:
10.1021/ic00333a034
PDF
Structural and thermodynamic characterization of manganese(II) N,N'-dipyridoxylethylenediamine-N,N'-diacetate. A novel manganese(II) chelate [Erratum to document cited in CA109(18):162299a]
Scott M. Rocklage, Steve H. Sheffer, William P. Cacheris, Steven C. Quay, Ekkehardt F. Hahn, and Kenneth N. Raymond
pp 1594 - 1594; DOI:
10.1021/ic00333a035
PDF

Issue 9


The organotin(IV) coordination polymer [(Me3Sn)4Fe(CN)6.2H2O.C4H8O2].infin.: a three-dimensional host-guest network involving "cascade type" guests
Martin Adam, Abdul K. Brimah, R. D. Fischer, and Xingfu Li
pp 1595 - 1597; DOI:
10.1021/ic00334a001
PDF
Cyclic voltammetry of imidazolemicroperoxidase-8: modeling the control of the redox potential of the cytochromes
Helder M. Marques
pp 1597 - 1599; DOI:
10.1021/ic00334a002
PDF
The first ambient pressure organic superconductor containing oxygen in the donor molecule, .beta.m-(BEDO-TTF)3Cu2(NCS)3, Tc = 1.06 K
Mark A. Beno, Hau H. Wang, Aravinda M. Kini, K. Douglas Carlson, Urs Geiser, W. K. Kwok, James E. Thompson, Jack M. Williams, Jingqing Ren, and Myung Hwan Whangbo
pp 1599 - 1601; DOI:
10.1021/ic00334a003
PDF
Synthesis and structural characterization of the platinum complex, cis-[(Cy2PCH2CH2PCy2)(NP)PtGa(NP)2 (Cy = cyclohexyl; NP = neopentyl)
R. A. Fischer, H. D. Kaesz, S. I. Khan, and H. J. Muller
pp 1601 - 1602; DOI:
10.1021/ic00334a004
PDF
Facile, high yield synthesis of functionalized spherosilicates: precursors of novel organolithic macromolecular materials
Pradyot A. Agaskar
pp 1603 - 1603; DOI:
10.1021/ic00334a005
PDF
Antiferromagnetic exchange in an isomorphous series of siloxy-bridged early-transition-metal dimers: comparisons of antiferromagnetic exchange interactions in isomorphous d1-d1, d1-d2, d2-d2, and d2-d3 exchange-coupled dimers
Frank J. Feher and John F. Walzer
pp 1604 - 1611; DOI:
10.1021/ic00334a006
PDF
Polymeric anions leading to novel packing motifs in donor-radical salts: synthesis and crystal and band electronic structure of (BEDT-TTF)BiI4
Urs Geiser, Hau H. Wang, Sandra M. Budz, Michael J. Lowry, Jack M. Williams, Jinqing Ren, and Myung Hwan Whangbo
pp 1611 - 1614; DOI:
10.1021/ic00334a007
PDF
Optical spectrum of dipotassium tetrafluorocuprate
Mark J. Riley, Lucjan Dubicki, Grainne Moran, Elmars R. Krausz, and Isao Yamada
pp 1614 - 1626; DOI:
10.1021/ic00334a008
PDF
Variable-photon-energy photoelectron spectroscopic studies of high-spin d6 tetrahedral tetrachloroferrate(2-): electronic relaxation effects on ionization
Kristine D. Butcher, Stephen V. Didziulis, Bernard Briat, and Edward I. Solomon
pp 1626 - 1637; DOI:
10.1021/ic00334a009
PDF
Structural changes accompanying oxidative additions of tetrachloro-1,2-benzoquinone to phosphine-bridged binuclear and trinuclear rhodium complexes
Alan L. Balch, Vincent J. Catalano, and Marilyn M. Olmstead
pp 1638 - 1642; DOI:
10.1021/ic00334a010
PDF
Preparation of thiazyl tetrachloroaluminate and trifluoromethanesulfonate and reactions of the thiazyl cation with thiadiazoles and organoselenium halides: x-ray crystal structure of [N2S2SeCl][AlCl4]
Allen Apblett, Tristram Chivers, and James F. Fait
pp 1643 - 1648; DOI:
10.1021/ic00334a011
PDF
Synthesis, x-ray structures, and spectroscopic and magnetic properties of a series of isomeric binuclear molybdenum(III) complexes of general formula Mo2Cl6L3 (L = thioether): large structural influence of bridging ligands in confacial bioctahedral complexes
Kelly J. Moynihan, Xiaoliang Gao, P. Michael Boorman, James F. Fait, Gavin K. W. Freeman, Peter Thornton, and David J. Ironmonger
pp 1648 - 1654; DOI:
10.1021/ic00334a012
PDF
An adduct with a one-dimensional chain structure from bis(hexafluoroacetylacetonato)copper(II) and an aliphatic nitroxyl diradical
Phillip T. Matsunaga, Dialne T. McCall, Michael D. Carducci, and Robert J. Doedens
pp 1655 - 1659; DOI:
10.1021/ic00334a013
PDF
Insertion of a copper nitrene into a carbon-hydrogen bond to form bis(2-(phenylamino)-1,10-phenanthrolinato)dicopper(I): a short copper-copper distance with no bond?
Soon W. Lee and William C. Trogler
pp 1659 - 1662; DOI:
10.1021/ic00334a014
PDF
Preparation and reactions of sulfido and persulfido complexes of (pentamethylcyclopentadienyl)tungsten
J. W. Faller, Robin R. Kucharczyk, and Yinong Ma
pp 1662 - 1667; DOI:
10.1021/ic00334a015
PDF
Solid-state chemistry of molecular metal oxide clusters. Bis(triphenylphosphine)rhodium(I) carbonyl derivatives
A. R. Siedle, W. B. Gleason, R. A. Newmark, R. P. Skarjune, P. A. Lyon, C. G. Markell, K. O. Hodgson, and A. L. Roe
pp 1667 - 1673; DOI:
10.1021/ic00334a016
PDF
Reactivity of [bis(dimethylgermyl)alkane]iron tetracarbonyls with carbonyl compounds
Jacques Barrau, Najib Ben Hamida, Hamid Agrebi, and Jacques Satge
pp 1674 - 1678; DOI:
10.1021/ic00334a017
PDF
Synthesis of vanadium, niobium, and tantalum silylimido complexes and reactivity of their nitrogen-silicon bonds
Carolyn M. Jones, Megan E. Lerchen, Carolyn J. Church, Beth M. Schomber, and Nancy M. Doherty
pp 1679 - 1682; DOI:
10.1021/ic00334a018
PDF
Models of vitamin B6 enzymes. 3. Steric and electronic effects in carbon-hydrogen bond breaking reactions of bis(salicylideneglycinato)cobaltate(III) anions
James R. Fischer, Ross J. Fischer, and Edwin H. Abbott
pp 1682 - 1687; DOI:
10.1021/ic00334a019
PDF
Synthesis and dioxygen reactivity of dinuclear copper-phenolate and copper-phenol complexes with pyrazole and pyridine donors
Thomas N. Sorrell and Vivian A. Vankai
pp 1687 - 1692; DOI:
10.1021/ic00334a020
PDF
Selective formation of ruthenium(IV) complexes with a monooxygen ligand: trans-[RuX(O)(py)4]+ (X = Cl, ONO)
Hirotaka Nagao, Hisatoshi Nishimura, Yoshiko Kitanaka, F. Scott Howell, Masao Mukaida, and Hidetake Kakihana
pp 1693 - 1700; DOI:
10.1021/ic00334a021
PDF
Temperature and pressure effects on the outer-sphere electron-transfer reaction between hexacyanoferrate(II) and pentaamminecobalt(III) complexes in aqueous solution. Comparison of experimental and theoretical volumes of activation
I. Krack and R. Van Eldik
pp 1700 - 1704; DOI:
10.1021/ic00334a022
PDF
Kinetics and mechanism of the autoxidation of iron(II) induced through chelation by ethylenediaminetetraacetate and related ligands
V. Zang and R. Van Eldik
pp 1705 - 1711; DOI:
10.1021/ic00334a023
PDF
Kinetics of the outer-sphere oxidation of the mixed molybdenum(V)-tungsten(V) dinuclear complex [MoW(O)2(.mu.-O)2(.mu.-edta-N,N')]2- and of the mixed-bridged complex [W2(O)2(.mu.-O)(.mu.-S)(.mu.-edta-N,N')]2- by [IrIVCl6]2- in aqueous solution
J. Folorunso Ojo, Yoshinori Hasegawa, Yoichi Sasaki, and Shinji Ikari
pp 1712 - 1716; DOI:
10.1021/ic00334a024
PDF
Heptacoordination of manganese(II) by the polyazacycloalkane 1,4,7,10,13,16,19-heptaazacycloheneicosane, [21]aneN7. Crystal structure of the [Mn([21]aneN7)](ClO4)2 solid compound and thermodynamics of complexation in water solution
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Victor Marcelino, Mauro Micheloni, Piero Paoletti, and Paola Paoli
pp 1716 - 1718; DOI:
10.1021/ic00334a025
PDF
Perchlorinated phthalocyanines: spectroscopic properties and surface electrochemistry
M. Neal Golovin, Penny Seymour, Karupiah Jayaraj, Yan Song Fu, and A. B. P. Lever
pp 1719 - 1727; DOI:
10.1021/ic00334a026
PDF
Influence of distal steric hindrance on multiple energy barriers in ligand binding to heme model compounds
Catherine Tetreau, Michel Momenteau, and Daniel Lavalette
pp 1727 - 1731; DOI:
10.1021/ic00334a027
PDF
Early/late heterobimetallic complexes: syntheses and spectral and structural studies of thiolato-bridged titanium/copper and vanadium/copper complexes
Teresa A. Wark and Douglas W. Stephan
pp 1731 - 1736; DOI:
10.1021/ic00334a028
PDF
Stable cationic 17-electron [LM(CO)3]+ species (L = 1,4,7-tribenzyl-1,4,7-triazacyclononane; M = Cr, Mo, W): synthesis, spectroscopic properties, and reactivity. Crystal structure of [LMo(CO)3](PF6).cntdot.dmf
Thomas Beissel, Beatriz S. P. C. Della Vedova, Karl Wieghardt, and Roland Boese
pp 1736 - 1741; DOI:
10.1021/ic00334a029
PDF
Five-coordinate platinum(II) hydrides containing 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane as a tetradentate monometallic ligand
Peter Brueggeller
pp 1742 - 1750; DOI:
10.1021/ic00334a030
PDF
Synthesis, crystal structure, and magnetic properties of tetranuclear complexes containing exchange-coupled dilanthanide-dicopper(lanthanide = gadolinium, dysprosium) species
Cristiano Benelli, Andrea Caneschi, Dante Gatteschi, Olivier Guillou, and Luca Pardi
pp 1750 - 1755; DOI:
10.1021/ic00334a031
PDF
Crystal structure and magnetic properties of a copper(II) chloride nitronyl nitroxide complex containing six exchange-coupled S = 1/2 spins
Andrea Caneschi, Fabrizio Ferraro, Dante Gatteschi, Paul Rey, and Roberta Sessoli
pp 1756 - 1760; DOI:
10.1021/ic00334a032
PDF
Ground-state and excited-state properties of monometallic and bimetallic complexes based on rhenium(I) tricarbonyl chloride: effect of an insulating vs a conducting bridge
Shawn Van Wallendael, Randy J. Shaver, D. Paul Rillema, B. J. Yoblinski, Michael Stathis, and Thomas F. Guarr
pp 1761 - 1767; DOI:
10.1021/ic00334a033
PDF
Ruthenium(II) complexes of N,N'-bridged derivatives of 2,2'-biimidazole
Veronique Goulle and Randolph P. Thummel
pp 1767 - 1772; DOI:
10.1021/ic00334a034
PDF
Synthesis and characterization of novel (cyclopentadienyl) nitroruthenium complexes
Lisa F. Szczepura and Kenneth J. Takeuchi
pp 1772 - 1777; DOI:
10.1021/ic00334a035
PDF
X-ray structure of {HB(Me2pz)3}WVIO2(.mu.-O)WIVO(CO){HB(Me2pz)3}, a molecule containing rare cis-[WO(CO)]2+ and syn-[WVIWIVO3(.mu.-O)]2+ moieties [HB(Me2pz)3- = hydrotris(3,5-dimethyl-1-pyrazolyl)borate]
Charles G. Young, Robert W. Gable, and Maureen F. Mackay
pp 1777 - 1779; DOI:
10.1021/ic00334a036
PDF
New syntheses of xenon hexafluoride (XeF6) and xenon tetrafluoride (XeF4)
Jon B. Nielsen, Scott A. Kinkead, John D. Purson, and P. Gary Eller
pp 1779 - 1780; DOI:
10.1021/ic00334a037
PDF
Solution and solid-state structures of the monomeric, piano-stool mono(peralkylcyclopentadienyl)vanadium(IV) trihalides
Michael S. Hammer and Louis Messerle
pp 1780 - 1782; DOI:
10.1021/ic00334a038
PDF

Issue 10


Reactivity of triphenylphosphine toward Ru2Cl(.mu.-O2CAr)4: isolation of asymmetric, trapped mixed-valence diruthenium(III,II) compounds with an {Ru2(.mu.-OH2)(.mu.-O2CAr)23+} core (Ar = Ph, C6H4-p-OMe)
Birinchi K. Das and Akhil R. Chakravarty
pp 1783 - 1784; DOI:
10.1021/ic00335a001
PDF
Polyoxoanions as soluble metal oxide analogs. 5. Synthesis and characterization of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir.cntdot.P2W15Nb3O628-
Richard G. Finke, David K. Lyon, Kenji Nomiya, Sandip Sur, and Noritaka Mizuno
pp 1784 - 1787; DOI:
10.1021/ic00335a002
PDF
Polyoxoanions as soluble metal oxide analogs. 6. Catalytic activity and initial kinetic and mechanistic studies of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir.cntdot.P2W15Nb3O628-
David K. Lyon and Richard G. Finke
pp 1787 - 1789; DOI:
10.1021/ic00335a003
PDF
Chemistry of zerovalent tungsten alkoxides. Synthesis, x-ray structure and reactivity toward carbon dioxide
Donald J. Darensbourg, Brian L. Mueller, Christopher J. Bischoff, and Joseph H. Reibenspies
pp 1789 - 1791; DOI:
10.1021/ic00335a004
PDF
Molecular structure of (bipyridine)dioxobis(pyridine)rhenium(1+) perchlorate: an unusual example of a d2 metal complex with a cis-dioxo ligand configuration
Robert L. Blackbourn, Lisa M. Jones, M. S. Ram, Michal Sabat, and Joseph T. Hupp
pp 1791 - 1792; DOI:
10.1021/ic00335a005
PDF
Carbon-13 and cadmium-113 nuclear magnetic resonance evidence for a novel transannular oscillation of cadmium(II) in the pendant arm macrocyclic complex [1,4,8,11-tetrakis(2-hydroxyethyl)-1,4,8,11-tetraazacyclotetradecane]cadmium(II)
Philip Clarke, Andrea M. Hounslow, Rebecca A. Keough, Stephen F. Lincoln, and Kevin P. Wainwright
pp 1793 - 1797; DOI:
10.1021/ic00335a006
PDF
Chiroptical properties of a compound containing a metal-metal quadruple bond. Synthesis, structure, and spectra of .beta.-Mo2Cl4(S,S-bppm)2, where S,S-bppm is (2S,4S)-N-(tert-butoxycarbonyl)-4-(diphenylphosphino)-2-[(diphenylphosphino)methyl]pyrrolidine
Jhy Der Chen and F. Albert Cotton
pp 1797 - 1802; DOI:
10.1021/ic00335a007
PDF
Tertiary phosphine complexes of chromium(III): syntheses, magnetic properties, and single-crystal structure studies on Cr2Cl6(PMe3)4, Cr2Cl6(PEt3)4, and Cr2Cl6(dmpm)2
F. A. Cotton, Judith L. Eglin, Rudy L. Luck, and Kyung Ae Son
pp 1802 - 1806; DOI:
10.1021/ic00335a008
PDF
Chromyl complexes with aryloxy and siloxy ligands
Pericles Stavropoulos, Nathan Bryson, Marie Therese Youinou, and John A. Osborn
pp 1807 - 1811; DOI:
10.1021/ic00335a009
PDF
Weak platinum-hydrogen-carbon interactions. Extensions to 8-methylquinoline, benzoquinoline, and a tetralone Schiff base. X-ray crystal structure of trans-PtCl2(benzoquinoline)(PEt3)
Alberto Albinati, Paul S. Pregosin, and Franz Wombacher
pp 1812 - 1817; DOI:
10.1021/ic00335a010
PDF
[1]Ferrocenophanes containing a Group 4 transition metal in the bridge. X-ray structure of one representative
Roland Broussier, Anne Da Rold, Bernard Gautheron, Yves Dromzee, and Yves Jeannin
pp 1817 - 1822; DOI:
10.1021/ic00335a011
PDF
Transition-metal complexes with sulfur ligands. 50. Sulfur bond cleavage in organosulfur ligands induced by PPh3/NO substitution reactions at [Ru(PPh3)2('L4')] centers. Synthesis and reactions of various (vinylthio)arenethiolate and related [Ru(NO)(Y)('L4')] (Y = PPh3, Cl) complexes. X-ray structure analysis of nitrosyl(triphenylphosphine)(1,2-benzenedithiolato)(1-(vinylthio)-2-benzenethiolato)ruthenium(III)
Dieter Sellmann, Isabella Barth, Falk Knoch, and Matthias Moll
pp 1822 - 1826; DOI:
10.1021/ic00335a012
PDF
Preparation of (.eta.-C5H5)Ru(PPh3)(L)SR (R = 1-C3H7, CHMe2, 4-C6H4Me; L = PPh3, CO) and insertion of CS2 into the Ru-SR bond to give the thioxanthates (.eta.-C5H5)Ru(PPh3)S2CSR (R = 1-C3H7, CHMe2, 4-C6H4Me). Crystal structure of (.eta.-C5H5)Ru(PPh3)S2CS-1-C3H7
Alan Shaver, Pierre Yves Plouffe, Peter Bird, and Edward Livingstone
pp 1826 - 1832; DOI:
10.1021/ic00335a013
PDF
Preparation and crystal structure of bis(cyclopentadienyl)tetracarbonylbis(.mu.-2-propanethiolato)ditungsten(II), [CpW(CO)2(.mu.-SCHMe2)]2, and bis(cyclopentadienyl)dicarbonylbis(.mu.-2-propanethiolato)ditungsten(II), [CpW(CO)(.mu.-SCHMe2)]2
Alan Shaver, Bernadette Soo Lum, Peter Bird, Edward Livingstone, and Melodie Schweitzer
pp 1832 - 1835; DOI:
10.1021/ic00335a014
PDF
Preparation and structural characterization of two mixed ammine/chloro/1-methylthymine diplatinum(II) complexes: cis-[(NH3)2Pt(1-MeT)2Pt(NH3)Cl][Pt(NH3)Cl3].cntdot.H2O and cis-(NH3)2Pt(1-MeT)2PtCl2.cntdot.3H2O
Wolfgang Micklitz, Oliver Renn, Helmut Schoellhorn, Ulf Thewalt, and Bernhard Lippert
pp 1836 - 1840; DOI:
10.1021/ic00335a015
PDF
Novel osmium(IV) and -(V) porphyrins. Synthesis, spectroscopy, and electrochemistry
Chi Ming Che, Wa Hung Leung, and Wai Cheung Chung
pp 1841 - 1846; DOI:
10.1021/ic00335a016
PDF
Proton NMR studies of iron(III) porphyrins with axial phenoxide or thiophenoxide ligands
Ramesh D. Arasasingham, Alan L. Balch, Charles R. Cornman, Jeffrey S. De Ropp, Ken Eguchi, and Gerd N. La Mar
pp 1847 - 1850; DOI:
10.1021/ic00335a017
PDF
.mu.-Oxo-bis(oxo) dinuclear complexes of technetium(V) with amine phenol ligands: syntheses, characterization, and x-ray crystal structures
M. R. A. Pillai, C. S. John, J. M. Lo, E. O. Schlemper, and D. E. Troutner
pp 1850 - 1856; DOI:
10.1021/ic00335a018
PDF
Indole nitrogen-palladium(II) bonding. Chemical and structural characterization of palladium(II) complexes of alkylindoles and intermediacy of the 3H-indole ring
Osamu Yamauchi, Masako Takani, Kazuo Toyoda, and Hideki Masuda
pp 1856 - 1860; DOI:
10.1021/ic00335a019
PDF
Spectroelectrochemical characterization of nitridochromium(V) porphyrins and their reactivity with substituted acetic anhydrides
Lawrence A. Bottomley and Frank L. Neely
pp 1860 - 1865; DOI:
10.1021/ic00335a020
PDF
Resonance Raman spectra of high- and low-spin ferric phenolates. Models for dioxygenases and nitrile hydratase
Carl J. Carrano, Mary W. Carrano, Kamala Sharma, Gabriele Backes, and Joann Sanders-Loehr
pp 1865 - 1870; DOI:
10.1021/ic00335a021
PDF
Biomineralization of iron: Moessbauer spectroscopy and electron microscopy of ferritin cores from the chiton Acanthopleura hirtosa and the limpet Patella laticostata
T. G. St. Pierre, K. S. Kim, J. Webb, S. Mann, and D. P. E. Dickson
pp 1870 - 1874; DOI:
10.1021/ic00335a022
PDF
Proton NMR studies of the oxidized and partially reduced 2(4Fe-4S) ferredoxin from Clostridium pasteurianum
Ivano Bertini, Fabrizio Briganti, Claudio Luchinat, and Andrea Scozzafava
pp 1874 - 1880; DOI:
10.1021/ic00335a023
PDF
Characterization of products from chloro(diethylenetriamine)platinum(1+) chloride and S-adenosyl-L-homocysteine. Evidence for a pH-dependent migration of the platinum moiety from the sulfur atom to the amine group and vice versa
Edwin L. M. Lempers and Jan Reedijk
pp 1880 - 1884; DOI:
10.1021/ic00335a024
PDF
Spectroscopic studies of cyclometalated platinum(II) complexes: superposition of two different spectroscopic species in the electronic spectra of a single crystal of [Pt(bpm)(CN)2] (bpm = 2,2'-bipyrimidine)
Josef Biedermann, Guenter Gliemann, Ulrich Klement, Klaus Juergen Range, and Manfred Zabel
pp 1884 - 1888; DOI:
10.1021/ic00335a025
PDF
Photophysics and photoredox reactions of ligand-bridged binuclear polypyridyl complexes of ruthenium(II) and of their monomeric analogs
K. Kalyanasundaram and M. K. Nazeeruddin
pp 1888 - 1897; DOI:
10.1021/ic00335a026
PDF
Design and evaluation of conjugated bridging .pi. systems. Molecular orbital characterization and electrochemical determination of the pentacarbonyltungsten binding site in two new ambidentate ligands
Wolfgang Kaim and Stephen Kohlmann
pp 1898 - 1902; DOI:
10.1021/ic00335a027
PDF
Plutonium(IV) polymers in aqueous and organic media
P. Thiyagarajan, H. Diamond, L. Soderholm, E. P. Horwitz, L. M. Toth, and L. K. Felker
pp 1902 - 1907; DOI:
10.1021/ic00335a028
PDF
Chemistry and electronic and vibrational spectroscopy of mononuclear and dinuclear (tris(1-pyrazolyl)borato)- and chloro molybdenum(V)-oxo complexes
Sandra E. Lincoln and Thomas M. Loehr
pp 1907 - 1915; DOI:
10.1021/ic00335a029
PDF
Comparison of laser-desorption and fast-atom-bombardment mass spectra of a series of rhodium Rh(PPh3)2(CO)Y complexes
Daniel M. Branan, Norris W. Hoffman, E. Andrew McElroy, David L. Ramage, Martha J. Robbins, John R. Eyler, Clifford H. Watson, Paul DeFur, and Julie A. Leary
pp 1915 - 1919; DOI:
10.1021/ic00335a030
PDF
Excited-state absorption spectroscopy and spectroelectrochemistry of tetrakis(2,2'-bipyridine)(.mu.-2,3-bis(2-pyridyl)pyrazine)diruthenium(II) and its mononuclear counterpart: a comparative study
Robert M. Berger
pp 1920 - 1924; DOI:
10.1021/ic00335a031
PDF
Photochemistry of semiconductor surfaces: in situ photoreduction of tin disulfide
R. Ken Force, Mebrahtu G. Fessehaie, Robert Grosso, Skye McClain, William S. Willis, and Steven L. Suib
pp 1924 - 1929; DOI:
10.1021/ic00335a032
PDF
Theoretical studies of borylphosphine, its conjugate base, and the lithium salt of its conjugate base. The use of orbital kinetic energies to determine the origin of the driving force for changes in molecular geometry
Thomas L. Allen, Andrew C. Scheiner, and Henry F. Schaefer
pp 1930 - 1936; DOI:
10.1021/ic00335a033
PDF
Tetrasolventoberyllium(II): high-pressure evidence for a sterically controlled solvent-exchange mechanism crossover
Pierre Andre Pittet, Gilles Elbaze, Lothar Helm, and Andre E. Merbach
pp 1936 - 1942; DOI:
10.1021/ic00335a034
PDF
Nonmetal redox kinetics: reactions of sulfite with dichloramines and trichloramine
Boudin S. Yiin and Dale W. Margerum
pp 1942 - 1948; DOI:
10.1021/ic00335a035
PDF
Pressure effect on the kinetics of the hexaaquairon(II/III) self-exchange reaction in aqueous perchloric acid
William H. Jolley, Donald R. Stranks, and Thomas W. Swaddle
pp 1948 - 1951; DOI:
10.1021/ic00335a036
PDF
Electrochemistry and redox chemistry of aquaferrotungstosilicate, H2OFeIIISiW11O395- in the presence of hydrogen peroxide and hydroxyl
James E. Toth, Jon D. Melton, Diane Cabelli, Benon H. J. Bielski, and Fred C. Anson
pp 1952 - 1957; DOI:
10.1021/ic00335a037
PDF
Multinuclear NMR studies of platinum(IV) complexes. 1. Acid dissociation, anation, and intramolecular catalysis of bipyridyl proton exchange in [aqua(bipyridine) (1,3,5-triaminocyclohexane)platinum(IV)](4+)
Luther E. Erickson, David J. Cook, Gregory D. Evans, Joseph E. Sarneski, Paul J. Okarma, and Anthony D. Sabatelli
pp 1958 - 1967; DOI:
10.1021/ic00335a038
PDF
Ligand design for complexation in aqueous solution. 2. Chelate ring size as a basis for control of size-based selectivity for metal ions
Robert D. Hancock, Peter W. Wade, M. Patrick Ngwenya, Alvaro S. De Sousa, and Kirty V. Damu
pp 1968 - 1974; DOI:
10.1021/ic00335a039
PDF
Electron transfer to ozone: outer-sphere reactivities of the ozone/ozonide and related non-metal redox couples
Larry E. Bennett and Philip Warlop
pp 1975 - 1981; DOI:
10.1021/ic00335a040
PDF
Synthesis and oxidation of two ferrocene-capped cobalt clathrochelates in methylene chloride
Mark A. Murguia, Daniel Borchardt, and Scot Wherland
pp 1982 - 1986; DOI:
10.1021/ic00335a041
PDF
Bimetallic .mu.-oxo complexes formed by coordination of the oxo ligands of Cp2Mo:O and Cp2W:O to rhodium(I) and iridium (I) centers
Robert S. Pilato, David Rubin, Gregory L. Geoffroy, and Arnold L. Rheingold
pp 1986 - 1990; DOI:
10.1021/ic00335a042
PDF
Lead-207 NMR, mass spectrometric, and electrochemical studies on labile lead(II) dithiocarbamate complexes: formation of mixed mercury-lead complexes at a mercury electrode in dichloromethane solution
Alan M. Bond, Ray Colton, and Anthony F. Hollenkamp
pp 1991 - 1995; DOI:
10.1021/ic00335a043
PDF
Influence of porphyrin radical type on vanadium-oxygen double bond strength in vanadyl porphyrin cation radicals: implications for heme protein intermediates
Kathleen A. Macor, Roman S. Czernuszewicz, and Thomas G. Spiro
pp 1996 - 2000; DOI:
10.1021/ic00335a044
PDF
Syntheses and properties of paramagnetic monocyclopentadienylmolybdenum(III) compounds with a four-legged piano-stool structure containing the bidentate bis(diphenylphosphino)ethane ligand
Steven T. Krueger, Beth E. Owens, and Rinaldo Poli
pp 2001 - 2006; DOI:
10.1021/ic00335a045
PDF
Octahedral tantalum and niobium cluster complexes with chloro and trialkylphosphine ligands. Isolation and structure determination of the trans and cis isomers
Hideo Imoto, Seiichiro Hayakawa, Nobutoshi Morita, and Taro Saito
pp 2007 - 2014; DOI:
10.1021/ic00335a046
PDF
Photochemistry of a square-planar cobalt(III) complex
Gyu Hwan Lee, James L. Larson, Thomas A. Perkins, and Kirk S. Schanze
pp 2015 - 2017; DOI:
10.1021/ic00335a047
PDF
Structure and reactivity of a (triphenylsilyl)rhodium(I) compound
David L. Thorn and Richard L. Harlow
pp 2017 - 2019; DOI:
10.1021/ic00335a048
PDF
Epoxidation of alkenes by oxo[5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]chromium(V) in aqueous solution
J. Mark Garrison, Robert W. Lee, and Thomas C. Bruice
pp 2019 - 2021; DOI:
10.1021/ic00335a049
PDF
Crystal structure of [Ru(OEP-N-C6H5)(C6H5)](BF4): an organometallic porphyrin complex containing an N-C6H5 group with an agostic hydrogen
Jeffery W. Seyler, Phillip E. Fanwick, and Charles R. Leidner
pp 2021 - 2023; DOI:
10.1021/ic00335a050
PDF
Synthesis and structure of dicarbonylbis(.eta.-pentamethylcyclopentadienyl)diiridium
R. G. Ball, W. A. G. Graham, D. M. Heinekey, J. K. Hoyano, A. D. McMaster, B. M. Mattson, and S. T. Michel
pp 2023 - 2025; DOI:
10.1021/ic00335a051
PDF
Electrocatalytic dehalogenation of .alpha.-haloacetic acids by vitamin B12
James F. Rusling, Chang Ling Miaw, and Eric C. Couture
pp 2025 - 2027; DOI:
10.1021/ic00335a052
PDF
Preparation, solution dynamics and x-ray crystal structure of the anilide-bridged diruthenium complex [(.eta.6-C6Me6)2Ru2(.mu.-NHPh)3][BF4]
Gaines C. Martin, Gus J. Palenik, and James M. Boncella
pp 2027 - 2030; DOI:
10.1021/ic00335a053
PDF
The layered, metallic scandium iodide Sc0.93I2: synthesis, structure, and properties
B. C. McCollum, D. S. Dudis, A. Lachgar, and John D. Corbett
pp 2030 - 2032; DOI:
10.1021/ic00335a054
PDF
First examples of an isomeric methylene-bridged free phosphinomethylphosphoranimine and a metalated phosphinomethylphosphoranimine. Synthesis, characterization, and isomerization of the heterodifunctional ligand Me3SiN:P(Ph)2CH2PPh2 and the transmetalation to the titanium derivative (.eta.5-C5H5)TiCl2N:P(Ph)2CH2PPh2 [Erratum to document cited in CA110(9):75663s]
Kattesh V. Katti and Ronald G. Cavell
pp 2032 - 2032; DOI:
10.1021/ic00335a055
PDF

Issue 11


Photoinduced oxidative addition to a quadruply bonded tungsten complex bis[bis(diphenylphosphino)methane]tetrachloroditungsten
Colleen M. Partigianoni and Daniel G. Nocera
pp 2033 - 2034; DOI:
10.1021/ic00336a001
PDF
Fluxionality in hexacoordinated copper(II) complexes with 2,2':6',2''-terpyridine (terpy) and related ligands: structural and spectroscopic investigations
Jose Vicente Folgado, Wolfgang Henke, Rudolf Allmann, Horst Stratemeier, Daniel Beltran-Porter, Teofilo Rojo, and Dirk Reinen
pp 2035 - 2042; DOI:
10.1021/ic00336a002
PDF
Structure and magnetic and spectroscopic properties of a nickelIIcopperIInickelII trinuclear species
Juan Ribas, Carmen Diaz, Ramon Costa, Yves Journaux, Corine Mathoniere, Olivier Kahn, and Alain Gleizes
pp 2042 - 2047; DOI:
10.1021/ic00336a003
PDF
Infrared frequencies and intensities of the vibrational modes of alkynes coordinated on metal carbonyl clusters
Pier Luigi Stanghellini and Rosanna Rossetti
pp 2047 - 2052; DOI:
10.1021/ic00336a004
PDF
The chemistry of iron-alkene ions with chlorobenzene
Yongqing Huang and Ben S. Freiser
pp 2052 - 2054; DOI:
10.1021/ic00336a005
PDF
Metal-mediated reduction of alkanenitriles to imido ligands. Formation of the imido complexes Re(NCH2R)X3(dppbe) (R = Me, Et, iso-Pr; X = Cl, Br) from the reactions of the octahalodirhenate(III) anions with 1,2-bis(diphenylphosphino)benzene in nitrile solvents (RCN)
David Esjornson, Mohammed Bakir, Phillip E. Fanwick, Karen S. Jones, and Richard A. Walton
pp 2055 - 2061; DOI:
10.1021/ic00336a006
PDF
Effect of coordinating anions on the kinetics and thermodynamics of oxygen binding by a macrocyclic cobalt(II) complex
Andreja Bakac and James H. Espenson
pp 2062 - 2067; DOI:
10.1021/ic00336a007
PDF
Variable-energy photoelectron spectroscopic comparison of the bonding in ferric sulfide and ferric chloride: an alternative description of the near-IR-visible spin-forbidden transitions in high-spin d5 complexes
Kristine D. Butcher, Matthew S. Gebhard, and Edward I. Solomon
pp 2067 - 2074; DOI:
10.1021/ic00336a008
PDF
Mechanistic information from a volume profile treatment for the complexation of aquocobalamin (vitamin B12a) by pyridine
G. Stochel and R. Van Eldik
pp 2075 - 2077; DOI:
10.1021/ic00336a009
PDF
Diruthenium(III) compounds, Ru2O(O2CAr)2(MeCN)4(PPh3)2(ClO4)2.cntdot.H2O and Ru2O(O2CAr)4(PPh3)2, with an {Ru2(.mu.-O)(.mu.-O2CAr)22+} core as model systems for the diiron centers in hemerythrin
Birinchi K. Das and Akhil R. Chakravarty
pp 2078 - 2083; DOI:
10.1021/ic00336a010
PDF
Molecular architecture of a novel vertex-sharing biicosahedral cluster [(p-Tol3P)10Au13Ag12Br8](PF6) containing a staggered-staggered-staggered configuration for the 25-atom metal framework
Boon K. Teo, Hong Zhang, and Xiaobo Shi
pp 2083 - 2091; DOI:
10.1021/ic00336a011
PDF
Synthesis of technetium(V)-nitrido complexes with chelating amines: a novel class of monocationic, octahedral complexes containing the [Tc.tplbond.N]2+ core. Crystal structures of [TcN(en)2Cl]+ (en = ethylenediamine) and [TcN(tad)Cl]+ (tad = 1,5,8,12-tetraazadodecane)
Andrea Marchi, Patrizia Garuti, Adriano Duatti, Luciano Magon, Roberto Rossi, Valeria Ferretti, and Valerio Bertolasi
pp 2091 - 2096; DOI:
10.1021/ic00336a012
PDF
Crystal structure of head-to-head bis(.mu.-.alpha.-pyridonato-N,O)bis[(ethylenediamine)palladium] nitrate [Pd2(en)2(C5H4NO)2](NO3)2 and carbon-13 and proton-carbon-13 COSY NMR study of head-to-head to head-to-tail isomerization in solution
Kazuko Matsumoto, Hiroshi Moriyama, and Katsuhiko Suzuki
pp 2096 - 2100; DOI:
10.1021/ic00336a013
PDF
Cobalt complexes with bulky perfluorinated alkyl ligands. Synthesis, characterization, and molecular structure of trans-bis(dimethylglyoximato)(pyridine)(F-isopropyl)cobalt(III)
Paul J. Toscano, Holger Brand, Shuncheng Liu, and Jon Zubieta
pp 2101 - 2105; DOI:
10.1021/ic00336a014
PDF
Reduction pathways in lateral and diagonal (.eta.5-C5Me5)Re(CO)2Br2. Synthesis, structure, and reactivity of [(.eta.5-C5Me5)Re(CO)2Br-]
Christine M. Nunn, Alan H. Cowley, Sang Woo Lee, and Michael G. Richmond
pp 2105 - 2112; DOI:
10.1021/ic00336a015
PDF
Synthesis and structural characterization of layered calcium and lanthanide phosphonate salts
Guang Cao, Vincent M. Lynch, J. Steven Swinnea, and Thomas E. Mallouk
pp 2112 - 2117; DOI:
10.1021/ic00336a016
PDF
Electronic structure of (.beta.-diketonato)trimethylplatinum(IV) complexes from UV photoelectron spectra and SCF-MS-X.alpha. calculations
Dong Sheng Yang, G. Michael Bancroft, and Richard J. Puddephatt
pp 2118 - 2122; DOI:
10.1021/ic00336a017
PDF
EPR and ENDOR spectra of copper(II) centers with dz2 and dx2-y2 ground states in barium hexafluorozincate: analysis of hyperfine parameters and dynamic vibronic coupling
Gabriele Steffen, Dirk Reinen, Horst Stratemeier, Mark J. Riley, Michael A. Hitchman, Horst E. Matthies, Kurt Recker, Franz Wallrafen, and Juergen R. Niklas
pp 2123 - 2131; DOI:
10.1021/ic00336a018
PDF
Solvent dependence of ligand to metal charge-transfer oscillator strength: outer-sphere perturbation of the ruthenium(III)-cyanamide bond
Akila A. Saleh and Robert J. Crutchley
pp 2132 - 2135; DOI:
10.1021/ic00336a019
PDF
Non-metal redox kinetics: reactions of trichloramine with ammonia and with dichloramine
Boudin S. Yiin and Dale W. Margerum
pp 2135 - 2141; DOI:
10.1021/ic00336a020
PDF
Influence of symmetry on the vibrational spectra of Zn(TPP), Zn(TPC), and Zn(TPiBC)
Laura A. Andersson, Thomas M. Loehr, Ronald G. Thompson, and Steven H. Strauss
pp 2142 - 2147; DOI:
10.1021/ic00336a021
PDF
The unpredictable structural features of chromium(II) pyrrolyls: synthesis and x-ray structures of monomeric square-planar (.eta.1-2,5-Me2C4H2N)2Cr(py)2, square-pyramidal (.eta.1-C4H4N)2Cr(py)3, dimeric [(7-azaindolyl)2Cr(DMF)]2, and polymeric [(.eta.1-2,5-Me2C4N2)4CrNa2(THF)2(Et2O)]n. An aborted Cr-Cr quadruple bond formation?
Jilles J. H. Edema, Sandro Gambarotta, Auke Meetsma, Fre Van Bolhuis, Anthony L. Spek, and Wilberth J. J. Smeets
pp 2147 - 2153; DOI:
10.1021/ic00336a022
PDF
Crystal structure and reactivity of bis[bis(1,2-dimethylphosphino)ethane]copper(2+) bis(tetracarbonylcobalt)curprate(2-): staggered and eclipsed conformations of [(CO)4CoCuCo(CO)4]- anions
Donald J. Darensbourg, Chi Shan Chao, Joseph H. Reibenspies, and Christopher J. Bischoff
pp 2153 - 2157; DOI:
10.1021/ic00336a023
PDF
Electronic effects of substitution chemistry in the potassium titanyl phosphate (KTiOPO4) structure field: structure and optical properties of potassium vanadyl phosphate
Mark L. F. Phillips, William T. A. Harrison, Thurman E. Gier, Galen D. Stucky, Gururaj V. Kulkarni, and Jeremy K. Burdett
pp 2158 - 2163; DOI:
10.1021/ic00336a024
PDF
Topological aspects of the chemical bonding in superconducting transition-metal borides, silicides, and alloys
R. B. King
pp 2164 - 2170; DOI:
10.1021/ic00336a025
PDF
Spin crossover and light-induced excited-spin-state trapping in bis(thiocyanato)bis(2,2'-bi-2-thiazoline)iron(II) and bis(selenocyanato)bis(2,2'-bi-2-thiazoline)iron(II)
D. C. Figg and R. H. Herber
pp 2170 - 2173; DOI:
10.1021/ic00336a026
PDF
Thermal decomposition of vanadium tetrachloride in hydrocarbon solvents
S. Datta and F. Morrar
pp 2174 - 2176; DOI:
10.1021/ic00336a027
PDF
Proton NMR hyperfine-shifted resonances from the exchange-coupled Fe4S4-siroheme of the assimilatory sulfite reductase from Desulfovibrio vulgaris (Hildenborough)
J. A. Cowan and Marco Sola
pp 2176 - 2179; DOI:
10.1021/ic00336a028
PDF
Unusual synthesis and x-ray structure of cis-dichloro[1,2-bis(o-(diphenylphosphino)phenyl)ethane-1,2-diolato(2-)]technetium(IV) hemiethanol solvate
Fiorenzo Refosco, Giuliano Bandoli, Ulderico Mazzi, Francesco Tisato, Alessandro Dolmella, and Marino Nicolini
pp 2179 - 2180; DOI:
10.1021/ic00336a029
PDF
Reaction of dimethyl sulfide-triborane(7) with trimethylamine. Facile formation of bis(trimethylamine)-diborane(4)
Minoru Ishii and Goji Kodama
pp 2181 - 2183; DOI:
10.1021/ic00336a030
PDF
Unusual isomerization reaction of a platinum-dinucleotide compound
Kenji Inagaki, Maarten Alink, Akinori Nagai, Yoshinori Kidani, and Jan Reedijk
pp 2183 - 2185; DOI:
10.1021/ic00336a031
PDF
Preparation and characterization of trans-bis(.alpha.-dioximato)ruthenium complexes
James G. Muller and Kenneth J. Takeuchi
pp 2185 - 2188; DOI:
10.1021/ic00336a032
PDF

Issue 12


Models for reduced blue copper sites: nearly tetrahedral complexes of copper(I) and silver(I) with a novel N2(imidazole)S*2(thioether)ligand
Spencer Knapp, Terence P. Keenan, Jiangnan Liu, Joseph A. Potenza, and Harvey J. Schugar
pp 2189 - 2191; DOI:
10.1021/ic00337a001
PDF
Preparation and characterization of [closo-1,1,1-(MeCN)3-1,2,4-SrC2B10H12]n; the first structural characterization of a polymeric self-assembling metallacarborane
Rajesh Khattar, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 2191 - 2192; DOI:
10.1021/ic00337a002
PDF
Synthesis, structure, and magnetic properties of a reactive complex containing a nearly linear MnIII-O-MnIII core, bis[N,N-bis(5-nitrosalicylidene)-1,7-diamino-3-azapentanato(2-)]oxodimanganese
Cary A. Kipke, Michael J. Scott, Joel W. Gohdes, and William H. Armstrong
pp 2193 - 2194; DOI:
10.1021/ic00337a003
PDF
Reaction of carbon monoxide in the super acid HSO3F-Au(SO3F)3, and the gold(I)bis(carbonyl)cation [Au(CO)2]+. Isolation and characterization of gold(I) carbonyl fluorosulfate, Au(CO)SO3F
Helge Willner and F. Aubke
pp 2195 - 2200; DOI:
10.1021/ic00337a004
PDF
Effect of solvent on sequential two-electron transfer in bis(1,3,5-triketonato)dicopper(II) complexes
J. K. Zehetmair and R. L. Lintvedt
pp 2201 - 2204; DOI:
10.1021/ic00337a005
PDF
Tetranuclear complexes of 1,3,5,9,11,13-hexaketonates. 1. Synthesis and structure of bis[1,3-bis(2-methyl-4,6,8-octanetrion-8-yl)benzenato(4-)]tetrakis(pyridine)tetracopper(II), Cu4(MOB)2(py)4. Observation of four-electron-transfer electrochemistry
R. L. Lintvedt and J. K. Zehetmair
pp 2204 - 2209; DOI:
10.1021/ic00337a006
PDF
Phosphorus ylides as hard donor ligands: synthesis and characterization of MCl4(ylide-O)(THF) (M = Ti, Zr, Hf; ylide = (acetylmethylene)triphenylphosphorane, (benzoylmethylene)triphenylphosphorane). Molecular structure of trans-((acetylmethylene)triphenylphosphorane-O)(tetrahydrofuran)tetrachlorotitanium-(IV)-tetrahydrofuran
Joseph A. Albanese, Donna L. Staley, Arnold L. Rheingold, and John L. Burmeister
pp 2209 - 2213; DOI:
10.1021/ic00337a007
PDF
Bridgehead-bridgehead communication in untransannulated phosphatrane ZP(ECH2CH2)3N systems
S. K. Xi, H. Schmidt, C. Lensink, S. Kim, D. Wintergrass, L. M. Daniels, R. A. Jacobson, and John G. Verkade
pp 2214 - 2220; DOI:
10.1021/ic00337a008
PDF
Crystal structure, thermal properties, and spectroscopy of (H2Me2pipz)[CuCl3(H2O)]2 (H2Me2pipz = N,N'-dimethylpiperazinium) and (HAmpym)[CuCl3(H2O)] (HAmpym = 2-aminopyrimidinium)
Tiziano Manfredini, Gian Carlo Pellacani, Anna Bonamartini-Corradi, Luigi Pietro Battaglia, Giulio G. T. Guarini, Jolanda Gelsomini Giusti, George Pon, Roger D. Willett, and Douglas X. West
pp 2221 - 2228; DOI:
10.1021/ic00337a009
PDF
Trialkoxysiloxy complexes of nickel. Molecular structures of Na3(.mu.3-I){Ni[.mu.3-OSi(O-tert-Bu)3]3I}.cntdot.0.5THF.cntdot.0.5C5H12 and {(.eta.3-C3H5)Ni[.mu.2-OSi(O-tert-Bu)3]}2
Anne K. McMullen, T. Don Tilley, Arnold L. Rheingold, and Steven J. Geib
pp 2228 - 2232; DOI:
10.1021/ic00337a010
PDF
Synthesis and magnetic properties of binuclear iron(III) complexes with oxalate, 2,5-dihydroxy-1,4-benzoquinone dianion, and squarate as bridging ligands. Crystal structure of (.mu.-1,3-squarato)bis[(N,N'-ethylenebis(salicylideneaminato))(methanol)iron(III)]
Francesc Lloret, Miguel Julve, Juan Faus, Xavier Solans, Yves Journaux, and Irene Morgenstern-Badarau
pp 2232 - 2237; DOI:
10.1021/ic00337a011
PDF
Synthesis and electrochemical characterization of binuclear rhodium and ruthenium complexes with 1,8-naphthyridine-2,7-dicarboxylate. X-ray molecular structure of tris(.mu.-acetato)(1,8-naphthyridine-2,7-dicarboxylato)diruthenium
Jean Paul Collin, Abdelaziz Jouaiti, Jean Pierre Sauvage, William C. Kaska, Margaret A. McLoughlin, Nancy L. Keder, William T. A. Harrison, and Galen D. Stucky
pp 2238 - 2241; DOI:
10.1021/ic00337a012
PDF
Revision of the structure of zirconium triiodide. The presence of metal dimers
Abdessadek Lachgar, Douglas S. Dudis, and John D. Corbett
pp 2242 - 2246; DOI:
10.1021/ic00337a013
PDF
Encapsulation of the platinum and neighboring metals within cluster iodides of rare-earth elements
Martin W. Payne and John D. Corbett
pp 2246 - 2251; DOI:
10.1021/ic00337a014
PDF
Importance of the X4 ring orbitals for the semiconducting, metallic, or superconducting properties of skutterudites MX3 and RM4X12
Dongwoon Jung, Myung Hwan Whangbo, and Santiago Alvarez
pp 2252 - 2255; DOI:
10.1021/ic00337a015
PDF
Band electronic structure study of the structural modulation in the Magneli phase molybdenum oxides, Mo8O23
Enric Canadell and Myung Hwan Whangbo
pp 2256 - 2260; DOI:
10.1021/ic00337a016
PDF
Synthesis and characterization of mononuclear oxomolybdenum(V) complexes with aliphatic diolato, dithiolato, or alkoxo ligands: effect of chelate ring size on the properties of the metal center
C. S. J. Chang, D. Collison, F. E. Mabbs, and J. H. Enemark
pp 2261 - 2267; DOI:
10.1021/ic00337a017
PDF
Interactions of vanadate with mono- and dicarboxylic acids
Alan S. Tracey, Huali Li, and Michael J. Gresser
pp 2267 - 2271; DOI:
10.1021/ic00337a018
PDF
Cobalt(II)-substituted Limulus polyphemus hemocyanin: cobalt equilibria, ligand binding, and oxygenation chemistry
T. J. Dutton, T. F. Baumann, and J. A. Larrabee
pp 2272 - 2278; DOI:
10.1021/ic00337a019
PDF
Spectral properties of cis- and trans-metallooctaethylchlorins: effects of pyrroline ring stereochemistry and macrocyclic conformation
Laura A. Andersson, Thomas M. Loehr, Matthew T. Stershic, and Alan M. Stolzenberg
pp 2278 - 2285; DOI:
10.1021/ic00337a020
PDF
Synthetic control of excited-state properties in ligand-bridged complexes of rhenium(I). Intramolecular energy transfer by an electron-transfer/energy-transfer cascade
Gilles Tapolsky, Rich Duesing, and Thomas J. Meyer
pp 2285 - 2297; DOI:
10.1021/ic00337a021
PDF
Chiral induction in electron-transfer reactions of iron(II) and iron(III) bis(oxime-imine) complexes
Rosemary A. Marusak, Christopher Sharp, and A. Graham Lappin
pp 2298 - 2302; DOI:
10.1021/ic00337a022
PDF
Molecular orbital investigation of the oxidation of olefins by cis- and trans-ruthenium(VI)-dioxo complexes
Thomas R. Cundari and Russell S. Drago
pp 2303 - 2308; DOI:
10.1021/ic00337a023
PDF
Luminescence from diplatinum(III) tetraphosphate complexes: dynamics of emissive d.sigma.* excited states
Yeung Gyo K. Shin, Vincent M. Miskowski, and Daniel G. Nocera
pp 2308 - 2313; DOI:
10.1021/ic00337a024
PDF
Competitive hydrogen production and emission through the photochemistry of mixed-metal bimetallic complexes
D. Brent MacQueen and John D. Petersen
pp 2313 - 2320; DOI:
10.1021/ic00337a025
PDF
Synthesis, characterization, and EPR studies of stable ruthenium(III) Schiff base chloro and carbonyl complexes
M. M. Taqui Khan, D. Srinivas, R. I. Kureshy, and N. H. Khan
pp 2320 - 2326; DOI:
10.1021/ic00337a026
PDF
Bimetallic complexes of rhenium(I). Preparation of Re(BL)(CO)3Cl and [Re(CO)3Cl]2(BL) (BL = 2,3-bis(2-pyridyl)pyrazine, 2,3-bis(2-pyridyl)quinoxaline, and 2,3-bis(2-pyridyl)benzo[g]quinoxaline)
John A. Baiano, David L. Carlson, Glenn M. Wolosh, Doris E. DeJesus, Carla F. Knowles, Edith G. Szabo, and W. Rorer Murphy
pp 2327 - 2332; DOI:
10.1021/ic00337a027
PDF
Hydrogen transfer from dicarbonyl(cyclopentadienyl)dihydridorhenium to trans carbonylchlorobis(triphenylphosphine)iridium via a heterobimetallic Re-Ir intermediate
Charles P. Casey and Edward W. Rutter
pp 2333 - 2335; DOI:
10.1021/ic00337a028
PDF
Ruthenium carbonyl 1,4-diaza-1,3-butadienes (R-DAB) complexes. 10. Facile preparation of Ru(CO)3(R-DAB) and its relation to the reversible carbon-carbon bond formation and fission between two R-DAB ligands on a diruthenium fragment
Wilhelmus P. Mul, Cornelis J. Elsevier, Hans Werner Fruhauf, Kees Vrieze, Ingrid Pein, Martin C. Zoutberg, and Casper H. Stam
pp 2336 - 2345; DOI:
10.1021/ic00337a029
PDF
Niobotungstate, Nb2W4O194- and triphosphate, P3O93-, complexes of (cyclooctadiene)iridium(I): synthesis, structure, and stability of tetra-n-butylammonium salts of {[(C8H12)Ir]5(Nb2W4O19)2}3-, {[(C8H12)Ir]2H(Nb2W4O19)2}5-, and [(C8H12)Ir(P3O9)]2-
V. W. Day, W. G. Klemperer, and D. J. Main
pp 2345 - 2355; DOI:
10.1021/ic00337a030
PDF
Polyoxoanion-supported metal carbonyls: synthesis and characterization of {[(OC)2Rh]5(Nb2W4O19)2}3-, {[(OC)2Rh]3(Nb2W4O19)2}5-, {[(OC)2Ir]2H(Nb2W4O19)2}5-, and [(OC)2Ir(P3O9)]2-
W. G. Klemperer and D. J. Main
pp 2355 - 2360; DOI:
10.1021/ic00337a031
PDF
Chemistry of sulfur halides. 36. Preparation of S7X+MF6- (X = F, Cl; M = As, Sb) and vibrational spectra of the series S7X+ (X = F, Cl, Br, I)
Rolf Minkwitz and Joachim Nowicki
pp 2361 - 2364; DOI:
10.1021/ic00337a032
PDF
Synthesis and structural characterization of metallacarborane poly(pyrazolyl)borate complexes
David M. Schubert, Carolyn B. Knobler, Swiatoslaw Trofimenko, and M. Frederick Hawthorne
pp 2364 - 2369; DOI:
10.1021/ic00337a033
PDF
Linear oligophosphaalkanes. 23. Novel copper(I) complexes with electron-deficient triply bridging secondary phosphido groups .mu.3-PRR' (R = isopropyl, tert-butyl, R' = CH2-P R2; R = R' = phenyl)
David J. Brauer, Gisbert Hessler, Peter C. Knueppel, and Othmar Stelzer
pp 2370 - 2375; DOI:
10.1021/ic00337a034
PDF
Interaction of triruthenium dodecacarbonyl with silanols and silanolate groups. X-ray crystal structure analysis of (.mu.-H)Ru3(CO)10(.mu.-OSiEt3), a molecular analogue of a silica-supported metal cluster
Jose Puga, Thomas P. Fehlner, Bruce C. Gates, Dario Braga, and Fabrizia Grepioni
pp 2376 - 2381; DOI:
10.1021/ic00337a035
PDF
Solvent, anion, and temperature dependences of the ruthenocene(II)/bromoruthenocene(IV) and ruthenocene(II)/iodoruthenocene(IV) electron exchange
Karl Kirchner, Harold W. Dodgen, Scot Wherland, and John P. Hunt
pp 2381 - 2385; DOI:
10.1021/ic00337a036
PDF
Conversion of an SF5 group into an F2S(O): substituent by a novel elimination-rearrangement sequence
R. Winter and G. L. Gard
pp 2386 - 2387; DOI:
10.1021/ic00337a037
PDF
The vanadium-vanadium double bond in bis(butanediyl)bis(cyclopentadienyl)divanadium: an antiferromagnetic coupling. An ab initio SCF/CI study
Charles Poumbga, Chantal Daniel, and Marc Benard
pp 2387 - 2389; DOI:
10.1021/ic00337a038
PDF
Vibrational spectra of carboxylate complexes. Part 8. Valence localization in triangular trimanganese(II, 2III) complexes
Ladda Meesuk, Ross P. White, Barry Templeton, Upali A. Jayasooriya, and Roderick D. Cannon
pp 2389 - 2392; DOI:
10.1021/ic00337a039
PDF

Issue 13


New route to layered double hydroxides intercalated by organic anions: precursors to polyoxometalate-pillared derivatives
Emmanuel D. Dimotakis and Thomas J. Pinnavaia
pp 2393 - 2394; DOI:
10.1021/ic00338a001
PDF
Switching between solid-state electroactivity, coupled with ionic conductivity, and semiconducting or dielectric properties in dry mixed-metal hexacyanoferrate powders
Pawel J. Kulesza
pp 2395 - 2397; DOI:
10.1021/ic00338a002
PDF
Nigericin-mediated transport of cesium ions through phospholipid bilayers studied by a cesium-133 magnetization-transfer NMR technique
Frank G. Riddell, S. Arumugam, and Ayyub Patel
pp 2397 - 2398; DOI:
10.1021/ic00338a003
PDF
Investigation of copper-zinc superoxide dismutase Ser-137 and Ala-137 mutants
Lucia Banci, Ivano Bertini, Diane Cabelli, Robert A. Hallewell, Claudio Luchinat, and Maria Silvia Viezzoli
pp 2398 - 2403; DOI:
10.1021/ic00338a004
PDF
Intramolecular binding of nitrogen bases to a cofacial binuclear copper(II) complex
Andrew W. Maverick, Michael L. Ivie, John H. Waggenspack, and Frank R. Fronczek
pp 2403 - 2409; DOI:
10.1021/ic00338a005
PDF
Hydrolysis of phosphodiesters with nickel(II), copper(II), zinc(II), palladium(II), and platinum(II) complexes
Mark A. De Rosch and William C. Trogler
pp 2409 - 2416; DOI:
10.1021/ic00338a006
PDF
Base binding to zinc picket fence porphyrins. Attractive intramolecular interactions in organic solvents
Hiroyasu Imai and Eishin Kyuno
pp 2416 - 2422; DOI:
10.1021/ic00338a007
PDF
A family of mononuclear manganese(IV) complexes: an MnIVO4N2 sphere assembled via phenolate-imine-carboxylate coordination
Swapan Kumar Chandra, Partha Basu, Debashis Ray, Samudranil Pal, and Animesh Chakravorty
pp 2423 - 2428; DOI:
10.1021/ic00338a008
PDF
Neutral, seven-coordinate dioxime complexes of technetium(III): synthesis and characterization
Karen E. Linder, Mary F. Malley, Jack Z. Gougoutas, Steve E. Unger, and Adrian D. Nunn
pp 2428 - 2434; DOI:
10.1021/ic00338a009
PDF
Syntheses and characterization of binuclear manganese(III,IV) and -(IV,IV) complexes with ligands related to tris(2-pyridylmethyl)amine
Aderemi R. Oki, Joergen Glerup, and Derek J. Hodgson
pp 2435 - 2441; DOI:
10.1021/ic00338a010
PDF
Structure and spectroscopic properties of five-coordinate (2-methylimidazolato)- and six-coordinate (imidazole)(imidazolato)iron(II) "picket-fence" porphyrins
D. Mandon, F. Ott-Woelfel, J. Fischer, R. Weiss, E. Bill, and A. X. Trautwein
pp 2442 - 2447; DOI:
10.1021/ic00338a011
PDF
Structural characterization and magnetic study (EPR and static susceptibility measurements) of a novel ferric spin-crossover complex: bis(7-amino-4-methyl-5-aza-3-hepten-2-onato(1-))iron(III) tetraphenylborate
Jean Pierre Costes, Francoise Dahan, and Jean Pierre Laurent
pp 2448 - 2452; DOI:
10.1021/ic00338a012
PDF
(Tris-(3-tert-butylpyrazolyl)hydroborato)manganese(II), -iron(II), -cobalt(II), and -nickel(II) halide derivatives: facile abstraction of fluoride from tetrafluoroborate(1-)
Ian B. Gorrell and Gerard Parkin
pp 2452 - 2456; DOI:
10.1021/ic00338a013
PDF
Multielectron transfer and single-crystal x-ray structure of a trinuclear cyanide-bridged platinum-iron species
Meisheng Zhou, Brian W. Pfennig, Jana Steiger, Donna Van Engen, and Andrew B. Bocarsly
pp 2456 - 2460; DOI:
10.1021/ic00338a014
PDF
Inner- and outer-sphere complex formation in aqueous erbium halide and perchlorate solutions. An x-ray diffraction study using isostructural substitution
Georg Johansson and Haruhiko Yokoyama
pp 2460 - 2466; DOI:
10.1021/ic00338a015
PDF
Bonding in the two-dimensional copper-gallium layer of a calcium copper gallium, Ca2Cu2Ga, crystal
Christian Kollmar and Roald Hoffmann
pp 2466 - 2475; DOI:
10.1021/ic00338a016
PDF
Direct electrochemical synthesis of copper and silver derivatives of alkanedithiols and crystal structure of [Cu2S2C3H6-1,2.cntdot.(C6H5)2PCH2P(C6H5)2]4.cntdot.4CH3CN
Theodore A. Annan, Rajesh Kumar, and Dennis G. Tuck
pp 2475 - 2479; DOI:
10.1021/ic00338a017
PDF
Oxidation of cobalt(II) macrocycles by tris(bipyridyl)ruthenium(III) ions
Shaoyung Lee, Andreja Bakac, and James H. Espenson
pp 2480 - 2482; DOI:
10.1021/ic00338a018
PDF
Theoretical study of the intramolecular cis-trans isomerization mechanism in the chromium carbonyl complex, Cr(CO)5X (X = carbonyl, phosphine, triphenylphosphine)
Lillian M. Hansen and Dennis S. Marynick
pp 2482 - 2486; DOI:
10.1021/ic00338a019
PDF
Electronic structure of cis-dimethylplatinum(II) complexes from UV photoelectron spectra and SCF-MS-X.alpha. calculations
Dong Sheng Yang, G. Michael Bancroft, Lisa Dignard-Bailey, Richard J. Puddephatt, and John S. Tse
pp 2487 - 2495; DOI:
10.1021/ic00338a020
PDF
Electronic structure of square-planar cis-bis(trifluoromethyl)platinum(II) complexes from UV photoelectron spectra and SCF-MS-X.alpha. calculations
Dong Sheng Yang, G. Michael Bancroft, R. J. Puddephatt, and John S. Tse
pp 2496 - 2501; DOI:
10.1021/ic00338a021
PDF
The emission spectrum of ruthenocene: calculation of the excited-state distortions and the spacings in the repetitive pattern
Gary J. Hollingsworth, Kyeong Sook Kim Shin, and Jeffrey I. Zink
pp 2501 - 2506; DOI:
10.1021/ic00338a022
PDF
Assignments of ground- and excited-state spectra from time-resolved absorption and circular dichroism measurements of the 2E state of (.DELTA.)-tris(2,2'-bipyridine)chromium(3+)
Steven J. Milder, Jon S. Gold, and David S. Kliger
pp 2506 - 2511; DOI:
10.1021/ic00338a023
PDF
Low-temperature precursor synthesis of crystalline nickel disulfide
Philippe R. Bonneau, Robert K. Shibao, and Richard B. Kaner
pp 2511 - 2514; DOI:
10.1021/ic00338a024
PDF
The first second-row triketone complex structure: synthesis and properties of a substituted (1,3,5-pentanetrionato) (.mu.-oxo)bis(dioxomolybdenum(VI))
Londa L. Borer and Ekkehard Sinn
pp 2514 - 2518; DOI:
10.1021/ic00338a025
PDF
Synthesis and structure of dimeric metal complexes with N(3)/N(9)-chelating hypoxanthine ligands and with bridging water molecules: [M2(.mu.-hyxan)2(SO4)2(.mu.-H2O)2(H2O)2] (M = copper, cadmium, zinc; hyxan = hypoxanthine)
Erich Dubler, Gaby Haenggi, and Helmut Schmalle
pp 2518 - 2523; DOI:
10.1021/ic00338a026
PDF
Synthesis and structural characterization of a neutral lacunar complex formed by deprotonation of methyl groups of the cyclidene macrocycle
Kenneth A. Goldsby, Alan J. Jircitano, Dennis L. Nosco, James C. Stevens, and Daryle H. Busch
pp 2523 - 2527; DOI:
10.1021/ic00338a027
PDF
Synthesis and characterization of new cobalt dioxygen carriers based on a familiar macrocyclic ligand
Sharlene J. Dzugan and Daryle H. Busch
pp 2528 - 2532; DOI:
10.1021/ic00338a028
PDF
Disulfur and diselenium titanium(IV) porphyrins: synthesis and characterization of (P)Ti(.eta.2-S2) and (P)Ti(.eta.2-Se2), where P is one of several different porphyrin rings. Crystal structure of (5,10,15,20-tetra-p-tolylporphinato)perthiotitanium(IV)
R. Guilard, C. Ratti, A. Tabard, P. Richard, D. Dubois, and K. M. Kadish
pp 2532 - 2540; DOI:
10.1021/ic00338a029
PDF
cis-{[(NH3)2Pt(1-MeU)2Pt(bpy)]2}(NO3)5.cntdot.mHNO3.nH2O, a Pt(2.25) blue derived from a dinuclear, mixed-amine complex of 1-methyluracil (1-MeUH). Characterization of the cation, analytical evaluation of cocrystallized HNO3, and x-ray structure of its reduced [Pt2.0]2 form
Gabriele Troetscher, Wolfgang Micklitz, Helmut Schoellhorn, Ulf Thewalt, and Bernhard Lippert
pp 2541 - 2547; DOI:
10.1021/ic00338a030
PDF
Homogeneous catalytic reduction of nitric oxide by olefins in the presence of palladium(II) chloride
C. H. Cheng and K. S. Sun
pp 2547 - 2548; DOI:
10.1021/ic00338a031
PDF

Issue 14


A trinuclear copper(I) complex: reaction with dioxygen and the formation of a hexanuclear copper(II) cluster
Kenneth D. Karlin, Qing Fen Gan, Amjad Farooq, Shuncheng Liu, and Jon Zubieta
pp 2549 - 2551; DOI:
10.1021/ic00339a001
PDF
Synthesis and spectroscopic characterization of bis[bis(bipyridine)ruthenium(II)]-3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl and its redox products
Pamela R. Auburn and A. B. P. Lever
pp 2551 - 2553; DOI:
10.1021/ic00339a002
PDF
Alkane functionalization by nonporphyrin iron complexes: mechanistic insights
Randolph A. Leising, Richard E. Norman, and Lawrence Que
pp 2553 - 2555; DOI:
10.1021/ic00339a003
PDF
A new ambient-pressure organic superconductor, .kappa.-(ET)2Cu[N(CN)2]Br, with the highest transition temperature yet observed (inductive onset Tc = 11.6 K, resistive onset = 12.5 K)
Aravinda M. Kini, Urs Geiser, Hau H. Wang, K. Douglas Carlson, Jack M. Williams, W. K. Kwok, K. G. Vandervoort, James E. Thompson, Daniel L. Stupka, and et al.
pp 2555 - 2557; DOI:
10.1021/ic00339a004
PDF
Reductive alkylation of cobalt(III) porphyrin by tetraalkyltin compounds and alkylcobalt(III) complexes
Shunichi Fukuzumi and Toshiaki Kitano
pp 2558 - 2559; DOI:
10.1021/ic00339a005
PDF
Facile .alpha./.beta. diastereomerism in (2,2,2-trifluoroethyl)cobalt corrins
Kenneth L. Brown and Daniel R. Evans
pp 2559 - 2561; DOI:
10.1021/ic00339a006
PDF
Sulfur L-edge XANES study of zinc-, cadmium-, and mercury-containing metallothionein and model compounds
Wuhua Lu, Masoud Kasrai, G. Michael Bancroft, Martin J. Stillman, and K. H. Tan
pp 2561 - 2563; DOI:
10.1021/ic00339a007
PDF
Kinetics of complexation of aquated (diethylenetriamine)platinum(II) with inosine and 1-methylinosine as a function of pH
Jorma Arpalahti and Pertti Lehikoinen
pp 2564 - 2567; DOI:
10.1021/ic00339a008
PDF
Bonding in crystals containing one-dimensional bridged and unbridged group 11 and 12 linear, zigzag and helical chains
C. X. Cui and Miklos Kertesz
pp 2568 - 2575; DOI:
10.1021/ic00339a009
PDF
Pentaammineruthenium(III) phenylcyanamide complexes: crystal structure determination and the dependence of b1*.rarw. b1 LMCT oscillator strength on the nature of the phenylcyanamide ligand
Robert J. Crutchley, Kierstan McCaw, Florence L. Lee, and Eric J. Gabe
pp 2576 - 2581; DOI:
10.1021/ic00339a010
PDF
Structure and magnetic properties of ferromagnetic alternating spin chains
Carmen I. Cabello, Andrea Caneschi, Richard L. Carlin, Dante Gatteschi, Paul Rey, and Roberta Sessoli
pp 2582 - 2587; DOI:
10.1021/ic00339a011
PDF
Chemistry of sulfur-halogen compounds. 37. Synthesis of CF3SSI, vibrational analyses for (trifluoromethyl)disulfanes CF3SSX (X = F, Cl, Br, I, and H), and gas-phase structures of CF3SSF and CF3SSH
Rolf Minkwitz, Reinhard Lekies, Dirk Lennhoff, Juergen Sawatzki, Johannes Kadel, and Heinz Oberhammer
pp 2587 - 2590; DOI:
10.1021/ic00339a012
PDF
An unusual ternary chloride of tin and tantalum, Sn[Ta2Cl9]2
F. Albert Cotton, Elizabeth Babaian-Kibala, Larry R. Falvello, and Maoyu Shang
pp 2591 - 2593; DOI:
10.1021/ic00339a013
PDF
Structures of Mo2(CH3)4(PR3)4 molecules: constancy of covalent radius of molybdenum in these and other Mo2X4(PR3)4 molecules
F. Albert Cotton and Kenneth J. Wiesinger
pp 2594 - 2599; DOI:
10.1021/ic00339a014
PDF
Transition-metal complexes of superstructured cyclidene macrobicycles: structural features and their chemical consequences. 3. Cyclidenes with long polymethylene bridges
Nathaniel W. Alcock, Peter A. Padolik, Graham A. Pike, Masaaki Kojima, Colin J. Cairns, and Daryle H. Busch
pp 2599 - 2607; DOI:
10.1021/ic00339a015
PDF
Synthesis of mono- and diphosphorus phosphazane oligomer/polymer precursors
Elizabeth G. Bent, Riley Schaeffer, R. Curtis Haltiwanger, and Arlan D. Norman
pp 2608 - 2613; DOI:
10.1021/ic00339a016
PDF
New niobium complexes with alkynes. 3. An extraordinary hexaniobium compound containing a central Nb3 cluster and three outer Nb atoms bound to .eta.4-tetraphenylcyclobutadiene ligands
F. Albert Cotton and Maoyu Shang
pp 2614 - 2618; DOI:
10.1021/ic00339a017
PDF
New niobium complexes with alkynes. 4. A compound containing both an oxo-centered tetrameric anion and a related dinuclear cation
F. Albert Cotton and Maoyu Shang
pp 2619 - 2622; DOI:
10.1021/ic00339a018
PDF
Highly active antitumor platinum(II) complexes of amino sugars
Taro Tsubomura, Masumi Ogawa, Shigenobu Yano, Kimiko Kobayashi, Tosio Sakurai, and Sadao Yoshikawa
pp 2622 - 2626; DOI:
10.1021/ic00339a019
PDF
Electron-transfer properties of potassium tetrachloroaurate(III), gold(I) trialkylphosphine, and gold(I) trialkyl phosphite complexes in nonaqueous media
J. E. Anderson, S. M. Sawtelle, and C. E. McAndrews
pp 2627 - 2633; DOI:
10.1021/ic00339a020
PDF
Factors affecting the iron-oxygen vibrations of ferrous oxy and ferryl oxo heme proteins and model compounds
W. Anthony Oertling, Robert T. Kean, Ron Wever, and Gerald T. Babcock
pp 2633 - 2645; DOI:
10.1021/ic00339a021
PDF
Redox chemistry of iron picolinate complexes and of their hydrogen peroxide and dioxygen adducts
Pablo Cofre, Silvia A. Richert, Andrzej Sobkowiak, and Donald T. Sawyer
pp 2645 - 2651; DOI:
10.1021/ic00339a022
PDF
Laser-induced europium(III) luminescence and NMR spectroscopic characterization of macrocyclic diaza crown ether complexes containing carboxylate ligating groups
Richard C. Holz, Scott L. Klakamp, C. Allen Chang, and William D. Horrocks
pp 2651 - 2658; DOI:
10.1021/ic00339a023
PDF
The addition of phosphazenocuprates to aldehydes and ketones: a new route to gem-organo-substituted cyclotriphosphazenes
Pieter L. Buwalda, Andre Steenbergen, Gerard E. Oosting, and Johan C. Van de Grampel
pp 2658 - 2663; DOI:
10.1021/ic00339a024
PDF
Cytochrome c oxidase models: iron(III) porphyrin-copper(II) complexes with sulfur bridges
Barbara R. Serr, Christine E. L. Headford, Oren P. Anderson, C. Michael Elliott, Cynthia K. Schauer, Kozo Akabori, Kevork Spartalian, William E. Hatfield, and Brian R. Rohrs
pp 2663 - 2671; DOI:
10.1021/ic00339a025
PDF
Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 3. Synthesis and complexation studies of ten-membered-ring trithioethers
William N. Setzer, Elizabeth L. Cacioppo, Qin Guo, Gregory J. Grant, David D. Kim, John L. Hubbard, and Donald G. VanDerveer
pp 2672 - 2681; DOI:
10.1021/ic00339a026
PDF
Synthesis and spectral characterization of dinuclear palladium(I) phenoxides and the crystal structure of Pd2(dppm)2(OCOCF3)2
Terry E. Krafft, Carolyn I. Hejna, and Joanne S. Smith
pp 2682 - 2688; DOI:
10.1021/ic00339a027
PDF
Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles
Soonheum Park, Marie Pontier-Johnson, and D. Max Roundhill
pp 2689 - 2697; DOI:
10.1021/ic00339a028
PDF
Fluorine-19 NMR chemical shift of sulfur difluoride in the gas phase
Willy Gombler, Joerg Schaebs, and Helge Willner
pp 2697 - 2698; DOI:
10.1021/ic00339a029
PDF
Synthesis and spectroscopic characterization of 1,2-bis(trimethylsilyl)-1,2-dicarba-closo-hexaborane(6) derived from closo-stannacarborane and the x-ray crystal structure of the precursor 1-Sn-2,3-[Si(CH3)3]2-2,3-C2B4H4
Narayan S. Hosmane, Reynaldo D. Barreto, Michael A. Tolle, John J. Alexander, William Quintana, Upali Siriwardane, Sheldon G. Shore, and Robert E. Williams
pp 2698 - 2701; DOI:
10.1021/ic00339a030
PDF
Synthetic, electrochemical and structural studies of monoalkyne complexes of molybdenum(II) and tungsten(II)
Brian J. Brisdon, Annabelle G. W. Hodson, Mary F. Mahon, Kieran C. Molloy, and Richard A. Walton
pp 2701 - 2704; DOI:
10.1021/ic00339a031
PDF

Issue 15


Synthesis and characterizations of two novel heterometallic trinuclear incomplete cubane-like clusters [(Et)4N]{M2CuS4}(S2C2H4)2(PPh3) (M = Mo, W)
Nianyong Zhu, Yifan Zheng, and Xintao Wu
pp 2705 - 2707; DOI:
10.1021/ic00340a001
PDF
Facile synthesis and structural principles of the strontium phenoxide Sr4(OPh)8(PhOH)2(THF)6
Simon R. Drake, William E. Streib, Malcolm H. Chisholm, and Kenneth G. Caulton
pp 2707 - 2708; DOI:
10.1021/ic00340a002
PDF
Hydrolysis and dimerization of nitrile to diacetamide and crystal structures of chloro(2,2,2,2',2',2'-hexachlorodiacetamido)(dimethyl sulfoxide)platinum(II) and cis-aquadichloro(dimethyl sulfoxide)platinum(II)
F. D. Rochon, P. C. Kong, and R. Melanson
pp 2708 - 2712; DOI:
10.1021/ic00340a003
PDF
Crystal structures and magnetic behavior of two novel copper(II) halide chains. (C7H10N)4Cu5Cl14 and (C5H14N)4Cu5Cl14: multiple copper(II) halide coordination geometries
Marcus R. Bond, Roger D. Willett, and Gerald V. Rubenacker
pp 2713 - 2720; DOI:
10.1021/ic00340a004
PDF
Isolation of chromium(0) thiols: molecular structure of (tert-butylmercaptan)pentacarbonylchromium
Marcetta Y. Darensbourg, Elizabeth M. Longridge, Vilia Payne, Joseph Reibenspies, Charles G. Riordan, Jerry J. Springs, and Joseph C. Calabrese
pp 2721 - 2726; DOI:
10.1021/ic00340a005
PDF
Electrochemical oxidative addition involving dirhodium(I) complexes containing transoid bridging bis(diphenylphosphino)methane ligands. Crystal structure of a dirhodium(II) complex with an unusual folding of the diphosphine ligand
Louis J. Tortorelli, Clifton Woods, and Andrew T. McPhail
pp 2726 - 2733; DOI:
10.1021/ic00340a006
PDF
Structural studies of metalloporphyrins. 9. "Looping-over" cobalt porphyrins: coordinating properties and application to dioxygen fixation and activation
L. Salmon, C. Bied-Charreton, A. Gaudemer, P. Moisy, F. Bedioui, and J. Devynck
pp 2734 - 2740; DOI:
10.1021/ic00340a007
PDF
Six-coordinate quantum-mechanically weakley spin-mixed (S = 5/2, 3/2) (triflato)aquoiron(III) "picket-fence" porphyrin complex: synthesis and structural, Moessbauer, EPR, and magnetic characterization
A. Gismelseed, E. L. Bominaar, E. Bill, A. X. Trautwein, H. Winkler, H. Nasri, P. Doppelt, D. Mandon, J. Fischer, and R. Weiss
pp 2741 - 2749; DOI:
10.1021/ic00340a008
PDF
Electrochemistry, spectroscopy, and reactivity of (meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(III,II,I) in nonaqueous media
C. Araullo-McAdams and K. M. Kadish
pp 2749 - 2757; DOI:
10.1021/ic00340a009
PDF
Non-metal redox kinetics: hypochlorite and hypochlorous acid reactions with cyanide
Cynthia M. Gerritsen and Dale W. Margerum
pp 2757 - 2762; DOI:
10.1021/ic00340a010
PDF
Redox behavior of nitro substituents of cage complexes
Peter A. Lay and Alan M. Sargeson
pp 2762 - 2770; DOI:
10.1021/ic00340a011
PDF
Selenium-77 NMR spectroscopic study of fluxional selenium sulfide 1,2,3,4,5-Se5S2
Pentti Pekonen, Yrjo Hiltunen, Risto S. Laitinen, and Tapani A. Pakkanen
pp 2770 - 2773; DOI:
10.1021/ic00340a012
PDF
Matrix infrared spectra of the products from photochemical reactions of tetraphosphorus with ozone and decomposition of tetraphosphorus hexoxide
Zofia Mielke and Lester Andrews
pp 2773 - 2779; DOI:
10.1021/ic00340a013
PDF
Free energies of electron attachment to tris(acetylacetonate) and tris(hexafluoroacetylacetonate) transition-metal complexes in the gas phase: experimental results and ligand field analysis
Paul Sharpe, John R. Eyler, and David E. Richardson
pp 2779 - 2787; DOI:
10.1021/ic00340a014
PDF
Testing the T1 method: a comparison of T1(min) and structural data
Xiao Liang Luo and Robert H. Crabtree
pp 2788 - 2791; DOI:
10.1021/ic00340a015
PDF
Synthesis and characterization of a new family of luminescent cis-(4,4'-X2-5,5'-Y2-2,2'-bipyridine)2Os(CO)Cl(PF6) complexes (X = NEt2, OMe, Me, H, Cl, Y = H; X = H, Y = Me; X = Y = Me): control of excited-state properties by bipyridyl substituents
Leopoldo Della Ciana, Walter J. Dressick, Diana Sandrini, Mauro Maestri, and Mauro Ciano
pp 2792 - 2798; DOI:
10.1021/ic00340a016
PDF
Photophysical studies of copper phenanthrolines bound to DNA
Ramasamy Tamilarasan and David R. McMillin
pp 2798 - 2802; DOI:
10.1021/ic00340a017
PDF
Spectrophotometric and resonance Raman studies on the formation of phenolate and thiolate complexes of (octaethylporphinato)iron(III)
Tadayuki Uno, Keiichiro Hatano, Yoshifumi Nishimura, and Yoji Arata
pp 2803 - 2807; DOI:
10.1021/ic00340a018
PDF
Direct and superexchange electron tunneling at the adjacent and remote sites of higher plant plastocyanins
Hans E. M. Christensen, Lars S. Conrad, Kurt V. Mikkelsen, Martin K. Nielsen, and Jens Ulstrup
pp 2808 - 2816; DOI:
10.1021/ic00340a019
PDF
Bimetallic oxidation catalysts. Synthesis, x-ray analysis, and reactivity of a binuclear p-hydroquinone-containing copper(II) complex
Onko Jan Gelling, Auke Meetsma, and Ben L. Feringa
pp 2816 - 2822; DOI:
10.1021/ic00340a020
PDF
Tetraazamacrocycle functionalized with pendant pyrazole groups: synthesis of the octadentate ligand 1,4,7,10-tetrakis(1-pyrazolylmethyl)-1,4,7,10-tetraazacyclododecane (L) and its transformation to the ligand 1,4,7-tris(1-pyrazolylmethyl)-10-((ethyloxy)methyl)-1,4,7,10-tetraazacyclododecane (L'). Structural characterizations of the complexes [NiL]I2, [NiL'](BPh4)2.cntdot.2(CH3)2CO, and [ZnL'](BPh4)2.cntdot.(CH3)2CO
Guia De Martino Norante, Massimo Di Vaira, Fabrizio Mani, Stefania Mazzi, and Piero Stoppioni
pp 2822 - 2829; DOI:
10.1021/ic00340a021
PDF
Synthesis, structure, and reactivity of the nickel(II) complex of 7-aza-1,4-dithiacyclononane
A. McAuley and S. Subramanian
pp 2830 - 2837; DOI:
10.1021/ic00340a022
PDF
Novel Cu6O15 "bowls" in seven new barium copper oxides: metal barium copper oxide (M6Ba46Cu24O84) (M = aluminum, silicon, titanium, iron, gallium, germanium, zirconium)
Paul D. VerNooy, Michael A. Dixon, Frederick J. Hollander, and Angelica M. Stacy
pp 2837 - 2841; DOI:
10.1021/ic00340a023
PDF
Oxide and hydroxide species formed on addition of water in ambient-temperature chloroaluminate melts: an oxygen-17 NMR study
Thomas A. Zawodzinski and Robert A. Osteryoung
pp 2842 - 2847; DOI:
10.1021/ic00340a024
PDF
Electron-transfer thermodynamics and bonding for the superoxide (O2.-), dioxygen (.O2.), and hydroxy (.OH) adducts of (tetrakis(2,6-dichlorophenyl)porphinato)iron, -manganese, and -cobalt in dimethylformamide
Paul K. S. Tsang and Donald T. Sawyer
pp 2848 - 2855; DOI:
10.1021/ic00340a025
PDF
Influence of the pendant group on the substitution lability of N-substituted ethylenediaminetriacetate complexes of ruthenium(III) in aqueous solution
H. C. Bajaj and R. Van Eldik
pp 2855 - 2858; DOI:
10.1021/ic00340a026
PDF
Thermodynamic and spectroscopic studies on silver(I) complex formation with phosphorus multidentate ligands in dimethyl sulfoxide
Plinio Di Bernardo, Giuliano Dolcetti, Roberto Portanova, Marilena Tolazzi, Giuliana Tomat, and Pierluigi Zanonato
pp 2859 - 2862; DOI:
10.1021/ic00340a027
PDF
A novel copper(II) complex containing the ligand 1,2-bis(2,2'-bipyridyl-6-yl)ethane: structural, magnetic, redox, and spectral properties
Ty Garber, Shawn Van Wallendael, D. Paul Rillema, Martin Kirk, William E. Hatfield, Jane H. Welch, and P. Singh
pp 2863 - 2868; DOI:
10.1021/ic00340a028
PDF
Preparation and structure of mononuclear iron(III) complexes [LFeCl3]- and [LFe(N3)3]- (L = hydrotris(1-pyrazolyl)borate and hydrotris(3,5-dimethyl-1-pyrazolyl)borate)
Hideno Fukui, Masami Ito, Yoshihiko Morooka, and Nobumasa Kitajima
pp 2868 - 2870; DOI:
10.1021/ic00340a029
PDF
Phosphorus-31 and platinum-195 NMR data of several "T-frame" diplatinum complexes that exhibit unusual structure, bonding, and reactivity
Eduardo Baralt and C. M. Lukehart
pp 2870 - 2872; DOI:
10.1021/ic00340a030
PDF
Crystal structure of pyrazinium chlorochromate
M. R. Pressprich, R. D. Willett, W. W. Paudler, and G. L. Gard
pp 2872 - 2873; DOI:
10.1021/ic00340a031
PDF
Reaction of (tetrahydrofuran)borane with dihydridotridecacarbonyl- and tetrahydridododecacarbonyltetraruthenate: preparation and structure of the tetraruthenium butterfly cluster HRu4(CO)12BH2
Fung E. Hong, Deborah A. McCarthy, James P. White, Charles E. Cottrell, and Sheldon G. Shore
pp 2874 - 2876; DOI:
10.1021/ic00340a032
PDF
Dilatometric studies on reaction volumes for the formation of nickel(II) complexes in aqueous solution [Erratum to document cited in CA109(16):136023m]
Toru Amari, Shigenobu Funahashi, and Motoharu Tanaka
pp 2876 - 2876; DOI:
10.1021/ic00340a033
PDF

Issue 16


Correlation of heterogeneous electron-transfer rate with electron-transfer site in metalloporphyrins
Xi Hai Mu and Franklin A. Schultz
pp 2877 - 2879; DOI:
10.1021/ic00341a001
PDF
Preparation and characterization of a layered molybdenum phosphate with Mo-Mo bonds: structure of Na3Mo2P2O11(OH).cntdot.2H2O
Linda A. Mundi and Robert C. Haushalter
pp 2879 - 2881; DOI:
10.1021/ic00341a002
PDF
Iron-hydroxide stretching resonance Raman bands of a water-soluble sterically hindered porphyrin
Robert A. Reed, Kenton R. Rodgers, Kristine Kushmeider, Thomas G. Spiro, and Y. Oliver Su
pp 2881 - 2883; DOI:
10.1021/ic00341a003
PDF
Soluble and volatile yttrium and copper alkoxo-acetylacetonato derivatives: synthesis and crystal structure of Y3(.mu.3,.eta.2-OC2H4OMe)2(.mu.2,.eta.2-OC2H4OMe)2(.mu.2,.eta.1-OC2H4OMe)(acac)4
O. Poncelet, L. G. Hubert-Pfalzgraf, and J. C. Daran
pp 2883 - 2885; DOI:
10.1021/ic00341a004
PDF
Synthesis, structure, and reactivity of the nitrosyl ligand/Lewis acid adduct (.eta.5-C5H5)Re(NO-BCl3)(PPh3)(SiMe2Cl)
Kenneth E. Lee, Atta M. Arif, and J. A. Gladysz
pp 2885 - 2887; DOI:
10.1021/ic00341a005
PDF
Structure and magnetic moment of pyrrolidinium copper trichloride, a linear ferromagnet
Diane M. Nilsen, R. D. Larsen, Kenneth Emerson, Gerald V. Rubenacker, Zhou Ping, and John E. Drumheller
pp 2887 - 2888; DOI:
10.1021/ic00341a006
PDF
A new polymorph of tetraphosphorus triselenide, .alpha.'-P4Se3: an x-ray, Raman, and XPS study of the normal crystalline phases and a DSC study of the crystalline and the orientationally disordered phases of P4Se3
Joanne R. Rollo, Gary R. Burns, Ward T. Robinson, Robin J. H. Clark, Helen M. Dawes, and Michael B. Hursthouse
pp 2889 - 2894; DOI:
10.1021/ic00341a007
PDF
Nickel-electrode-confined {Ru(bipyrazine)3[Fe(CN)5]n}2-3n: an inorganic structural matrix yielding photoinduced multinuclear charge-transfer reactivity
Carmela Hidalgo-Luangdilok and Andrew B. Bocarsly
pp 2894 - 2900; DOI:
10.1021/ic00341a008
PDF
Electronic structure of nickel carbonyl clusters: chemical bonding and spectroscopy of [Ni5(CO)12]2-, [Ni6(CO)12]2-, and [Ni8C(CO)16]2- studied by the LCGTO-LDF method
Gianfranco Pacchioni and Notker Roesch
pp 2901 - 2908; DOI:
10.1021/ic00341a009
PDF
The nature of reduced and excited states of .pi.-electron-deficient complexes between tricarbonylhalorhenium and diimine ligands
Wolfgang Kaim and Stephan Kohlmann
pp 2909 - 2914; DOI:
10.1021/ic00341a010
PDF
Extended Heuckel MO studies of boranes. I. Relative stabilities of closo-BnHn and -BnHn2-
William W. Porterfield, Marion E. Jones, Wendy R. Gill, and Kenneth Wade
pp 2914 - 2919; DOI:
10.1021/ic00341a011
PDF
Extended Hueckel MO studies of boranes. II. Isomer preferences of BnHn+4 species
William W. Porterfield, Marion E. Jones, and Kenneth Wade
pp 2919 - 2923; DOI:
10.1021/ic00341a012
PDF
Extended Hueckel MO studies of boranes. III. Isomer preferences of BnHn+6 species
William W. Porterfield, Marion E. Jones, and Kenneth Wade
pp 2923 - 2927; DOI:
10.1021/ic00341a013
PDF
Extended Hueckel MO studies of boranes. IV. Rationalization and prediction of endo- and bridging-hydrogen positions in nido and arachno systems
William W. Porterfield, Marion E. Jones, and Kenneth Wade
pp 2927 - 2933; DOI:
10.1021/ic00341a014
PDF
Kinetics and mechanism of the reaction of aqueous copper(II) with ascorbic acid
Jinhuang Xu and R. B. Jordan
pp 2933 - 2936; DOI:
10.1021/ic00341a015
PDF
Kinetics and mechanism of the linkage isomerism in the nickel(II)-2,3-dihydroxybenzoate system
Li Cun and R. B. Jordan
pp 2937 - 2940; DOI:
10.1021/ic00341a016
PDF
Characterization of pentacyanoferrate(II) and -(III) complexes of adenosine and related aminopyridine ligands
C. H. Hung, H. Y. Huang, J. Y. Liao, and A. Yeh
pp 2940 - 2944; DOI:
10.1021/ic00341a017
PDF
Synthesis and characterization of new dioxygen carriers: a reexamination of the fly-over ligand system
Susan Ransohoff, Michael T. Adams, Sharlene J. Dzugan, and Daryle H. Busch
pp 2945 - 2947; DOI:
10.1021/ic00341a018
PDF
Protecting groups in the preparation of thiolate complexes of technetium
N. Bryson, J. Lister-James, A. G. Jones, W. M. Davis, and Alan Davison
pp 2948 - 2951; DOI:
10.1021/ic00341a019
PDF
Synthesis and structural characterization of mixed-metal chloro chalcogenido cluster complexes of molybdenum and nickel [Mo3Ni2X4Cl4{P(C2H5)3}5] (X = S, Se)
Taro Saito, Yoshimichi Kajitani, Tsuneaki Yamagata, and Hideo Imoto
pp 2951 - 2955; DOI:
10.1021/ic00341a020
PDF
Deprotonation of octacarbonyl(hydrido)(diphenylphosphido)dirhenium for synthesis of mixed rhenium-gold clusters with Re2Aun cores (n = 1-3)
H. J. Haupt, C. Heinekamp, and U. Floerke
pp 2955 - 2963; DOI:
10.1021/ic00341a021
PDF
1-(4-tolylsulfonyl)-1,4,8,11-tetraazacyclotetradecane (Tscyclam): a versatile ligand for nickel(II) and nickel(III) cations
Mario Calligaris, Oliviero Carugo, Giuseppe Crippa, Giancarlo De Santis, Michela Di Casa, Luigi Fabbrizzi, Antonio Poggi, and Barbara Seghi
pp 2964 - 2970; DOI:
10.1021/ic00341a022
PDF
Platinum-gold-mercury (PtAu8Hg2) and (PtAu7Hg2) cluster compounds: x-ray structure of [Pt(AuPPh3)8(Hg)2](NO3)4.3CH2Cl2
J. J. Bour, W. Van den Berg, P. P. J. Schlebos, R. P. F. Kanters, M. F. J. Schoondergang, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, J. J. Steggerda, and P. Van der Sluis
pp 2971 - 2975; DOI:
10.1021/ic00341a023
PDF
Selective oxygenation of aliphatic ethers catalyzed by ruthenium(II) complexes
Mario Bressan, Antonino Morvillo, and Giorgio Romanello
pp 2976 - 2979; DOI:
10.1021/ic00341a024
PDF
Molecular vapor synthesis: the use of titanium monoxide and vanadium monoxide vapors as reagents
Thomas J. Groshens and Kenneth J. Klabunde
pp 2979 - 2982; DOI:
10.1021/ic00341a025
PDF
Chemistry of perfluoromethylsulfonyl perfluorobutylsulfonyl imide
Sukhjinder Singh and Darryl D. DesMarteau
pp 2982 - 2985; DOI:
10.1021/ic00341a026
PDF
Formation and properties of dimethyl sulfide-tetraborane(8): base-induced dynamic behavior of tetraborane(8) adducts
Minoru Ishii and Goji Kodama
pp 2986 - 2989; DOI:
10.1021/ic00341a027
PDF
Ammine(trimethyl)aluminum formation and pyrolytic methane loss: thermodynamics, kinetics, and mechanism
Frederick C. Sauls, Leonard V. Interrante, and Zhiping Jiang
pp 2989 - 2996; DOI:
10.1021/ic00341a028
PDF
Synthesis and multinuclear (carbon-13, selenium-77, tellurium-125, mercury-199) magnetic resonance spectra of adamantane-like anions of mercury(II), [(.mu.-ER)6(HgX)4]2- (E = sulfur, selenium, tellurium; X = chlorine, bromine, iodine)
Philip A. W. Dean and Veeragathy Manivannan
pp 2997 - 3002; DOI:
10.1021/ic00341a029
PDF
Studies of titanium(IV) chloride in a strongly Lewis acidic molten salt: electrochemistry and titanium NMR and electronic spectroscopy
R. T. Carlin, Robert A. Osteryoung, J. S. Wilkes, and J. Rovang
pp 3003 - 3009; DOI:
10.1021/ic00341a030
PDF
Tetranuclear complexes of 1,3,5,9,11,13-hexaketonates. 2. Synthesis and electrochemistry of a series of heterotetranuclear complexes, bis {1,1'-(1,3-phenylene)bis[7-methyl-1,3,5-octanetrionato(4-)]}hexakis(pyridine)bis[di-oxouranium(VI)dimetal(II), M2(UO2)2(MOB)2(py)6
Richard L. Lintvedt, W. E. Lynch, and J. K. Zehetmair
pp 3009 - 3013; DOI:
10.1021/ic00341a031
PDF
Oxovanadium alkoxides: structure, reactivity and vanadium-51 NMR characteristics. Crystal and molecular structures of tris(2-chloroethoxo)oxovanadium and aquadichlorooxobis(tetrahydrofuran)vanadium
Wolfgang Priebsch and Dieter Rehder
pp 3013 - 3019; DOI:
10.1021/ic00341a032
PDF
Structural study of optical resolution. XIV. Highly efficient chiral discrimination of the lel3-tris(trans-1,2-cyclohexanediamine)cobalt(III) ion attained with the d-(R,R)-tartrate ion assuming an anomalous conformation
Tsutomu Mizuta, Kazuo Toshitani, Katsuhiko Miyoshi, and Hayami Yoneda
pp 3020 - 3026; DOI:
10.1021/ic00341a033
PDF
Crystal structure, magnetism, and electronic and EPR spectroscopies of bis(2-aminopyrimidinium) tetrachlorocuprate(II): a square-planar CuCl42- anion with semicoordinated cationic ligands
Claudia Zanchini and Roger D. Willett
pp 3027 - 3030; DOI:
10.1021/ic00341a034
PDF
Molecular crystal structure and magnetic properties of (croconato)- and (oxalato)manganese(II) complexes
Diane Deguenon, Gerald Bernardinelli, Jean Pierre Tuchagues, and Paule Castan
pp 3031 - 3037; DOI:
10.1021/ic00341a035
PDF
Lower valence fluorides of chromium. 2. The phase potassium chromium fluoride (K0.43-0.59CrF3)
Y. S. Hong, K. N. Baker, A. V. Shah, R. F. Williamson, and W. O. J. Boo
pp 3037 - 3041; DOI:
10.1021/ic00341a036
PDF
Two-coordinate complexes of univalent coinage metals with Group VB ligands and the crystal structures of bis(tricyclopentylarsine)silver perchlorate and bis(cyclopentyldiphenylphosphine)silver perchlorate
A. Baiada, F. H. Jardine, and R. D. Willett
pp 3042 - 3046; DOI:
10.1021/ic00341a037
PDF
Hypercoordination in SiH5- and SiH5.bul.. An electron-count dependence
P. Maitre, F. Volatron, P. C. Hiberty, and S. S. Shaik
pp 3047 - 3048; DOI:
10.1021/ic00341a038
PDF
Single-crystal EPR study of copper(II) trinuclear compounds: exchange-averaging effects
Yves Journaux, Francisco Lloret, and Olivier Kahn
pp 3048 - 3051; DOI:
10.1021/ic00341a039
PDF
Ion-pair charge transfer (IPCT) between bipyridinium cations and the tetracarbonylcobaltate anion. Spectroscopy and thermal and photochemical reactions
H. Knoll, R. Billing, H. Hennig, and D. J. Stufkens
pp 3051 - 3053; DOI:
10.1021/ic00341a040
PDF
Competitive CO attack in pentacarbonyliron using methanolic tetraethylammonium hydroxide. IR spectra observation and reactivity studies of tetracarbonyl(hydroxycarbonyl)- and tetracarbonyl(methoxycarbonyl)ferrate
Sang Woo Lee, W. David Tucker, and Michael G. Richmond
pp 3053 - 3056; DOI:
10.1021/ic00341a041
PDF
Crossover from metal-centered to ligand-centered emission in rhodium(III) polypyridine complexes: Rh(phen)2(NH3)Cl2+, Rh(phen)2(NH3)23+, Rh(phen)2(CN)2+
Maria Teresa Indelli and Franco Scandola
pp 3056 - 3058; DOI:
10.1021/ic00341a042
PDF
Crystal structure of 2-hydroxy-1-(pentafluoro-.lambda.6-sulfanyl)-2,2-difluoroethanesulfonic acid sultone
M. R. Pressprich, R. D. Willett, R. J. Terjeson, R. Winter, and G. L. Gard
pp 3058 - 3060; DOI:
10.1021/ic00341a043
PDF
Proton nuclear magnetic resonance studies of iron(II/III)-amide complexes. Spectroscopic models for nonheme iron proteins
Li June Ming, Randall B. Lauffer, and Lawrence Que
pp 3060 - 3064; DOI:
10.1021/ic00341a044
PDF

Issue 17


Pyrolytic transformation of metal alkoxides to oxides: mechanistic studies. Pyrolysis of homoleptic titanium alkoxides
Manish Nandi, Doug Rhubright, and Ayusman Sen
pp 3065 - 3066; DOI:
10.1021/ic00342a001
PDF
Metal ions as ligands: complexation of tin(II) chloride by the bidentate ligand bis[bis(diphenylphosphino)butane]dicarbonyldichlorodiiridium
Alan L. Balch, Brian J. Davis, and Marilyn M. Olmstead
pp 3066 - 3068; DOI:
10.1021/ic00342a002
PDF
A novel coordination mode for dithiatetrazocines: preparation, x-ray structure, and fluxional behavior of [Pt(PPh3)(1,5-Ph4P2N4S2)]2
Tristram Chivers, Mark Edwards, Pramesh N. Kapoor, Auke Meetsma, Johan C. Van de Grampel, and Arie Van der Lee
pp 3068 - 3069; DOI:
10.1021/ic00342a003
PDF
The electronic structure of barium gallium antimonide (Ba7Ga4Sb9): a compound seemingly probing the limits of the Zintl concept
Pere Alemany, Santiago Alvarez, and Roald Hoffmann
pp 3070 - 3073; DOI:
10.1021/ic00342a004
PDF
Electronic spectra and bonding parameters of three planar complexes trans-dichlorobis(heterocyclic amine)copper where N is a heterocyclic amine
Robbie G. McDonald and Michael A. Hitchman
pp 3074 - 3080; DOI:
10.1021/ic00342a005
PDF
Electronic spectra and bonding of the planar complexes diaquadichlorocopper tetrakis(triphenylphosphine oxide) and dichlorobis(4-methylpyridine-N-oxide) copper
Robbie G. McDonald and Michael A. Hitchman
pp 3081 - 3088; DOI:
10.1021/ic00342a006
PDF
Solvent dependence of the EPR spectra of oxochromate(V) complexes: solution structures and the effects of hydrogen bonding between the solvent and the complex
Richard Bramley, Ji Ying Ji, Robert J. Judd, and Peter A. Lay
pp 3089 - 3094; DOI:
10.1021/ic00342a007
PDF
Electronic origin of molybdenum-95 NMR chemical shifts in molybdenum complexes. Relationship between excitation energy and chemical shift
Hiroshi Nakatsuji, M. Sugimoto, and S. Saito
pp 3095 - 3097; DOI:
10.1021/ic00342a008
PDF
Electron-impact and flash-vacuum pyrolysis of trivalent and pentavalent phosphorus azides: generation of original unsaturated mono-, di-, and tricoordinated phosphorus cations
A. Maquestiau, L. Z. Chen, R. Flammang, J. P. Majoral, and G. Bertrand
pp 3097 - 3102; DOI:
10.1021/ic00342a009
PDF
Application of the Fenske-Hall molecular orbital method to the calculation of boron-11 NMR chemical shifts. Antipodal substituent effects in deltahedral clusters
Thomas P. Fehlner, Paul T. Czech, and Richard F. Fenske
pp 3103 - 3109; DOI:
10.1021/ic00342a010
PDF
Ab initio MO and SD-CI study of (carbon dioxide)bis(phosphine)nickel. Electron correlation effects on geometry, binding energy, and electronic structure
Shigeyoshi Sakaki, Nobuaki Koga, and Keiji Morokuma
pp 3110 - 3116; DOI:
10.1021/ic00342a011
PDF
Preparation and characterization of superconducting bismuth lead strontium calcium copper oxides[(Bi,Pb)2Sr2Ca2Cu3] oxides with Tc above 110 K by coprecipitation in triethylamine media
C. Y. Shei, R. S. Liu, C. T. Chang, and P. T. Wu
pp 3117 - 3119; DOI:
10.1021/ic00342a012
PDF
A bromide analog of a one-dimensional Ising ferromagnet: trimethylammonium catena-bis(.mu.-bromo)diaquoiron(II) bromide
R. E. Greeney, Christopher P. Landee, J. H. Zhang, and W. M. Reiff
pp 3119 - 3125; DOI:
10.1021/ic00342a013
PDF
Alcohol adducts of alkoxides: intramolecular hydrogen bonding as a general structural feature
Brian A. Vaartstra, John C. Huffman, Peter S. Gradeff, Liliane G. Hubert-Pfalzgraf, Jean Claude Daran, Stephen Parraud, Kenan Yunlu, and Kenneth G. Caulton
pp 3126 - 3131; DOI:
10.1021/ic00342a014
PDF
Organometallic chemistry of fluorocarbon acids. Structure of hexakis(isopropoxo)bis[bis(trifluoromethylsulfonyl)methanato)dititanium: an example of an oxygen-bonded HC(SO2CF3)2 ligand
A. R. Siedle and J. C. Huffman
pp 3131 - 3134; DOI:
10.1021/ic00342a015
PDF
Oxidative decarbonylation of dimanganese decacarbonyl by polyselenide anions: molecular structure of [(C6H5)4P]2[Mn2(Se2)2(CO)6].cntdot.C4H10O, [(C6H5)4P]2[Mn2(Se4)2(CO)6], and [(C6H5)4P]2[Mn(Se4)2]
S. C. O'Neal, W. T. Pennington, and J. W. Kolis
pp 3134 - 3138; DOI:
10.1021/ic00342a016
PDF
Nitrogen- and oxygen-bonded urethane: hydrolysis and linkage isomerization of [(NH3)5Co(NH2CO2C2H5)]3+ and [(NH3)5CoOC(NH2)OCH2CH3]3+
D. P. Fairlie and W. G. Jackson
pp 3139 - 3145; DOI:
10.1021/ic00342a017
PDF
Linkage isomeric pentaamminecobalt(III) complexes of methanesulfinamide
David P. Fairlie, W. Gregory Jackson, and Katherine H. Thompson
pp 3145 - 3150; DOI:
10.1021/ic00342a018
PDF
Equilibria and spectra of mono- and polynuclear bromocuprate(I) complexes in aqueous solution
Kenneth L. Stevenson, Melissa M. Grush, and Kristine S. Kurtz
pp 3150 - 3153; DOI:
10.1021/ic00342a019
PDF
Reactions of fluorenylidene nitrile ylides with (salen)metal complexes
Somu SriHari and John Masnovi
pp 3154 - 3157; DOI:
10.1021/ic00342a020
PDF
Synthesis of dialkyltriazanium chlorides through chloramination reactions of dialkylamines
Awni A. Khatib and Harry H. Sisler
pp 3158 - 3161; DOI:
10.1021/ic00342a021
PDF
Polymeric ruthenium(I) and binuclear ruthenium(I) and osmium(I) carboxylate-bridged complexes containing diphoshine, diarsine, arsinophosphine, diphosphine chalcogenide, and dithioether ligands: the structure of [Ru2(CO)4(.mu.-O2CMe)2(MeSCH2SMe)]2.cntdot.THF
Robert W. Hilts, Stephen J. Sherlock, Martin Cowie, Eric Singleton, and Margot M. de V. Steyn
pp 3161 - 3167; DOI:
10.1021/ic00342a022
PDF
Synthesis and properties of binuclear ruthenium complexes with 2,7-bis(2-pyridyl)-1,8-naphthyridine (bpnp). X-ray crystal structure of [Ru2(.mu.-O2CCH3)3bpnp]PF6
Elizabeth Binamira-Soriaga, Nancy L. Keder, and William C. Kaska
pp 3167 - 3171; DOI:
10.1021/ic00342a023
PDF
Mercury(II) and methylmercury(II) complexes of novel sterically hindered thiolates: carbon-13 and mercury-199 NMR studies and the crystal and molecular structures of [MeHg(SC6H2-2,4,6-Pr-iso3)], [Hg(SC6H4-2-SiMe3)2], [Hg(2-SC5H3N-3-SiMe3)2], and [Hg{(2-SC6H4)2SiMe2}]2
Eric Block, Maria Brito, Michael Gernon, Deborah McGowty, Hyunkyu Kang, and Jon Zubieta
pp 3172 - 3181; DOI:
10.1021/ic00342a024
PDF
Phosphorus-31 NMR spectroscopy as a probe of models for the molybdenum-phosphate interaction in oxo-type molybdoenzymes and their cofactors
Ulrich Kuesthardt, Michael J. LaBarre, and John H. Enemark
pp 3182 - 3187; DOI:
10.1021/ic00342a025
PDF
Electronic structure study of dinuclear transition-metal complexes with alkynes as bridges
F. Albert Cotton and Xuejun Feng
pp 3187 - 3192; DOI:
10.1021/ic00342a026
PDF
A new type of metal-olefin complex. Synthesis and characterization of four compounds that contain an ethylene bridge perpendicularly bisecting a metal-metal axis
F. Albert Cotton and Piotr A. Kibala
pp 3192 - 3196; DOI:
10.1021/ic00342a027
PDF
Further studies of Os2X82- ions: bis[methyltriphenylphosphonium] octachlorodiosmate with eclipsed, disordered anions and the first octaiododiosmate(2-) compound
F. Albert Cotton and K. Vidyasagar
pp 3197 - 3199; DOI:
10.1021/ic00342a028
PDF
A compound with a hafnium-hafnium bond. The first structurally characterized hafnium(III) complex: hexachlorobis(1,2-bis(diisopropylphosphino)ethane)dihafnium
Paige M. Morse, Scott R. Wilson, and Gregory S. Girolami
pp 3200 - 3202; DOI:
10.1021/ic00342a029
PDF
Preparations and structures of two polynuclear aggregates obtained by using the metallaligand dichloro[bis(diphenylphosphinomethyl)phenylarsine]digold
Alan L. Balch, Ella Y. Fung, and Marilyn M. Olmstead
pp 3203 - 3207; DOI:
10.1021/ic00342a030
PDF
Coordination of the "pendant-arm" macrocycle 6,13-diamino-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane to chromium(III). Crystal structure and physical properties of the hexacoordinated complex ion
Paul V. Bernhardt, Peter Comba, Neil F. Curtis, Trevor W. Hambley, Geoffrey A. Lawrance, Marcel Maeder, and Asokamali Siriwardena
pp 3208 - 3213; DOI:
10.1021/ic00342a031
PDF
Thermochemical interpretation of electrode potentials for transition metal complexes
David E. Richardson
pp 3213 - 3217; DOI:
10.1021/ic00342a032
PDF
Synthesis and characterization of monosubstituted borane adducts of diethyl [(dimethylamino)methyl]phosphonate
Mallaiah Mittakanti, M. R. M. D. Charandabi, and Karen W. Morse
pp 3218 - 3220; DOI:
10.1021/ic00342a033
PDF
Synthesis, structure, and spectroscopic properties of germanium and tin compounds containing aryloxide ligation: comparison of aryloxide bonding to group 4 and group 14 metal centers
Glen D. Smith, Phillip E. Fanwick, and Ian P. Rothwell
pp 3221 - 3226; DOI:
10.1021/ic00342a034
PDF
Polymeric xenon materials: (-Xe-O-TeF4-O-)n. Crystal structure of HF.cntdot.HO-TeF4-O-Xe+AsF6-
L. Turowsky and K. Seppelt
pp 3226 - 3228; DOI:
10.1021/ic00342a035
PDF
Iron(II) and iron(III) complexes of N-(2-(4-imidazolyl)ethyl)pyrimidine-4-carboxamide, a ligand resembling part of the metal-binding domain of bleomycin
Steven J. Brown, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 3229 - 3234; DOI:
10.1021/ic00342a036
PDF
Hyperfine interactions of coordinating nitrogens in the copper(II) complexes having a N2S2 donor set and blue copper proteins
Ryo Miyamoto, Yasunori Ohba, and Masamoto Iwaizumi
pp 3234 - 3238; DOI:
10.1021/ic00342a037
PDF
Synthesis, structure and reactivity of a novel series of propargylic cationic derivatives: [Co2(CO)6(CH.tplbond.CCH2SR1R2)]BF4, [(Co2(CO)6(CH.tplbond.CCH2PR3)]BF4 and [Co2(CO)6(CH.tplbond.CCH2Py)]BF4
Hani El-Amouri, Michel Gruselle, Gerard Jaouen, Jean Claude Daran, and Jacqueline Vaissermann
pp 3238 - 3242; DOI:
10.1021/ic00342a038
PDF
Synthesis and structural characterization of new boron-substituted monocarbon carborane adducts: nido-8-L-7-CB10H12 (L = dimethyl sulfide, triphenylphosphine)
William Quintana and Larry G. Sneddon
pp 3242 - 3245; DOI:
10.1021/ic00342a039
PDF
Influence of electronic configuration on the structure and optical properties of potassium tin oxide phosphate
Mark L. F. Phillips, William T. A. Harrison, and Galen D. Stucky
pp 3245 - 3247; DOI:
10.1021/ic00342a040
PDF
Isocyanocobalt(III) species: identification of the elusive pentaamminecyanocobalt(2+) ion
W. Greg Jackson and A. F. M. M. Rahman
pp 3247 - 3250; DOI:
10.1021/ic00342a041
PDF
Reaction of isopropyl isocyanate with bare vanadium(I) cations leading to combined decarbonylation/demethanation
Karsten Eller and Helmut Schwarz
pp 3250 - 3252; DOI:
10.1021/ic00342a042
PDF
Synthesis and characterization of bis(trifluoromethyl)gold .mu.-halide dimers: x-ray structural characterization of [Au(CF3)2(.mu.-I)]2
John L. Margrave, Kenton H. Whitmire, Robert H. Hauge, and Nathan T. Norem
pp 3252 - 3253; DOI:
10.1021/ic00342a043
PDF
Nuclear magnetic resonance studies of hydroquinone dianion bridged iron(III) porphyrin dimers
Alan L. Balch, Rebecca L. Hart, and Lechoslaw Latos-Grazynski
pp 3253 - 3256; DOI:
10.1021/ic00342a044
PDF
Charge density study of thiourea S,S-dioxide
Yu Wang, Ning Leh Chang, and Ching Tzong Pai
pp 3256 - 3259; DOI:
10.1021/ic00342a045
PDF
Head-tail oriented nucleobases (B = guanine, cytosine) in platinum complexes cis-A2PtB2 resisting cyanide substitution. Implications for the nature of strongly DNA-bound cisplatin
Gudrun Frommer and Bernhard Lippert
pp 3259 - 3260; DOI:
10.1021/ic00342a046
PDF
Layered titanate pillared with alumina
Michael W. Anderson and Jacek Klinowski
pp 3260 - 3263; DOI:
10.1021/ic00342a047
PDF
Chromatographic separation and characterization of linkage isomers of the 3-(pyridin-2-yl)-1H-1,2,4-triazole complex of ruthenium(II) bis(2,2'-bipyridyl)
Barbara E. Buchanan, Renyi Wang, Johannes G. Vos, Ronald Hage, Jaap G. Haasnoot, and Jan Reedijk
pp 3263 - 3265; DOI:
10.1021/ic00342a048
PDF
Synthesis and deprotonation reactions of neutral and cationic cyclic (aminooxy)carbenes derived from platinum(II) carbonyls
Livio Zanotto, Roberta Bertani, and Rino A. Michelin
pp 3265 - 3268; DOI:
10.1021/ic00342a049
PDF

Issue 18


Hydrogen-rich metal cluster complexes. Hexahydrido platinum-osmium carbonyl cluster complexes from the reaction of Pt2Os4(CO)18 with hydrogen
Richard D. Adams, Gong Chen, Dean A. Katahira, James T. Tanner, and Wengan Wu
pp 3269 - 3270; DOI:
10.1021/ic00343a001
PDF
Inverse experiments with fluorine detection
M. Bourdonneau and C. Brevard
pp 3270 - 3272; DOI:
10.1021/ic00343a002
PDF
From semiconductor-semiconductor transition (42 K) to the highest-Tc organic superconductor, .kappa.-(ET)2Cu[N(CN)2]Cl (Tc = 12.5 K)
Jack M. Williams, Aravinda M. Kini, Hau H. Wang, K. Douglas Carlson, Urs Geiser, Lawrence K. Montgomery, Gloria J. Pyrka, Diana M. Watkins, Jefferson M. Kommers, and et al.
pp 3272 - 3274; DOI:
10.1021/ic00343a003
PDF
Chemistry in the polar intermetallic host zirconium antimonide, Zr5Sb3. Fifteen interstitial compounds
Eduardo Garcia and John D. Corbett
pp 3274 - 3282; DOI:
10.1021/ic00343a004
PDF
Selective lithium encapsulation in aqueous solution by the new cage 4,10-dimethyl-1,4,7,10,15-pentaazabicyclo[5.5.5]heptadecane (L). Synthesis, characterization, and structural aspects. Crystal structures of [LiL](ClO4) and [CuL]Br2.cntdot.3H2O
Andrea Bencini, Antonio Bianchi, Angela Borselli, Stefano Chimichi, Mario Ciampolini, Paolo Dapporto, Mauro Micheloni, Nicoletta Nardi, Paola Paoli, and Barbara Valtancoli
pp 3282 - 3286; DOI:
10.1021/ic00343a005
PDF
Gas-phase structures of dimethylboron azide and dimethylboron isocyanate. Electron diffraction and ab initio study
Renee Hausser-Wallis, Heinz Oberhammer, Wolfgang Einholz, and Peter O. Paetzold
pp 3286 - 3289; DOI:
10.1021/ic00343a006
PDF
Synthesis and x-ray structure determination of [PPh4]2[Cl3W{.mu.-Se(Cl)}(.mu.-SePh)2WCl3].cntdot.2CH2Cl2: single-crystal ESR study of a mixed-oxidation-state binuclear tungsten(III)-tungsten(IV) complex dispersed in a diamagnetic crystal matrix
Joanne M. Ball, P. Michael Boorman, James F. Fait, Heinz Bernhard Kraatz, John F. Richardson, David Collison, and Frank E. Mabbs
pp 3290 - 3293; DOI:
10.1021/ic00343a007
PDF
Crystal structure and vibrational spectra of disodium oxo(disulfato)vanadate
Rasmus Fehrmann, S. Boghosian, G. N. Papatheodorou, K. Nielsen, R. W. Berg, and N. J. Bjerrum
pp 3294 - 3298; DOI:
10.1021/ic00343a008
PDF
Rubidium vanadium pyrophosphate RbV3P4O17+x (x = 0.14): a novel mixed-valence vanadium pyrophosphate
Kwang Hwa Lii and C. S. Lee
pp 3298 - 3301; DOI:
10.1021/ic00343a009
PDF
Magnetochemistry of the tetrahaloferrate(III) ions. 1. Crystal structure and magnetic ordering in bis[4-chloropyridinium tetrachloroferrate(III)]-4-chloropyridinium chloride and bis[4-bromopyridinium) tetrachloroferrate(III)]-4-bromopyridinium chloride
Jalal A. Zora, K. R. Seddon, Peter B. Hitchcock, Carol B. Lowe, Danny P. Shum, and Richard L. Carlin
pp 3302 - 3308; DOI:
10.1021/ic00343a010
PDF
Magnetochemistry of the tetrahaloferrate(III) ions. 2. Crystal structure and magnetic ordering in [4-Br(py)H]3Fe2Cl1.3Br7.7 and [4-Cl(py)H]3Fe2Br9. The superexchange paths in the A3Fe2X9 salts
Carol B. Lowe, Richard L. Carlin, Arthur J. Schultz, and C. K. Loong
pp 3308 - 3315; DOI:
10.1021/ic00343a011
PDF
Iron(II) complexes of ortho-functionalized naphthoquinones. 2. Crystal and molecular structure of bis(aquo)bis(lawsonato)iron(II) and intermolecular magnetic exchange interactions in bis(3-aminolawsonato)iron(II)
Prafulla Garge, Rajeev Chikate, Subhash Padhye, Jean Michel Savariault, Philippe De Loth, and Jean Pierre Tuchagues
pp 3315 - 3320; DOI:
10.1021/ic00343a012
PDF
Magnetic properties of a pyrazine-bridged dinuclear copper(II) compound. X-ray structure of {.mu.-2,5-bis[(dimethylamino)methyl]pyrazine}bis[(diethylenetriamine)copper(II)] perchlorate
Hiroki Oshio and Umpei Nagashima
pp 3321 - 3325; DOI:
10.1021/ic00343a013
PDF
Magnetism of A-copper(II) bimetallic chain compounds (A = iron, cobalt, nickel): one- and three-dimensional behaviors
Petra J. Van Koningsbruggen, Olivier Khan, Keitaro Nakatani, Yu Pei, Jean Pierre Renard, Marc Drillon, and Patrick Legoll
pp 3325 - 3331; DOI:
10.1021/ic00343a014
PDF
Synthesis, structure, and properties of a trinuclear and a mononuclear nickel(II) complex of N,N'-dimethyl-N,N'-bis(.beta.-mercaptoethyl)ethylenediamine
Mary A. Turner, Willem L. Driessen, and Jan Reedijk
pp 3331 - 3335; DOI:
10.1021/ic00343a015
PDF
Late-transition-metal .mu.-oxo and .mu.-imido complexes. 6. Gold(I) imido complexes
Visalakshi Ramamoorthy and Paul R. Sharp
pp 3336 - 3339; DOI:
10.1021/ic00343a016
PDF
Ascertaining the roles of each metal in the activation of S-H bonds in hydrogen sulfide and thiols by the heterobinuclear complex tetracarbonylbis(bis(diphenylphosphino)methane)rheniumrhodium
David M. Antonelli and Martin Cowie
pp 3339 - 3345; DOI:
10.1021/ic00343a017
PDF
Synthesis of monomeric (.eta.5-pentamethylcylopentadienyl)platinum(IV) methyl and bromo complexes and of [hydrotris(3,5-dimethyl-7-pyrazolyl)borato]trimethylplatinum
Steven Roth, Visalakshi Ramamoorthy, and Paul R. Sharp
pp 3345 - 3349; DOI:
10.1021/ic00343a018
PDF
Dithiophosphinate-bridged ruthenium(I) and ruthenium(II) complexes. The structure of [(Ru2(CO)4(.mu.-S2PMe2)2(PPh3)2].cntdot.1/2CH2Cl2
Robert W. Hilts and Martin Cowie
pp 3349 - 3354; DOI:
10.1021/ic00343a019
PDF
Novel cofacial bioctahedral complexes of ruthenium: syntheses and properties of the mixed-valence species [LRu2.5(.mu.-X)3Ru2.5L]2+ (X = Cl, Br, I, OH). Crystal structures of [LRu2.5(.mu.-OH)3Ru2.5L](PF6)2.cntdot.H2O and [LRuIV(.mu.-O)3RuIVL](PF6)2.cntdot.H2O (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
Peter Neubold, Beatriz S. P. C. Della Vedova, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 3355 - 3363; DOI:
10.1021/ic00343a020
PDF
Conformational studies and reduction chemistry of a bimetallic cobalt(I) carbonyl complex based on a binucleating hexakis(tertiary phosphine) ligand system
Andre D'Avignon, Fredric R. Askham, and George G. Stanley
pp 3363 - 3371; DOI:
10.1021/ic00343a021
PDF
Synthesis, properties and structure of bis(cis-(methylthio)stibenethiolato)nickel(II) and bis(bis(methylthio)stilbene)nickel(II) iodide
G. N. Schrauzer, Cheng Zhang, and E. O. Schlemper
pp 3371 - 3376; DOI:
10.1021/ic00343a022
PDF
Pentacoordinate iron tricarbonyl complexes of diphosphine ligands with bite angles greater than 120.degree.
Charles P. Casey, Gregory T. Whiteker, Charles F. Campana, and Douglas R. Powell
pp 3376 - 3381; DOI:
10.1021/ic00343a023
PDF
Solid-state molybdenum-95 NMR study of (aryldiazenido)- and (organohydrazido) polyoxomolybdates. Investigation of model compounds of catalytic molybdenum environments
John C. Edwards, Jon Zubieta, Shahid N. Shaikh, Quin Chen, Shelton Bank, and Paul D. Ellis
pp 3381 - 3393; DOI:
10.1021/ic00343a024
PDF
Electrochemistry as a diagnostic tool to discriminate between classical M-(H)2 and nonclassical M-(H2) structures within a family of dihydride and dihydrogen metal complexes
Claudio Bianchini, Franco Laschi, Maurizio Peruzzini, Francesca M. Ottaviani, Alberto Vacca, and Piero Zanello
pp 3394 - 3402; DOI:
10.1021/ic00343a025
PDF
A novel oxygen-carrying and activating system of rhodium(III). Oxidation and oxygenation reactions of 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complex
Claudio Bianchini, Piero Frediani, Franco Laschi, Andrea Meli, Francesco Vizza, and Piero Zanello
pp 3402 - 3409; DOI:
10.1021/ic00343a026
PDF
Electronic structure and reactivity of dioxolene adducts of nickel(II) and copper(II) triazamacrocyclic complexes
Cristiano Benelli, Andrea Dei, Dante Gatteschi, and Luca Pardi
pp 3409 - 3415; DOI:
10.1021/ic00343a027
PDF
Electrochemistry and spectroelectrochemistry of 1,8-naphthalene- and 1,8-anthracene-linked cofacial binuclear metallophthalocyanines. New mixed-valence metallophthalocyanines
Nagao Kobayashi, Herman Lam, W. Andrew Nevin, Pavel Janda, Clifford C. Leznoff, and A. B. P. Lever
pp 3415 - 3425; DOI:
10.1021/ic00343a028
PDF
Analogs for the specific iron-binding site in the transferrins: molecular structure of a ternary iron(III) model complex and spectroscopic, redox and reactivity properties of related compounds
Michael R. McDevitt, Anthony W. Addison, Ekkehard Sinn, and Laurence K. Thompson
pp 3425 - 3433; DOI:
10.1021/ic00343a029
PDF
Chromium(V)-oxo complexes of macrocyclic tetraamido-N ligands tailored for highly oxidized middle transition metal complexes: a new oxygen-18-labeling reagent and a structure with four nonplanar amides
Terrence J. Collins, Carla Slebodnick, and Erich S. Uffelman
pp 3433 - 3436; DOI:
10.1021/ic00343a030
PDF
Syntheses, rate constants, and x-ray structures of alkylrhodoximes with .sigma.-donating alkyl groups methyl, ethyl isopropyl. A comparison with the analogous alkylcobaloximes, a vitamin B12 model
Nevenka Bresciani Pahor, Renata Dreos-Garlatti, Silvano Geremia, Lucio Randaccio, Giovanni Tauzher, and Ennio Zangrando
pp 3437 - 3441; DOI:
10.1021/ic00343a031
PDF
Structure and reactivity of novel alkylcobalt macrocycles
Shaoyung Lee, James H. Espenson, and Andreja Bakac
pp 3442 - 3447; DOI:
10.1021/ic00343a032
PDF
Spectroscopy and structure of quadruply bonded complexes under extreme pressure (Re2X82-, Mo2Cl4(PMe3)4)
David E. Morris, C. Drew Tait, R. Brian Dyer, Jon R. Schoonover, Michael D. Hopkins, Alfred P. Sattelberger, and William H. Woodruff
pp 3447 - 3452; DOI:
10.1021/ic00343a033
PDF
Electronic absorption and MCD spectra for the triangular platinum(0) complex tri-.mu.-carbonyltris(tritert-butylphosphine)triplatinum
Huey Rong C. Jaw and W. Roy Mason
pp 3452 - 3455; DOI:
10.1021/ic00343a034
PDF
Oxidations of sulfite by hexachloroiridate(IV) and tris(2,2'-bipyridine)osmium(III): two reinvestigations
Rajeshuni Sarala and David M. Stanbury
pp 3456 - 3460; DOI:
10.1021/ic00343a035
PDF
Phosphato complexes of platinum(II): phosphorus-31 NMR and kinetics of formation and isomerization studies
Rathindra N. Bose, Niranjan Goswami, and Shadi Moghaddas
pp 3461 - 3467; DOI:
10.1021/ic00343a036
PDF
Kinetic study of .beta.-hydride elimination of monoalkyl complexes of platinum(II): effects of varying the alkyl chain length or the cis group in the reaction of cis-bis(triethylphosphine)(alkyl)(halo or pseudohalo)platinum(II) complexes
Giuseppe Alibrandi, Luigi Monsu Scolaro, Domenico Minniti, and Raffaello Romeo
pp 3467 - 3472; DOI:
10.1021/ic00343a037
PDF
Mechanistic comparison of thermal and photochemical intramolecular electron-transfer reactions: differentiation on the basis of remarkably different pressure dependencies
Pilar Guardado and Rudi Van Eldik
pp 3473 - 3477; DOI:
10.1021/ic00343a038
PDF
Octahedral metal carbonyls. 71. Kinetics and mechanism of benzene displacement from photogenerated (.eta.2-benzene)chromium pentacarbonyl
Shulin Zhang, Gerard R. Dobson, Volker Zang, Hari C. Bajaj, and Rudi Van Eldik
pp 3477 - 3482; DOI:
10.1021/ic00343a039
PDF
Synthesis and characterization of technetium(III) complexes with nitrogen heterocycles by oxygen atom transfer from oxotechnetium(V) cores. Crystal structures of mer-[Cl3(pic)3Tc] and mer-[Cl3(pic)(PMe2Ph)2Tc] (pic = 4-picoline). Electrochemical parameters for the reduction of TcII, TcIII, and TcIV
Jun Lu, Akahito Yamano, and Michael J. Clarke
pp 3483 - 3487; DOI:
10.1021/ic00343a040
PDF
Synthesis and spectroscopy of copper(II) compounds of a chelating imidazole-thioether ligand. Molecular structures of (1,5-bis(4-imidazolyl)-3-thiapentane)dichlorocopper(II), (1,5-bis(4-imidazolyl)-3-thiapentane)bis(thiocyanato-N)copper(II), and bis[(.mu.-chloro)(1,5-bis(4-imidazolyl)-3-thiapentane)copper(II)] bis(perchlorate)
M. Zoeteman, E. Bouwman, R. A. G. De Graaff, W. L. Driessen, J. Reedijk, and P. Zanello
pp 3487 - 3492; DOI:
10.1021/ic00343a041
PDF
Clusters containing the iron-rhenium-sulfur [ReFe3(.mu.3-S)4] core: an expansion of the heterometal cubane-type cluster series MFe3S4
S. Ciurli, M. Carrie, and Richard H. Holm
pp 3493 - 3501; DOI:
10.1021/ic00343a042
PDF
Tertiary arsines: a new synthesis route and an NMR study
Dileep K. Srivastava, Larry K. Krannich, and Charles L. Watkins
pp 3502 - 3506; DOI:
10.1021/ic00343a043
PDF
The hexafluorochlorate(V) anion, ClF6-
Karl O. Christe, William W. Wilson, Raman V. Chirakal, Jeremy C. P. Sanders, and Gary J. Schrobilgen
pp 3506 - 3511; DOI:
10.1021/ic00343a044
PDF
Chlorine-35 and proton NMR study of anion binding to reduced bovine copper-zinc superoxide dismutase
Duarte Mota de Freitas, Li June Ming, Ravichandran Ramasamy, and Joan Selverstone Valentine
pp 3512 - 3518; DOI:
10.1021/ic00343a045
PDF
Activation of the BCO unit in the ketenylidene analog (.mu.-H)3Os3(CO)9(.mu.3-BCO) by electrophiles: syntheses of vinylidene and alkyne analogs
David P. Workman, Deng Yang Jan, and Sheldon G. Shore
pp 3518 - 3525; DOI:
10.1021/ic00343a046
PDF
Preparation and characterization of tris(trimethylsilyl)silyl derivatives of tin. X-ray crystal structure of Cl2Sn[Si(Si(CH3)3)3]2
S. P. Mallela and Russell A. Geanangel
pp 3525 - 3528; DOI:
10.1021/ic00343a047
PDF
Preparations and crystal structures of Se2I4(AsF6)2.SO2 and Se2I4(Sb2F11)2 and electronic structure of the eclipsed diselenium tetraiodide dication, containing two SeI2 radical cations joined via a .pi.*-.pi.* bond and a delocalized 4p.pi.-5p.pi. bond. Implications for bonding in S2O42-, Se82+, and S82+
W. A. Shantha Nandana, Jack Passmore, Peter S. White, and Chi Ming Wong
pp 3529 - 3538; DOI:
10.1021/ic00343a048
PDF
Technetium(I) isocyamide complexes with bidentate aromatic amine ligands: structural characterization of [Tc(CN-tert-Bu)4(bpy)]PF6, a complex with "Tc(III) character"
Lynne A. O'Connell, John Dewan, Alun G. Jones, and Alan Davison
pp 3539 - 3547; DOI:
10.1021/ic00343a049
PDF
Effect of quenched disorder on phase transitions in the mixed-valence solid solution [FeIII2FeII1-xCoIIxO(O2CCH3)6(py)3](py)
Ho G. Jang, Kazutoshi Kaji, Michio Sorai, Richard J. Wittebort, Steven J. Geib, Arnold L. Rheingold, and David N. Hendrickson
pp 3547 - 3556; DOI:
10.1021/ic00343a050
PDF
Binuclear metallacyclic copper(II) complexes with a large unoccupied cavity derived from a tetradentate, nonmacrocyclic polyhydroimidazole ligand
Sanat K. Mandal, Laurence K. Thompson, Michael J. Newlands, Eric J. Gabe, and Florence L. Lee
pp 3556 - 3561; DOI:
10.1021/ic00343a051
PDF
Reactions of the cis-diamminediaquaplatinum(II) cation with glycinamide, N-glycylglycine, and N-(N-glycylglycyl)glycine. Crystal structure of a complex with two diammineplatinum(II) cations bound to glycylglycinate
Trevor G. Appleton, John R. Hall, Trevor W. Hambley, and Paul D. Prenzler
pp 3562 - 3569; DOI:
10.1021/ic00343a052
PDF
Platinum-195 NMR spectroscopy of nitrogen-15-labeled-peptide complexes
Brigitte E. Schwederski, Hsiupu D. Lee, and Dale W. Margerum
pp 3569 - 3578; DOI:
10.1021/ic00343a053
PDF
Stepwise hydrolysis kinetics of tetrachloroplatinate(II) in base
Li Wu, Brigitte E. Schwederski, and Dale W. Margerum
pp 3578 - 3584; DOI:
10.1021/ic00343a054
PDF
Complexation of lithium ion by the cryptand 4,7,13-trioxa-1,10-diazabicyclo[8.5.5]eicosane (C21C5) in a range of solvents. A lithium-7 nuclear magnetic resonance and potentiometric titration study
Stephen F. Lincoln and Amira Abou-Hamdan
pp 3584 - 3589; DOI:
10.1021/ic00343a055
PDF
Complexation of the uranyl ion (UO22+) with phenylene-1,2-dioxydiacetic acid
L. F. Rao and Gregory R. Choppin
pp 3589 - 3592; DOI:
10.1021/ic00343a056
PDF
Relativistic effects in gold chemistry. 3. Gold(I) complexes
Peter Schwerdtfeger, Peter D. W. Boyd, Anthony K. Burrell, Ward T. Robinson, and Michael J. Taylor
pp 3593 - 3607; DOI:
10.1021/ic00343a057
PDF
M{Hydrotris(3-phenylpyrazol-1-yl)borate}2: sterically encumbered iron(II) and manganese(II) complexes
David M. Eichhorn and William H. Armstrong
pp 3607 - 3612; DOI:
10.1021/ic00343a058
PDF
Calcium binding to carboxylate residues: synthesis and structure of a new form of calcium malonate
Derek J. Hodgson and R. Owen Asplund
pp 3612 - 3615; DOI:
10.1021/ic00343a059
PDF
Fluorodilithium(1+) and hydroxodilithium(1+) in molten alkali-metal nitrate
L. Bengtsson, Bertil Holmberg, and S. Ulvenlund
pp 3615 - 3618; DOI:
10.1021/ic00343a060
PDF
Stereospecificity in the synthesis of the tris((R)-cysteinato-N,S)- and tris((R)-cysteinesulfinato-N,S)cobaltate(III) ions
Alan P. Arnold and W. Gregory Jackson
pp 3618 - 3620; DOI:
10.1021/ic00343a061
PDF
A note on symmetry and the single-crystal NMR shift tensor of the cadmium chloride.cntdot.18-crown-6 complex
Mary Frances Richardson
pp 3620 - 3621; DOI:
10.1021/ic00343a062
PDF
A new synthesis of xenon oxytetrafluoride (XeOF4)
Jon B. Nielsen, Scott A. Kinkead, and P. Gary Eller
pp 3621 - 3622; DOI:
10.1021/ic00343a063
PDF
The novel redox reaction and thiolato ligand transfer between Cp2Ti(SCMe3)2 and CpCo(CO)2. Preparation and structure of [CpCo(.mu.-SCMe3)]2
Alan Shaver, Stephen Morris, Riccardo Turrin, and Victor W. Day
pp 3622 - 3623; DOI:
10.1021/ic00343a064
PDF
Proton NMR spectroscopy of flavocytochrome C552 from Chromatium vinosum
Ivano Bertini, Fabrizio Briganti, and Andrea Scozzafava
pp 3623 - 3625; DOI:
10.1021/ic00343a065
PDF
Synthesis and structure of a novel hexanuclear iron(III) complex containing six terminal and twelve bridging groups and one .mu.6-oxo bridge
Kaspar Hegetschweiler, Helmut Schmalle, Hans M. Streit, and Walter Schneider
pp 3625 - 3627; DOI:
10.1021/ic00343a066
PDF
Chelate binding preferences in CpML4 complexes: preparation and structure of trans-(.eta.5-C5H5)Mo[(C6F5)2PCH2CH2P(C6F5)2](CO)Cl
Michael F. Ernst and Dean M. Roddick
pp 3627 - 3630; DOI:
10.1021/ic00343a067
PDF
Cobalt-induced facile degradation of phenylurea to ammonia, carbon dioxide, and anilinium ion and other reactions of linkage isomeric cobalt(III) complexes of phenylurea [Erratum to document cited in CA110(22):199921u]
David P. Fairlie, W. Gregory Jackson, and George M. McLaughlin
pp 3630 - 3630; DOI:
10.1021/ic00343a068
PDF
Luminescence at high pressures and magnetic fields and the structure of single-crystal platinum(II) binuclear complexes Mx(Pt2(POP)4.cntdot.nH2O (Mx = Ba2, [NH4]4; POP - P2O5H22-) [Erratum to document cited in CA112(14):128218a]
Ludwig Baer, Helmut Englmeier, Guenter Gliemann, Ulrich Klement, and Klaus Juergen Range
pp 3630 - 3630; DOI:
10.1021/ic00343a069
PDF

Issue 19


Solvent dependent metal ion-nucleic base recognition. Extent of macrochelate formation in the binary copper(II) complexes of adenosine 5'-monophosphate (AMP) and adenosine 5'-triphosphate (ATP) in water-dioxane mixtures
Guogang Liang and Helmut Sigel
pp 3631 - 3632; DOI:
10.1021/ic00344a001
PDF
Reactivities of intermediates relevant to metal alkyl carbonylation. Flash photolysis of pentacarbonylmethylmanganese studied by time resolved infrared and optical detection
Simon T. Belt, David W. Ryba, and Peter C. Ford
pp 3633 - 3634; DOI:
10.1021/ic00344a002
PDF
Oxidatively enhanced intramolecular carbonyl scrambling in the mixed-metal cluster [Re7C(CO)21Rh(CO)2]2-
Scott W. Simerly and John R. Shapley
pp 3634 - 3635; DOI:
10.1021/ic00344a003
PDF
Redox and reaction chemistry of (octaethylporphyrinato) ruthenium-phenyl complexes
Jeffery W. Seyler and Charles R. Leidner
pp 3636 - 3641; DOI:
10.1021/ic00344a004
PDF
A pentaammineruthenium mixed-valence complex with 1,4-dicyanamido-2,3,5,6-tetrachlorobenzene dianion as bridging ligand: symmetry-attenuated electronic coupling between redox sites
Manuel A. S. Aquino, Ann E. Bostock, and Robert J. Crutchley
pp 3641 - 3644; DOI:
10.1021/ic00344a005
PDF
Synthesis and characterization of a series of macrocyclic chelates containing oxygen and nitrogen donors: prospects for use as NMR shift agents for alkali-metal cations
R. Merritt Sink, Douglas C. Buster, and A. Dean Sherry
pp 3645 - 3649; DOI:
10.1021/ic00344a006
PDF
Dioxomolybdenum(VI) complexes of the hydrotris(3,5-dimethyl-1-pyrazolyl)borate ligand. Synthesis and oxygen atom transfer reactions
Sue A. Roberts, Charles G. Young, Cary A. Kipke, W. E. Cleland, Katsumoto Yamanouchi, Michael D. Carducci, and John H. Enemark
pp 3650 - 3656; DOI:
10.1021/ic00344a007
PDF
Preparation and properties of the triply bridged, ferromagnetically coupled dinuclear copper(II) complexes [Cu2(OAc)3(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2
George Christou, Spiros P. Perlepes, Eduardo Libby, Kirsten Folting, John C. Huffman, Robert J. Webb, and David N. Hendrickson
pp 3657 - 3666; DOI:
10.1021/ic00344a008
PDF
High-resolution aluminum-27 solid-state magic-angle sample-spinning nuclear magnetic resonance spectroscopic study of aluminum trichloride-tetrahydrofuran complexes
Oc Hee Han and Eric Oldfield
pp 3666 - 3669; DOI:
10.1021/ic00344a009
PDF
Molybdenum(II) chloride in the aluminum chloride-1-methyl-3-ethylimidazolium chloride molten salt. Electrochemical and spectroscopic characterization of the [(Mo6Cl8)Cl6]2- ion in neutral and basic melts
Paul A. Barnard, I Wen Sun, and Charles L. Hussey
pp 3670 - 3674; DOI:
10.1021/ic00344a010
PDF
Crystal structures and single-crystal optical absorption spectra for two new polymorphs of tetrakis(.mu.-pivalato)dimolybdenum(II)
Don S. Martin and Hai Wei Huang
pp 3674 - 3680; DOI:
10.1021/ic00344a011
PDF
Alcohol elimination chemistry of tetrakis(tert-butoxocopper)
T. H. Lemmen, G. V. Goeden, J. C. Huffman, R. L. Geerts, and K. G. Caulton
pp 3680 - 3685; DOI:
10.1021/ic00344a012
PDF
Electron transfer and energy transfer through bridged systems. 4. Intermetallic coupling and electronic spectra of the bis(pentaammineruthenium) complexes of .alpha.,.omega.-dipyridyl trans-polyenes in deuterium oxide
J. R. Reimers and N. S. Hush
pp 3686 - 3697; DOI:
10.1021/ic00344a013
PDF
New niobium complexes of alkynes. 5. Electronic structure and bonding in the tetranuclear complex of niobium [Nb4OCl8{(PhC)4}2]2-
F. Albert Cotton and Xuejun Feng
pp 3697 - 3701; DOI:
10.1021/ic00344a014
PDF
Role of the LUMO in determining redox stability for 2,3-dipyridylpyrazine and 2,3-dipyridylquinoxaline-bridged ruthenium(II) bimetallic complexes
J. B. Cooper, D. B. MacQueen, J. D. Petersen, and Dennis W. Wertz
pp 3701 - 3705; DOI:
10.1021/ic00344a015
PDF
Thermally induced 2E decay pathways in chromium(III) complexes
Leslie S. Forster, Douglas Murrow, and Anthony F. Fucaloro
pp 3706 - 3710; DOI:
10.1021/ic00344a016
PDF
Partitioning of the electrochemical excitation energy in the electrogenerated chemiluminescence of hexanuclear molybdenum and tungsten clusters
Robert D. Mussell and Daniel G. Nocera
pp 3711 - 3717; DOI:
10.1021/ic00344a017
PDF
Chirality and bonding in the first coordination shells of three CoN2Cl2 chromophores: quantitative reproduction of rotatory strengths
Neil D. Fenton and Malcolm Gerloch
pp 3718 - 3726; DOI:
10.1021/ic00344a018
PDF
Energies, intensities, and circular dichroism of d-d transitions in trigonal-bipyramidal cobalt(II) and nickel(II) chromophores
Neil D. Fenton and Malcolm Gerloch
pp 3726 - 3733; DOI:
10.1021/ic00344a019
PDF
Bonding character in tetracoordinate (phthalocyaninato)iron(II) complexes with electron-releasing substituents as studied by Moessbauer spectroscopy
Toshie Ohya, Jun Takeda, Nagao Kobayashi, and Mitsuo Sato
pp 3734 - 3737; DOI:
10.1021/ic00344a020
PDF
Effects of substituents on the spectral and redox properties of cadmium(II) texaphyrins
Bhaskar G. Maiya, Thomas E. Mallouk, Gregory Hemmi, and Jonathan L. Sessler
pp 3738 - 3745; DOI:
10.1021/ic00344a021
PDF
The cavitand concept in the synthesis of subsite-differentiated analogs of biological [4Fe-4S/Se]2+ clusters: cluster capture reactions, ligand conformational analysis, and the structure of a trigonal [4Fe-4Se]2+ analog
T. D. P. Stack, J. A. Weigel, and Richard H. Holm
pp 3745 - 3760; DOI:
10.1021/ic00344a022
PDF
Synthesis, structure, and redox properties of the triaqua(tris(1-pyrazolyl)methane)ruthenium(II) cation
Antoni Llobet, Derek J. Hodgson, and Thomas J. Meyer
pp 3760 - 3766; DOI:
10.1021/ic00344a023
PDF
Inclusion complex formation involving a new class of transition-metal host
Thomas J. Meade, Nathaniel W. Alcock, and Daryle H. Busch
pp 3766 - 3776; DOI:
10.1021/ic00344a024
PDF
Y10I13C2: a novel compound with chains of both carbon-centered and empty clusters
Susan M. Kauzlarich, Martin W. Payne, and John D. Corbett
pp 3777 - 3781; DOI:
10.1021/ic00344a025
PDF
Synthesis of cobalt-tungsten clusters with tetrahedral metallic cores using the mixed-metal complex CoW(CO)7(.eta.5-C5H4Me)(CoW) as a cluster building block. X-ray diffraction study of the sterically crowded tetrahedral cluster CoW3(CO)9(.eta.5-C5H4Me)3
Michael J. Chetcuti, John C. Gordon, and Phillip E. Fanwick
pp 3781 - 3787; DOI:
10.1021/ic00344a026
PDF
Dirhenium complexes derived from the ligand 2-mercaptoquinoline (2-mqH). Structure of [Re2Cl3(.mu.-dppm)2(2-mq)]PF6 (dppm = Ph2PCH2PPh2)
Phillip E. Fanwick, Ju Sheng Qi, and Richard A. Walton
pp 3787 - 3791; DOI:
10.1021/ic00344a027
PDF
Formation and reactions of bis(trimethylphosphine)-methyldiborane(4)
Mitsuaki Kameda, Jerry A. Driscoll, and Goji Kodama
pp 3791 - 3795; DOI:
10.1021/ic00344a028
PDF
Comparative studies on charge distribution for the ruthenium and osmium quinone complexes [M(bpy)2(quinone)]n (M = Ru, Os; n = 0, +1, +2)
Masaaki Haga, Kiyoshi Isobe, Steven R. Boone, and Cortlandt G. Pierpont
pp 3795 - 3799; DOI:
10.1021/ic00344a029
PDF
Spectroscopic and kinetic investigation of bis(N-alkylsalicylaldiminato)copper(II) complexes: a study on the existence of planar .dblharw. tetrahedral configuration equilibria
Rainer Knoch, Andreas Wilk, Klaus J. Wannowius, Dirk Reinen, and Horst Elias
pp 3799 - 3805; DOI:
10.1021/ic00344a030
PDF
Kinetic and mechanistic study of the linkage isomerization of substituted (5-phenyltetrazolato)pentaamminecobalt(III) complexes
John H. Hall and William L. Purcell
pp 3806 - 3811; DOI:
10.1021/ic00344a031
PDF
Kinetics and mechanism of aquation of cobalt(II)-glycine complexes in aqueous solutions: a pulse radiolytic study
Nobuyoshi Shinohara and Jochen Lilie
pp 3812 - 3815; DOI:
10.1021/ic00344a032
PDF
Synthesis, electrochemistry, and kinetic investigations of low-spin ferrous bis(difluoroboryl)bis(dioximate) complexes
David W. Thompson and Dennis V. Stynes
pp 3815 - 3822; DOI:
10.1021/ic00344a033
PDF
Solvent dependence of the electron self-exchange of hexakis(2,6-diisopropylphenyl isocyanide)chromium(0,I) and -chromium(I,II) and a comparison with theoretical models
Kim A. Anderson and Scot Wherland
pp 3822 - 3828; DOI:
10.1021/ic00344a034
PDF
Interactions in aqueous solution at 25.degree.C of palladium(II) and mercury(II) with 1,4-dithia-18-crown-6 and 1,10-dithia-18-crown-6. A thermodynamic, spectral, and x-ray crystallographic study
Reed M. Izatt, Geng Wu, Weiming Jiang, and N. Kent Dalley
pp 3828 - 3832; DOI:
10.1021/ic00344a035
PDF
Synthesis, structure, spectroscopy, and reactivity of bis(tetraselenido)metallate(2-)[M(Se4)2]2- anions, M = nickel, palladium, zinc, cadmium, mercury and manganese
Mohammad A. Ansari, Charles H. Mahler, Gayatri S. Chorghade, Ying Jie Lu, and James A. Ibers
pp 3832 - 3839; DOI:
10.1021/ic00344a036
PDF
Ring expansion and equilibration in organophosphazenes and the relationship to polymerization
Harry R. Allcock, Gayann S. McDonnell, and James L. Desorcie
pp 3839 - 3844; DOI:
10.1021/ic00344a037
PDF
Boron-nitrogen compounds. 125. Pyrazole complexes of three-coordinated boranes
L. Komorowski, W. Maringgele, A. Meller, Kurt Niedenzu, and J. Serwatowski
pp 3845 - 3849; DOI:
10.1021/ic00344a038
PDF
Resonance Raman signatures of oxomolybdenum thiolate and dithiolene models of molybdenum proteins
Prem Subramanian, Sharon Burgmayer, Sarah Richards, Veronika Szalai, and Thomas G. Spiro
pp 3849 - 3853; DOI:
10.1021/ic00344a039
PDF
Heteronuclear NMR studies of Cobalamins. 10. Nitrogen-15 NMR studies of [15N]cyanocobalt corrins
Kenneth L. Brown and B. D. Gupta
pp 3854 - 3860; DOI:
10.1021/ic00344a040
PDF
Photoelectron spectroscopy of the tin dichalcogenides SnS2-xSex intercalated with cobaltocene
C. A. Formstone, E. T. FitzGerald, P. A. Cox, and D. O'Hare
pp 3860 - 3866; DOI:
10.1021/ic00344a041
PDF
Photophysical studies of tungsten carbonyl W(CO)5L complexes. Multiple-state luminescence of W(CO)5(4-cyanopyridine) in fluid and glassy solutions
Kathleen A. Rawlins, Alistair J. Lees, and Arthur W. Adamson
pp 3866 - 3871; DOI:
10.1021/ic00344a042
PDF
Similarity of the electronic properties of the monophosphate tungsten bronzes
Enric Canadell, Myung Hwan Whangbo, and Idris El Idrissi Rachidi
pp 3871 - 3875; DOI:
10.1021/ic00344a043
PDF
FT-IR and fluorometric investigation of rare earth and metal ion solvation. 9. Evidence for a coordination number change along the lanthanide series: FT-IR investigation of the solvates [Ln(NO3)3(DMSO)n] in anhydrous acetonitrile
Jean Claude G. Buenzli, Jean Pierre Metabanzoulou, Pascal Froidevaux, and Linpei Jin
pp 3875 - 3881; DOI:
10.1021/ic00344a044
PDF
AM1 parameters for sulfur
Michael J. S. Dewar and Yate Ching Yuan
pp 3881 - 3890; DOI:
10.1021/ic00344a045
PDF
Electron transfer. 105. Redox reactions of nitrosonium-bound chromium(I), CrI(NO+)
Amrit K. Jhanji and Edwin S. Gould
pp 3890 - 3892; DOI:
10.1021/ic00344a046
PDF
Synthesis and crystal structure of a novel layered Zintl phase: potassium gallium arsenide (K3Ga3As4)
Teresa L. T. Birdwhistell, Edwin D. Stevens, and Charles J. O'Connor
pp 3892 - 3894; DOI:
10.1021/ic00344a047
PDF
Water oxidation by .mu.-oxobis[bis(bipyridine)oxoruthenium(V)](4+). An oxygen-labeling study
Daniel Geselowitz and Thomas J. Meyer
pp 3894 - 3896; DOI:
10.1021/ic00344a048
PDF
Novel ambidentate and chelate complexes of ruthenium with methylenebis(1,3,2-dithiaphospholane) and (methylimino)bis(1,3,2-dithiaphospholane) as ligands
Sangha Kim, Marie Pontier Johnson, and D. Max Roundhill
pp 3896 - 3898; DOI:
10.1021/ic00344a049
PDF
First report on manganese(II)-tetrathiometalate(VI) complexes: isolation of [(bpy)2Mn(.mu.-S)2MS2] (M = molybdenum, tungsten; bpy = 2,2'-bipyridine)
B. R. Srinivasan and Sabyasachi Sarkar
pp 3898 - 3900; DOI:
10.1021/ic00344a050
PDF
Pressure-induced skeletal isomerization of octakis(triphenylphosphine)nonagold(3+) hexafluorophosphate in the solid state
Jeffery L. Coffer, John R. Shapley, and Harry G. Drickamer
pp 3900 - 3901; DOI:
10.1021/ic00344a051
PDF
Structure of (24-pyrimidinium crown-6)[(DMSO)HgI3][HgI4][Hg2I7].cntdot.11DMSO.cntdot.2H2O
Roger E. Cramer and Michel J. J. Carrie
pp 3902 - 3904; DOI:
10.1021/ic00344a052
PDF
Oxidation of alcohols by a six-coordinate ruthenium(IV)-oxo complex
Thomas R. Cundari and Russell S. Drago
pp 3904 - 3907; DOI:
10.1021/ic00344a053
PDF
Characterization of ammonia-ligated low-spin iron(III) porphyrin complexes
Yunghee Oh Kim and Harold M. Goff
pp 3907 - 3908; DOI:
10.1021/ic00344a054
PDF
Spectroscopic verification of a tetragonal compression in an octahedral copper(II) compound
Kim Finnie, Lucjan Dubicki, Elmars R. Krausz, and Mark J. Riley
pp 3908 - 3910; DOI:
10.1021/ic00344a055
PDF
Conformation of hydrogen molecule on dinuclear complexes: attractive effect of a cis hydride
Sarah A. Jackson and Odile Eisenstein
pp 3910 - 3914; DOI:
10.1021/ic00344a056
PDF
Synthesis and crystal and molecular structures of potassium bis(.mu.-hydroxo)bis[dinitritoplatinate(II)] sesquihydrate and potassium cyclo-tris(.mu.3-oxo-1:2:4;1:3:4;2:3:4)tris[dinitritoplatinate(II)]trinitritoplatinate(IV) trihydrate [Erratum to document cited in CA112(6):47571h]
D. Min, R. D. Larsen, K. Emerson, and E. H. Abbott
pp 3914 - 3914; DOI:
10.1021/ic00344a057
PDF

Issue 20


Nitrogen/chlorine atom exchange reactions between manganese porphyrins: apparent bridging ligand preference in an inner-sphere process
L. Keith Woo, Donald J. Czapla, and James G. Goll
pp 3915 - 3916; DOI:
10.1021/ic00345a001
PDF
Oxo-transfer reactions of chromium and titanium porphyrins
L. Keith Woo, J. Alan Hays, and James G. Goll
pp 3916 - 3917; DOI:
10.1021/ic00345a002
PDF
Molecular structure and exchange interactions in trans-bis(L-2-aminobutyrato)copper(II) and trans-bis(DL-2-aminobutyrato)copper(II)
P. R. Levstein, Rafael Calvo, E. E. Castellano, O. E. Piro, and B. E. Rivero
pp 3918 - 3922; DOI:
10.1021/ic00345a003
PDF
Structure and bonding in transition-metal carbonyls and nitrosyls. 4. Molecular structure of ruthenium pentacarbonyl determined by gas-phase electron diffraction
Jinfan Huang, Kenneth Hedberg, H. B. Davis, and R. K. Pomeroy
pp 3923 - 3925; DOI:
10.1021/ic00345a004
PDF
Synthesis and characterization of a series of novel rhodium and iridium complexes containing polypyridyl bridging ligands: potential uses in the development of multimetal catalysts for carbon dioxide reduction
Seth C. Rasmussen, Mark M. Richter, Eugene Yi, Helen Place, and Karen J. Brewer
pp 3926 - 3932; DOI:
10.1021/ic00345a005
PDF
Single-crystal structure and electrical conductivity of 1,2,3-trimethylimidazolium bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate(III)
Derk Reefman, Joost P. Cornelissen, Jaap G. Haasnoot, Rudolf A. G. De Graaff, and Jan Reedijk
pp 3933 - 3935; DOI:
10.1021/ic00345a006
PDF
One-electron transfer processes in the reaction of indium(I) halides with substituted o-quinones
Theodore A. Annan, Raj K. Chadha, Peter Doan, David H. McConville, Bruce R. McGarvey, Andrzej Ozarowski, and Dennis G. Tuck
pp 3936 - 3943; DOI:
10.1021/ic00345a007
PDF
Electronic and structural properties of the novel chain compound tantalum telluride silicide, Ta4Te4Si
Jing Li, Roald Hoffmann, Michael E. Badding, and Francis J. DiSalvo
pp 3943 - 3952; DOI:
10.1021/ic00345a008
PDF
Synthesis and structure of tantalum silicide telluride, Ta4SiTe4, a new low-dimensional material
Michael E. Badding and F. J. DiSalvo
pp 3952 - 3954; DOI:
10.1021/ic00345a009
PDF
An open structure for the adduct of fluoride ion with oxalyl fluoride
David A. Dixon, William B. Farnham, and Bruce E. Smart
pp 3954 - 3960; DOI:
10.1021/ic00345a010
PDF
Magnetodynamic effects on outer-sphere electron-transfer reactions: a paramagnetic transition state
S. Ronco and G. Ferraudi
pp 3961 - 3967; DOI:
10.1021/ic00345a011
PDF
Molecular topology exchange interaction: synthesis and magnetic properties of [Cu(II)3M(II)] (M = cadmium, nickel, manganese) tetranuclear species
Francesc Lloret, Yves Journaux, and Miguel Julve
pp 3967 - 3972; DOI:
10.1021/ic00345a012
PDF
Comparison of lithium ion transport and distribution in human red blood cells in the presence and absence of dysprosium(III) complexes of triphosphate and triethylenetetraminehexaacetate
Duarte Mota de Freitas, Maryceline T. Espanol, Ravichandran Ramasamy, and Richard J. Labotka
pp 3972 - 3979; DOI:
10.1021/ic00345a013
PDF
Effects of negatively charged shift reagents on red blood cell morphology, lithium ion transport, and membrane potential
Ravichandran Ramasamy, Duarte Mota de Freitas, Warren Jones, Frederick Wezeman, Richard Labotka, and Carlos F. G. C. Geraldes
pp 3979 - 3985; DOI:
10.1021/ic00345a014
PDF
Reactions of the cis-diamminediaquaplatinum(II) cation with 2-aminomalonic acid and its homologs, aspartic and glutamic acids. Rearrangements of metastable complexes with carboxylate-bound ligands to N,O-chelates and formation of di- and trinuclear complexes
Trevor G. Appleton, John R. Hall, Donald W. Neale, and Craig S. M. Thompson
pp 3985 - 3990; DOI:
10.1021/ic00345a015
PDF
Vanadium(III)-carbon and titanium(III)-carbon functionalities supported by a tetradentate Schiff base ligand
Jean Marie Rosset, Carlo Floriani, Marinella Mazzanti, Angiola Chiesi-Villa, and Carlo Guastini
pp 3991 - 3996; DOI:
10.1021/ic00345a016
PDF
Synthesis, characterization, and electrochemistry of cis-dioxomolybdenum(VI) complexes of Schiff bases derived from carbohydrazide, thiocarbohydrazide, and salicylaldehyde. Crystal structures of [MoO2(o-OC6H4CH:NN:CSNHN:CHC6H4OH-o)Me2SO] and [(MoO2)2(o-OC6H4CH:NN:CONN:CHC6H4O-o)(Me2SO)2].cntdot.0.5Me2SO
C. Bustos, O. Burckhardt, R. Schrebler, D. Carrillo, A. M. Arif, A. H. Cowley, and C. M. Nunn
pp 3996 - 4001; DOI:
10.1021/ic00345a017
PDF
A new bis(.mu.-sulfido)ditantalum(IV) edge-sharing bioctahedral molecule and a reassessment of some earlier "bis(.mu.-chloro)" molecules
Elizabeth Babaian-Kibala, F. Albert Cotton, and Piotr A. Kibala
pp 4002 - 4005; DOI:
10.1021/ic00345a018
PDF
The dinuclear palladium(II) complex of pyridine-2-thiol. Synthesis, structure, and electrochemistry
Keisuke Umakoshi, Akio Ichimura, Isamu Kinoshita, and Shunichiro Ooi
pp 4005 - 4010; DOI:
10.1021/ic00345a019
PDF
Crystal and molecular structure of dimeric bis[N,N-di-n-propyldithiocarbamato]zinc(II) and the study of exchange-coupled copper(II)-copper(II) pairs in its lattice
N. Sreehari, Babu Varghese, and P. T. Manoharan
pp 4011 - 4015; DOI:
10.1021/ic00345a020
PDF
Reactions of chloramine with methylpyridines. Synthesis and crystal structure of N-amino-3,5-dimethylpyridinium chloride
Gus J. Palenik, K. Qian, A. E. Koziol, and Harry H. Sisler
pp 4016 - 4018; DOI:
10.1021/ic00345a021
PDF
Hydrolysis chemistry of the chlorophosphazene cyclic trimer
Douglas G. Gabler and James F. Haw
pp 4018 - 4021; DOI:
10.1021/ic00345a022
PDF
Role of bridging ligand .pi.-acidity in determining the nature of the lowest excited states of binuclear complexes of nickel(0). Ligand-centered (M2 .fwdarw. .mu.-LCT), metal-centered (.mu.-L .fwdarw. M2CT), and intraligand (IL) lowest excited states for the series of complexes Ni2(.mu.-L)(CNMe)2(PPh2CH2PPh2)2 (L = CNR, CNMe(R)+, NO+)
K. S. Ratliff, D. L. DeLaet, J. Gao, P. E. Fanwick, and C. P. Kubiak
pp 4022 - 4027; DOI:
10.1021/ic00345a023
PDF
Complexes of the ligand 1,5,8,12-tetraazadodecane (3,2,3-tet) with manganese(III) and with a valence-trapped manganese(III)/manganese(IV) hexanuclear array. Crystal and molecular structures of [trans-Mn(3-IOBz)2(3,2,3-tet)](ClO4) and [Mn6(3,2,3-tet)4O6(OAc)3]I5.cntdot.2H2O.cntdot.4C4H8O
Rajumati Bhula, Susan Collier, Ward T. Robinson, and David C. Weatherburn
pp 4027 - 4032; DOI:
10.1021/ic00345a024
PDF
Synthesis and molecular structure of Rh2(ap)4(CCH) (ap = 2-anilinopyridinato). Spectroscopic and electrochemical properties of carbon-.sigma.-bonded dirhodium complexes
C. L. Yao, K. H. Park, A. R. Khokhar, M. J. Jun, and John L. Bear
pp 4033 - 4039; DOI:
10.1021/ic00345a025
PDF
Oxidative-addition reactions involving the mixed-valence complex bis[bis(diphenylphosphino)methane]tetracarbonylrheniumrhodium. Influence of the coordinatively unsaturated Rh(+I) center on the saturated Re(-I) center
David M. Antonelli and Martin Cowie
pp 4039 - 4045; DOI:
10.1021/ic00345a026
PDF
Alkyl group effects on carbon monoxide insertion into coordinatively unsaturated early-transition-metal alkyls. Preparations and the first structural characterizations of tantalum enolate-O and tantalum .eta.2-acyl complexes
Tara Y. Meyer, Lelia R. Garner, Norman C. Baenziger, and Louis Messerle
pp 4045 - 4050; DOI:
10.1021/ic00345a027
PDF
Preparation and properties of tris(trimethylstannyl)silyl complexes of chromium, molybdenum, and tungsten. X-ray structure of [NEt4][(CO)5WSi(SnMe3)3]
Richard H. Heyn and T. Don Tilley
pp 4051 - 4055; DOI:
10.1021/ic00345a028
PDF
Formation and chemical reactions of ruthenium tricarbonyls adsorbed on metal oxides. Use of chemical reactions as a method of surface structure determination
Joseph J. Bergmeister and Brian E. Hanson
pp 4055 - 4059; DOI:
10.1021/ic00345a029
PDF
Synthesis, structure, and properties of a new ternary metal nitride, Ca3CrN3
Deborah A. Vennos, Michael E. Badding, and F. J. DiSalvo
pp 4059 - 4062; DOI:
10.1021/ic00345a030
PDF
Structural and magnetic characterization of electron-transfer salts of hexacyanotrimethylenecyclopropanide, {C3[C(CN)2]3}.bul.- and [Fe(C5Me5)2].bul.+ (1:1; two phases) and [Fe(C6H3Me3)2]2+ (1:2). Evidence for 1-D antiferromagnetic behavior in segregated {Fe(C5Me5)2].bul.+ chains
Joel S. Miller, Michael D. Ward, Jian H. Zhang, and William M. Reiff
pp 4063 - 4072; DOI:
10.1021/ic00345a031
PDF
Single-crystal and powder EPR study on tetra-n-butylammonium bis(2-thioxo-1,3-dithiole-4,5-diselenolato)cuprate(II), (n-Bu4N)2[63Cu(dsit)2], doped into (n-Bu4N)2[Ni(dsit)2]
R. Kirmse, K. Koehler, Ruth Maria Olk, W. Dietzsch, E. Hoyer, and G. Zwanenburg
pp 4073 - 4076; DOI:
10.1021/ic00345a032
PDF
Synthesis and characterization of alkali-metal titanium alkoxide compounds MTi(O-iso-Pr)5 (M = Li, Na, K): single crystal x-ray diffraction structure of [LiTi(O-iso-Pr)5]2
Mark J. Hampden-Smith, D. S. Williams, and A. L. Rheingold
pp 4076 - 4081; DOI:
10.1021/ic00345a033
PDF
Exchange interactions in rare-earth-metal dimers. Neutron spectroscopy of cesium ytterbium halides, Cs3Yb2Cl9 and Cs3Yb2Br9
Hans U. Guedel, Albert Furrer, and Herma Blank
pp 4081 - 4084; DOI:
10.1021/ic00345a034
PDF
Crown thioether ligands containing rigid xylyl units. Synthesis and structures of 2,5,8-trithia[9]-o-benzenophane (TTOB), 2,5,8-trithia[9]-m-benzenophane (TTMB) and fac-Mo(CO)3(TTOB).DMSO
Broer De Groot and Stephen J. Loeb
pp 4084 - 4090; DOI:
10.1021/ic00345a035
PDF
Silver(II) tetraneopentoxyphthalocyanine and its redox chemistry
Guoyi Fu, Yansong Fu, K. Jayaraj, and A. B. P. Lever
pp 4090 - 4095; DOI:
10.1021/ic00345a036
PDF
Geometries of non-transition-metal complexes of a novel chiral .beta.-keto amide tripodal ligand elucidated from the optical transitions to excitonic states
Yitzhak Tor, Abraham Shanzer, and Avigdor Scherz
pp 4096 - 4099; DOI:
10.1021/ic00345a037
PDF
Synthesis, structure, and dynamic properties of bis(cis-(benzylthio)stilbenethiolate) complexes of nickel(II), palladium(II), and platinum(II) and of related compounds
Cheng Zhang, Hussain K. Reddy, Elmer O. Schlemper, and Gerhard N. Schrauzer
pp 4100 - 4103; DOI:
10.1021/ic00345a038
PDF
The cis-bis(cis-2-mercaptostilbene-1-sulfinato)nickel(II) dianion: a product of the irreversible oxidation of the bis(cis-stilbene-1,2-dithiolato)nickel(II) dianion
G. N. Schrauzer, Cheng Zhang, and R. Chadha
pp 4104 - 4107; DOI:
10.1021/ic00345a039
PDF
Transition-metal complexes with sulfur ligands. 52. Synthesis, x-ray structure characterization, and reactions of [Fe(CO)(.mu.-"S4")]2, a novel type of chiral complex with relevance to iron oxidoreductases ("S4"2- = 1,2-bis((2-mercaptophenyl)thio)ethanato(2-))
Dieter Sellmann, Robert Weiss, Falk Knoch, Gerhard Ritter, and Joachim Dengler
pp 4107 - 4114; DOI:
10.1021/ic00345a040
PDF
Iron(II) complexes of 2,2'-biimidazole and 2,2'-bibenzimidazole as models of the photosynthetic mononuclear non-heme ferrous sites. Synthesis, molecular and crystal structure, and Moessbauer and magnetic studies
Didier Boinnard, Patrick Cassoux, Vasili Petrouleas, Jean Michel Savariault, and Jean Pierre Tuchagues
pp 4114 - 4122; DOI:
10.1021/ic00345a041
PDF
Sulfur atom transfer with reduction of a [TcVI.tplbond.N]3+ core to a [TcI-N.tplbond.S]2+ core. Crystal structure of mer-dichlorotris(4-picoline)(thionitrosyl)technetium
Jun Lu and Michael J. Clarke
pp 4123 - 4125; DOI:
10.1021/ic00345a042
PDF
Tin(II) porphyrins: synthesis and spectroscopic properties of a series of divalent tin porphyrins. X-ray crystal structure of (2,3,7,8,12,13,17,18-octaethylprophinato)tin(II)
J. M. Barbe, C. Ratti, P. Richard, C. Lecomte, R. Gerardin, and R. Guilard
pp 4126 - 4130; DOI:
10.1021/ic00345a043
PDF
Structural chemistry of molybdenum-iron-sulfur cluster compounds with a single-cubane [MoFe3S4]n+ (n = 4-6) core and crystal structure of [MoFe3S4(Me2dtc)5].cntdot.2CH2Cl2
Qiutian Liu, Liangren Huang, Hanqin Liu, Xinjian Lei, Daxu Wu, Beisheng Kang, and Jiaxi Lu
pp 4131 - 4137; DOI:
10.1021/ic00345a044
PDF
Structural studies on rhenium and tungsten halo trialkylphosphine, M2X4(PR3)4 compounds (M = rhenium, tungsten; X = Cl, Br; R = Me, n-Pr, n-Bu). The first examples of simple three-way disorder of dimetal units within ordered ligand cages
F. Albert Cotton, J. Gregory Jennings, Andrew C. Price, and K. Vidyasagar
pp 4138 - 4143; DOI:
10.1021/ic00345a045
PDF
Model studies related to hemerythrin. Synthesis and characterization of a bridged tetranuclear iron(III) complex
Jonathan L. Sessler, John W. Sibert, and Vincent Lynch
pp 4143 - 4146; DOI:
10.1021/ic00345a046
PDF
Crystal and molecular structure of bis[1,3-bis(diphenylphosphino)propane]platinum(0): a reevaluation
Kahtan A. Asker, Peter B. Hitchcock, Roger P. Moulding, and Kenneth R. Seddon
pp 4146 - 4148; DOI:
10.1021/ic00345a047
PDF
Formation of trinuclear clusters by addition of (triphenylphosphine)gold(1+) to dinuclear platinum(I) complexes containing bridging cyclometalated arylphosphines. X-ray structure of [(Ph3P)AuPt2{C6H4P(Ph)CH2CH2CH2PPh2}2]BF4
Martin A. Bennett, David E. Berry, and Kathryn A. Beveridge
pp 4148 - 4152; DOI:
10.1021/ic00345a048
PDF
High yield synthesis of cis-dihydrido-trans-bis(phosphite)dicarbonyliron complexes H2Fe(CO)2[P(OR)3]2 (R = Me, Et, Ph)
Jean Jacques Brunet, Fadjai Banda Kindela, Daniel Labroue, and Denis Neibecker
pp 4152 - 4153; DOI:
10.1021/ic00345a049
PDF
Ferromagnetic coupling of gadolinium(III) ions and nitronyl nitroxide radicals in an essentially isotropic way
Cristiano Benelli, Andrea Caneschi, Antonio Costantino Fabretti, Dante Gatteschi, and Luca Pardi
pp 4153 - 4155; DOI:
10.1021/ic00345a050
PDF
The methyl(cyclam)nickel(III) dication in aqueous solutions: determination of the volume of reaction and volume of activation for the homolysis of the nickel-carbon bond. A pulse-radiolysis study
Rudi Van Eldik, Haim Cohen, Avraham Meshulam, and Dan Meyerstein
pp 4156 - 4158; DOI:
10.1021/ic00345a051
PDF
Effects of .pi..pi. interaction on the electronic properties of asymmetrical lanthanide porphyrin sandwich complexes
John K. Duchowski and David F. Bocian
pp 4158 - 4160; DOI:
10.1021/ic00345a052
PDF
Theoretical predictions and new structures of stacking patterns for CunX2nL2 oligomers
Roger D. Willett, Marcus R. Bond, and George Pon
pp 4160 - 4162; DOI:
10.1021/ic00345a053
PDF
A simple synthesis of 3-bromo-o-carborane
Ji Li and Maitland Jones
pp 4162 - 4163; DOI:
10.1021/ic00345a054
PDF
Models for structural environments in silicon chalcogenide glasses. Synthesis, characterization, and single-crystal x-ray structures of tetrakis(benzenethiolato)silicon and tetrakis(benzeneselenolato)silicon
Robert K. Shibao, Nancy L. Keder, and Hellmut Eckert
pp 4163 - 4166; DOI:
10.1021/ic00345a055
PDF

Issue 21


On the .pi.-donor ability of early transition metals: evidence that trialkylphosphines can engage in .pi.-back-bonding and x-ray structure of the titanium(II) phenoxide Ti(OPh)2(dmpe)2
Robert J. Morris and Gregory S. Girolami
pp 4167 - 4169; DOI:
10.1021/ic00346a001
PDF
Excited state properties of mononuclear and binuclear rhenium(I) complexes
Rongguang Lin, Rich Duesing, and Thomas F. Guarr
pp 4169 - 4172; DOI:
10.1021/ic00346a002
PDF
Oxidative addition of nitrogen-hydrogen bonds to iridium: synthesis and structure of (heterocyclic amine)iridium hydride complexes
Folami T. Ladipo and Joseph S. Merola
pp 4172 - 4173; DOI:
10.1021/ic00346a003
PDF
Reactions of the diboron tetrahalides B2Cl4 and B2Br4 with B5H9: preparation and properties of the (dihaloboryl)pentaborane derivatives 1-BX2B5H8, (X = Br, Cl, F, OCH3, tert-Bu, H) and synthesis of (BCl2)3B5H6
D. A. Saulys and J. A. Morrison
pp 4174 - 4179; DOI:
10.1021/ic00346a004
PDF
Kinetics and mechanism of the reaction of aqueous iron(III) with ascorbic acid
Jinhuang Xu and Robert B. Jordan
pp 4180 - 4184; DOI:
10.1021/ic00346a005
PDF
Electron-transfer reactions of optically active tris(phenanthroline)cobalt(3+/2+) and derivatives
Robert M. L. Warren, A. Graham Lappin, Brahm Dev Mehta, and H. M. Neumann
pp 4185 - 4189; DOI:
10.1021/ic00346a006
PDF
Synthesis and structures of dioxoruthenium(VI) complexes. Oxo transfer from trans-O2Ru(py)2(O2CR)2
S. Perrier, T. C. Lau, and Jay K. Kochi
pp 4190 - 4195; DOI:
10.1021/ic00346a007
PDF
Redox equilibria of the nitrosonium cation and of its nonbonded complexes
K. Y. Lee, D. J. Kuchynka, and Jay K. Kochi
pp 4196 - 4204; DOI:
10.1021/ic00346a008
PDF
Reaction of (dioxygen) (dithiocarbamato) rhodium complexes with carbon dioxide. Formation and chemical cleavage of rhodium peroxycarbonato and carbonato rings
Yasuo Wakatsuki, Masahiro Maniwa, and Hiroshi Yamazaki
pp 4204 - 4208; DOI:
10.1021/ic00346a009
PDF
Cluster synthesis. 28. New platinum-cobalt carbonyl cluster complexes and products obtained from their reactions with alkynes
Richard D. Adams, Gong Chen, Wengan Wu, and Jianguo Yin
pp 4208 - 4214; DOI:
10.1021/ic00346a010
PDF
Structure and magnetic properties of bis(N,N-diisopropyldithiocarbamato)copper(II)
William E. Hatfield, Phirtu Singh, and Francoise Nepveu
pp 4214 - 4217; DOI:
10.1021/ic00346a011
PDF
Ferro- and antiferromagnetic coupling between metal ions and pyridine-substituted nitronyl nitroxides
Andrea Caneschi, Fabrizio Ferraro, Dante Gatteschi, Paul Rey, and Roberta Sessoli
pp 4217 - 4223; DOI:
10.1021/ic00346a012
PDF
Linear-chain gadolinium(III) nitronyl nitroxide complexes with dominant next-nearest-neighbor magnetic interactions
Cristiano Benelli, Andrea Caneschi, Dante Gatteschi, Luca Pardi, and Paul Rey
pp 4223 - 4228; DOI:
10.1021/ic00346a013
PDF
Structure and magnetic properties of manganese(II) carboxylate chains with nitronyl nitroxides and their reduced amidino-oxide derivatives. From random-exchange one-dimensional to two-dimensional magnetic materials
Andrea Caneschi, Dante Gatteschi, Maria Chiara Melandri, Paul Rey, and Roberta Sessoli
pp 4228 - 4234; DOI:
10.1021/ic00346a014
PDF
Moessbauer and magnetic susceptibility investigation of a ferromagnetically coupled iron(III) porphyrin-dicopper(II) system with imidazolate bridging ligands
Govind P. Gupta, George Lang, Carol A. Koch, Bing Wang, W. Robert Scheidt, and Christopher A. Reed
pp 4234 - 4239; DOI:
10.1021/ic00346a015
PDF
A quasi-tetrahedral tetracopper cluster with syn-anti bridging carboxylate groups: crystal and molecular structure and magnetic properties
Enrique Colacio, Jean Pierre Costes, Raikko Kivekas, Jean Pierre Laurent, and Jose Ruiz
pp 4240 - 4246; DOI:
10.1021/ic00346a016
PDF
Electrochemical and spectroscopic studies of rhenium(IV) monomeric and dimeric chloride complexes in the basic aluminum chloride-1-methyl-3-ethylimidazolium chloride room-temperature molten salt
Sandra K. D. Strubinger, I Wen Sun, W. E. Cleland, and Charles L. Hussey
pp 4246 - 4252; DOI:
10.1021/ic00346a017
PDF
Synthesis and reactions of [bis(trimethylsilyl)amido]aluminum compounds
K. J. L. Paciorek, J. H. Nakahara, and S. R. Masuda
pp 4252 - 4255; DOI:
10.1021/ic00346a018
PDF
Fluorinated three- and four-nitrogen compounds and their reactions
Ghulam Sarwar, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 4255 - 4258; DOI:
10.1021/ic00346a019
PDF
Electron transfer. 103. Reactions of aqueous chromium(IV)
M. C. Ghosh and E. S. Gould
pp 4258 - 4262; DOI:
10.1021/ic00346a020
PDF
Selective cleavage of a vinyl ether group from a nickel(II) macrocycle complex and synthesis of derivatives
Colin P. Horwitz, Ralph Navarro, and Gregory C. Dailey
pp 4262 - 4268; DOI:
10.1021/ic00346a021
PDF
Unusual stereochemical rigidity in seven-coordination. Synthesis and structural characterization of ReH2(EPh3)(CO)(PMe2Ph)3 (E = Si, Sn)
Xiao Liang Luo, Gayle K. Schulte, Peter Demou, and Robert H. Crabtree
pp 4268 - 4273; DOI:
10.1021/ic00346a022
PDF
Dimerization of metalloporphyrin .pi. cation radicals. Characterization of two novel dimers: [Zn(OEP.cntdot.)(OH2)]2(ClO4)2 and [Ni(OEP)]2(ClO4)2
Hungsun Song, Robert D. Orosz, Christopher A. Reed, and W. Robert Scheidt
pp 4274 - 4282; DOI:
10.1021/ic00346a023
PDF
Condensation reactions of aqueous vanadate with the common nucleosides
Alan S. Tracey, Jaswinder S. Jaswal, Michael J. Gresser, and Dieter Rehder
pp 4283 - 4288; DOI:
10.1021/ic00346a024
PDF
Magnetic studies of the high-potential protein model [Fe4S4(S-2,4,6-(iso-Pr)3C6H2)4]- in the [Fe4S4]3+ oxidized state
J. Jordanov, E. K. H. Roth, P. H. Fries, and L. Noodleman
pp 4288 - 4292; DOI:
10.1021/ic00346a025
PDF
A bis(.mu.-alkoxo)diiron complex with novel terminally ligated carboxylates
Stephane Menage and Lawrence Que
pp 4293 - 4297; DOI:
10.1021/ic00346a026
PDF
Catalytic pathways for the electroreduction of oxygen by iron tetrakis(4-N-methylpyridyl)porphyrin or iron tetraphenylporphyrin adsorbed on edge plane pyrolytic graphite electrodes
Chunnian Shi and Fred C. Anson
pp 4298 - 4305; DOI:
10.1021/ic00346a027
PDF
Chemical and electrochemical reduction of binuclear platinum phosphine complexes
Jane V. Zeile Krevor and Lawrence Yee
pp 4305 - 4310; DOI:
10.1021/ic00346a028
PDF
Intermediates in the 1,2-diaminobenzene/tris(diethylamino)phosphine transamination reaction
Elizabeth G. Bent, R. Curtis Haltiwanger, and Arlan D. Norman
pp 4310 - 4318; DOI:
10.1021/ic00346a029
PDF
Organochromium(III) macrocyclic complexes. Factors controlling homolytic vs heterolytic cleavage of the chromium carbon bond
Shu Shi, James H. Espenson, and Andreja Bakac
pp 4318 - 4322; DOI:
10.1021/ic00346a030
PDF
Solvent-dependent redox thermodynamics of metal amine complexes. Delineation of specific solvation effects
Peter A. Lay, Neale S. McAlpine, Joseph T. Hupp, Michael J. Weaver, and Alan M. Sargeson
pp 4322 - 4328; DOI:
10.1021/ic00346a031
PDF
Unbridged M-M multiple bonds in the chromium Cr2(tmtaa)2 and molybdenum Mo2(tmtaa)2 molecules (tmtaa = dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine): experimental and theoretical investigations
F. Albert Cotton, Joanna Czuchajowska, and Xuejun Feng
pp 4329 - 4335; DOI:
10.1021/ic00346a032
PDF
Luminescence studies of pyridine .alpha.-diimine rhenium(I) tricarbonyl complexes
LouAnn Sacksteder, Arden P. Zipp, Elizabeth A. Brown, Julie Streich, J. N. Demas, and B. A. DeGraff
pp 4335 - 4340; DOI:
10.1021/ic00346a033
PDF
Cooperative absorptions in the electronic spectrum of dipotassium hexachlorotellurate
Marco Bettinelli, Lorenzo Di Sipio, and Gianluigi Ingletto
pp 4341 - 4342; DOI:
10.1021/ic00346a034
PDF
Photochemical grafting of triosmium dodecacarbonyl to inorganic metal oxides
Sadaaki Yamamoto, Robert M. Lewis, Yoshiyuki Nabata, Hajime Hotta, and Haruo Kuroda
pp 4342 - 4345; DOI:
10.1021/ic00346a035
PDF
Dynamic exchange between the covalent and dative metal-metal-bonded isomers of the heterodinuclear complex tris(acetonitrile)bis[bis(diphenylphosphino)methane]nickel palladium(2+) hexafluorophosphate
Jinfeng Ni and Clifford P. Kubiak
pp 4345 - 4347; DOI:
10.1021/ic00346a036
PDF
IR evidence for the formation of an .eta.2(C,O)-.alpha.-ketoacyl complex upon low-temperature photolysis of (.eta.-C5H4Me)(CO)(NO)MnC{O}C{O}Tol
Derk J. Stufkens, John B. Sheridan, and Gregory L. Geoffroy
pp 4347 - 4348; DOI:
10.1021/ic00346a037
PDF
Conversion of bis(acetylacetonato)hydridobis (triphenylphosphine)rhenium(1+) hexafluorophosphate to cis-[Re(acac)2(PPH3)2]PF6 through a coupled oxidation/deprotonation reaction
Malee Leeaphon, Phillip E. Fanwick, and Richard A. Walton
pp 4348 - 4351; DOI:
10.1021/ic00346a038
PDF
Application of 2D NMR techniques to paramagnetic systems
Claudio Luchinat, Stefan Steuernagel, and Paola Turano
pp 4351 - 4353; DOI:
10.1021/ic00346a039
PDF
Doubly bridged .mu.-fluoro-.mu.-oxo and .mu.-fluoro-.mu.-hydroxo chromium(III) dimers
Boyd G. Gafford and Robert A. Holwerda
pp 4353 - 4354; DOI:
10.1021/ic00346a040
PDF

Issue 22


Carbon dioxide activation by a transition metal-silicon bond. Formation of silanecarboxylate complexes [Cp2Sc[.mu.-O2CSiR3)]2
Brian K. Campion, Richard H. Heyn, and T. Don Tilley
pp 4355 - 4356; DOI:
10.1021/ic00347a001
PDF
Catalysis of the autoxidation of aqueous sulfur dioxide using [Ni(III)(cyclam)]: evidence for a novel radical chain mechanism
Donald E. Linn, Mark J. Dragan, and David E. Miller
pp 4356 - 4358; DOI:
10.1021/ic00347a002
PDF
Organotelluride chemistry: an unusual free organotelluride anion and the metal complex [Ag4(TeR)6]2- (R = thienyl)
Jin Zhao, David Adcock, William T. Pennington, and Joseph W. Kolis
pp 4358 - 4360; DOI:
10.1021/ic00347a003
PDF
Synthesis and characterization of the rhodium tin mixed-metal alkoxides [((L2)Rh)2Sn(OEt)6], where L2 = 1,5-cyclooctadiene (COD) and (CO)2 and the conversion of the COD complex to Rh and SnO2 under mild conditions
Teresa A. Wark, Eric A. Gulliver, Mark J. Hampden-Smith, and Arnold L. Rheingold
pp 4360 - 4362; DOI:
10.1021/ic00347a004
PDF
Synthesis and structure of five-coordinate aryl-imido derivatives of zirconium(IV)
Robert D. Profilet, Cesar H. Zambrano, Phillip E. Fanwick, John J. Nash, and Ian P. Rothwell
pp 4362 - 4364; DOI:
10.1021/ic00347a005
PDF
Sterically protected nickel(II) in a N2S2 donor environment: 1,5-bis(mercaptoethyl)-1,5-diazacyclooctane and its methylated derivative
Daniel K. Mills, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 4364 - 4366; DOI:
10.1021/ic00347a006
PDF
Synthesis and crystal structure of a nine-coordinate gadolinium(III) complex of 1,7,13-triaza-4,10,16-trioxacyclooctadecane-N,N',N"-triacetic acid
Dian Chen, Philip J. Squattrito, Arthur E. Martell, and Abraham Clearfield
pp 4366 - 4368; DOI:
10.1021/ic00347a007
PDF
Surface-mediated synthesis of H4M4(CO)12 (M = ruthenium, osmium) on hydroxylated silica
Carlo Dossi, Rinaldo Psaro, Dominique Roberto, Renato Ugo, and Gianmaria Zanderighi
pp 4368 - 4373; DOI:
10.1021/ic00347a008
PDF
Low-temperature reactions of atomic nickel with diazomethane
Sou Chan Chang, Robert H. Hauge, Zakya H. Kafafi, John L. Margrave, and W. E. Billups
pp 4373 - 4376; DOI:
10.1021/ic00347a009
PDF
Generation of reactive intermediates in the photochemistry of binuclear trihydridodiplatinum complexes
P. Bergamini, S. Sostero, O. Traverso, and L. M. Venanzi
pp 4376 - 4380; DOI:
10.1021/ic00347a010
PDF
Thiophenophane-metal complexes. 4. Structural and NMR study of a 1,4-fluxional pivot about a palladium-sulfur (thiophene) bond
Shuang Liu, C. Robert Lucas, Michael J. Newlands, and Jean Pierre Charland
pp 4380 - 4385; DOI:
10.1021/ic00347a011
PDF
Thiometalate complexes containing arene, thiophene, and cyclobutadiene coligands. Are thiometalate clusters good models for desulfurization catalysts?
Kevin E. Howard, John R. Lockemeyer, Mark A. Massa, Thomas B. Rauchfuss, Scott R. Wilson, and Xiaoguang Yang
pp 4385 - 4390; DOI:
10.1021/ic00347a012
PDF
Evidence for photodisproportionation of d1-d1 dimers [(Mo{S2CN(CH2Ph)2}2)2O] (M = molybdenum, tungsten) containing linear oxobridges and for oxygen atom transfer from [WO2{S2CN(CH2Ph)2}2] to triethylphosphine
Samkeun Lee, Donna L. Staley, Arnold L. Rheingold, and N. John Cooper
pp 4391 - 4396; DOI:
10.1021/ic00347a013
PDF
Regioselective coupling of a fluoromethylidyne ligand of nonacarbonylbis(.mu.3-fluoromethylidyne)triiron with alkynes
Dieter Lentz and Heike Michael-Schulz
pp 4396 - 4401; DOI:
10.1021/ic00347a014
PDF
Preparation and structure of Au2(.mu.-ylide)2[S2C6H4]2: a dinuclear gold(III) ylide complex with cis,cis geometry
Dwight D. Heinrich and John P. Fackler
pp 4402 - 4404; DOI:
10.1021/ic00347a015
PDF
Gold thiolate complexes with short intermolecular gold-gold distances from reactions of organic disulfides with gold(I) complexes. Syntheses and crystal structures of [AuI2(PPh3)2(.mu.-SCH2Ph)](NO3) and AuIII2Cl4(.mu.-SPh)2
Suning Wang and John P. Fackler
pp 4404 - 4407; DOI:
10.1021/ic00347a016
PDF
Synthesis of a mixed-valence gold(I)/gold(III) complex, [Au(CH2)2PPh2]2Br2, and its characterization by x-ray crystallography and x-ray photoelectron spectroscopy
Raphael G. Raptis, Leigh C. Porter, R. J. Emrich, H. H. Murray, and J. P. Fackler
pp 4408 - 4412; DOI:
10.1021/ic00347a017
PDF
Electrochemistry and infrared spectroelectrochemistry of MnSnPh4-n (M = CpMo(CO)3, Mn(CO)5, CpFe(CO)2; n = 1, 2)
John P. Bullock, Michael C. Palazzotto, and Kent R. Mann
pp 4413 - 4421; DOI:
10.1021/ic00347a018
PDF
Synthesis, properties, and structural investigations of 1,3,2-diazaborolidines and 2,3-dihydro-1H-1,3,2-diazaboroles
Guenter Schmid, Michael Polk, and Roland Boese
pp 4421 - 4429; DOI:
10.1021/ic00347a019
PDF
Steric effects in polypyrazolylborates: mixed complexes M(HB(3-isopropyl-4-bromopyrazolyl)3)L
Joseph C. Calabrese, Peter J. Domaille, Jeffery S. Thompson, and Swiatoslaw Trofimenko
pp 4429 - 4437; DOI:
10.1021/ic00347a020
PDF
Formation and characterization of the unsymmetrical dirhenium polyhydrides Re2H6(PMe3)5 and Re2H6(SbPh3)5 and observations concerning the mechanism of the conversion of Re2H8(PMe3)4 to [Re2H5(PMe3)6]+
Michael T. Costello, Phillip E. Fanwick, Karen E. Meyer, and Richard A. Walton
pp 4437 - 4441; DOI:
10.1021/ic00347a021
PDF
Spin transition in iron Fe(py)2L(NCS)2 complexes where py = pyridine and L = 2,2'-bipyrimidine (bpym) and 1,10-phenanthroline (phen): magnetic, calorimetric, and Moessbauer-effect investigation. Crystal structure of [Fe(py)2bpym(NCS)2].0.25py
Renee Claude, Jose Antonio Real, Jacqueline Zarembowitch, Olivier Kahn, Lahcene Ouahab, Daniel Grandjean, Kamel Boukheddaden, Francois Varret, and Ary Dworkin
pp 4442 - 4448; DOI:
10.1021/ic00347a022
PDF
X-ray crystal structure and homonuclear phosphorus-31-phosphorus-31 .sigma./J-resolved NMR spectroscopic studies of tetrakis (1,8-diisocyanomethane)bis(triphenylphosphine)diirdium silver(3+) tris(hexafluorophosphate). Observation of a statistical mixture of "head/tail" isomers
Andrew G. Sykes and Kent R. Mann
pp 4449 - 4453; DOI:
10.1021/ic00347a023
PDF
Direct determination of the self-exchange rate of a nickel(IV/III) bis(oxime-imine) complex. Investigation of orientation effects in electron-transfer reactions
Rosemary A. Marusak, Christopher Sharp, and A. Graham Lappin
pp 4453 - 4456; DOI:
10.1021/ic00347a024
PDF
Comparative kinetic study of oxygen atom transfer reactions of diperoxo and monoperoxo complexes of oxovanadium(V) in aqueous solution
Arlene F. Ghiron and Richard C. Thompson
pp 4457 - 4461; DOI:
10.1021/ic00347a025
PDF
Influence of the polyamino carboxylate chelating ligand (L) on the kinetics and mechanism of the formation of FeII(L)NO in the system FeII(L)/NO/HONO/NO2- in aqueous solution
V. Zang and Rudy Van Eldik
pp 4462 - 4468; DOI:
10.1021/ic00347a026
PDF
pH dependence of relaxivities and hydration numbers of gadolinium(III) complexes of linear amino carboxylates
C. Allen Chang, Harry G. Brittain, Joshua Telser, and Michael F. Tweedle
pp 4468 - 4473; DOI:
10.1021/ic00347a027
PDF
Equilibrium studies of lanthanide nitrate complexation in aqueous methanol
Herbert B. Silber, Roya Bakhshandehfar, Larry A. Contreras, Ferenc Gaizer, Mark Gonsalves, and Sabariah Ismail
pp 4473 - 4475; DOI:
10.1021/ic00347a028
PDF
Synthesis and spectroscopic and electrochemical characterization of ionic and .sigma.-bonded aluminum(III) porphyrins. Crystal structure of methyl(2,3,7,8,12,13,17,18-octaethylporphinato)aluminum(III), (OEP)Al(CH3)
R. Guilard, A. Zrineh, A. Tabard, A. Endo, B. C. Han, C. Lecomte, M. Souhassou, A. Habbou, M. Ferhat, and K. M. Kadish
pp 4476 - 4482; DOI:
10.1021/ic00347a029
PDF
Interactions of porphyrins and metalloporphyrins with single-stranded poly(dA)
R. F. Pasternack, R. A. Brigandi, M. J. Abrams, A. P. Williams, and E. J. Gibbs
pp 4483 - 4486; DOI:
10.1021/ic00347a030
PDF
Synthesis and characterization of physical, electronic, and photochemical aspects of 9,10-phenanthrenequinonediimine complexes of ruthenium(II) and rhodium(III)
Anna Marie Pyle, Michael Y. Chiang, and Jacqueline K. Barton
pp 4487 - 4495; DOI:
10.1021/ic00347a031
PDF
Characterization of (1,2-cyclohexanediamine)platinum(II) isomers and their d(GpG) adducts by means of proton NMR spectroscopy. A minor structural change induced by the isomers
Kenji Inagaki, Hideaki Nakahara, Maarten Alink, and Yoshinori Kidani
pp 4496 - 4500; DOI:
10.1021/ic00347a032
PDF
Oxalato-bridged and related dinuclear copper(II) complexes: theoretical analysis of their structures and magnetic coupling
Santiago Alvarez, Miguel Julve, and Michel Verdaguer
pp 4500 - 4507; DOI:
10.1021/ic00347a033
PDF
Oxygen-stable ferrocene reference electrodes
James K. Bashkin and Patrick J. Kinlen
pp 4507 - 4509; DOI:
10.1021/ic00347a034
PDF
Electron transfer and energy transfer through bridged systems. 5. Intermetallic coupling and electronic spectra of the bis(pentaammineruthenium) complexes of .alpha.,.omega.-dipyridyl trans-polyenes in nitrobenzene
J. R. Reimers and N. S. Hush
pp 4510 - 4513; DOI:
10.1021/ic00347a035
PDF
Evidence that the chlorine fluoride cation (Cl2F+) has an asymmetric bent (Cs) Cl-Cl-F+ structure
Gernot Frenking and Wolfram Koch
pp 4513 - 4517; DOI:
10.1021/ic00347a036
PDF
Formation of amine, phosphine, and thioether adducts of chlorotriborane(7)
Alan R. Dodds, Mansel A. Nelson, and Goji Kodama
pp 4517 - 4521; DOI:
10.1021/ic00347a037
PDF
Electrochemistry of cyanocopper thiomolybdates and thiotungstates: redox-based interconversion of species
Michael Kony, Alan M. Bond, and Anthony G. Wedd
pp 4521 - 4525; DOI:
10.1021/ic00347a038
PDF
Oxidation of chelated amino acids to imine derivatives with thionyl chloride
Anders Hammershoei, Richard M. Hartshorn, and Alan M. Sargeson
pp 4525 - 4530; DOI:
10.1021/ic00347a039
PDF
A theoretical study on the insertion of ethylene into the cobalt-hydrogen bond
Louis Versluis, Tom Ziegler, and Liangyou Fan
pp 4530 - 4536; DOI:
10.1021/ic00347a040
PDF
Effective new cobalt(II) dioxygen carriers derived from dimethylglyoxime by the replacement of the linking protons with difluoroboron(1+)
Kim A. Lance, Kenneth A. Goldsby, and Daryle H. Busch
pp 4537 - 4544; DOI:
10.1021/ic00347a041
PDF
The role of .pi.-bonding for trigonal level splittings in chelate complexes. 3. The lowest electronic states in tris(acetylacetonato)chromium
M. Atanasov and Thomas Schoenherr
pp 4545 - 4550; DOI:
10.1021/ic00347a042
PDF
Assignment of the electronic spectra of tris(.mu.-halo)bis(triammineruthenium)(2+) ions using resonance Raman spectroscopy
Robert S. Armstrong, Wendy A. Horsfield, and Kerry W. Nugent
pp 4551 - 4556; DOI:
10.1021/ic00347a043
PDF
Solvent and temperature dependences of the osmocene(II)/iodoosmocene(IV) atom/electron exchange
Karl Kirchner, Liang Feng Han, Harold W. Dodgen, Scot Wherland, and John P. Hunt
pp 4556 - 4559; DOI:
10.1021/ic00347a044
PDF
Hydrazido(1-) and 2,2-dimethylhydrazido(1-) derivatives of permethylscandocene. Preparation and structural characterization of their products from reactions with acetonitrile: (.eta.5-C5Me5)2ScN(H)C(CH3)NNH2 and (.eta.5-C5Me5)2ScN(H)C(CH3)NNMe2
Pamela J. Shapiro, Lawrence M. Henling, Richard E. Marsh, and John E. Bercaw
pp 4560 - 4565; DOI:
10.1021/ic00347a045
PDF
Synthesis and structure of FeCl(C.tplbond.CPh)(DMPE)2
Leslie D. Field, Adrian V. George, and Trevor W. Hambley
pp 4565 - 4569; DOI:
10.1021/ic00347a046
PDF
Synthesis and characterization of (nitro)ruthenium complexes that utilize identical trans-positioned tertiary phosphine ligands
Randolph A. Leising, Stephen A. Kubow, and Kenneth J. Takeuchi
pp 4569 - 4574; DOI:
10.1021/ic00347a047
PDF
Preparation and structure of tetrachlorobis(.mu.-ethanethiolato)bis(3,6-dithiaoctane)dirhenium: an edge-sharing bioctahedron with an unbuttressed rhenium(III)-rhenium(III) double bond
Bruce J. Heyen and Gregory L. Powell
pp 4574 - 4576; DOI:
10.1021/ic00347a048
PDF
Intramolecular bridging ligand exchange in [2,2-bis((phenylthio)methyl)-1-(diphenylphosphino)propane]palladium(II) chloride
Shiuh Tzung Liu and Kuo Jiun Liu
pp 4576 - 4579; DOI:
10.1021/ic00347a049
PDF
Chemical deposition of an organozirconium complex onto an oxided aluminum surface: using the "quartz crystal microbalance" to probe microscopic surface acidity
John B. Miller and Jeffrey Schwartz
pp 4579 - 4581; DOI:
10.1021/ic00347a050
PDF
Synthesis and characterization of cyanoiron(II) complexes bound to the bridging ligand tetrakis(2-pyridyl)1,4-diazine (tpd)
Ronald R. Ruminski and Jaqueline L. Kiplinger
pp 4581 - 4584; DOI:
10.1021/ic00347a051
PDF
Reformulation of the hexafluorooctadecatungstate anion as a heteropoly sodate complex: [H2F6NaW18O56]7-
Thomas L. Jorris, Mariusz Kozik, and Louis C. W. Baker
pp 4584 - 4586; DOI:
10.1021/ic00347a052
PDF
Unusual addition of the indium-butyl bond to organotin oxides. Preparation and characterization of novel dibutylindio- or butyl(propionyloxy)indio-substituted stannoxanes
Ryoki Nomura, Satoru Fujii, and Haruo Matsuda
pp 4586 - 4588; DOI:
10.1021/ic00347a053
PDF
(Pentafluoro-.lambda.6-sulfanyl)difluoromethanesulfonyl fluoride and derivatives
Gary L. Gard, A. Waterfeld, R. Mews, J. Mohtasham, and R. Winter
pp 4588 - 4590; DOI:
10.1021/ic00347a054
PDF

Issue 23


Novel approach to the synthesis of ring systems containing phosphorus, nitrogen and sulfur or selenium
Tristram Chivers, Santhanathan S. Kumaravel, Auke Meetsma, Johan C. Van de Grampel, and Arie Van der Lee
pp 4591 - 4592; DOI:
10.1021/ic00348a001
PDF
Bis(phenylimido) complexes of niobium and tantalum prepared by .alpha.-hydrogen abstraction reactions
Yuan Wei Chao, Pamela A. Wexler, and David E. Wigley
pp 4592 - 4594; DOI:
10.1021/ic00348a002
PDF
Is there an effective atomic number rule for adsorption on surfaces?
Jeremy K. Burdett and Thomas F. Faessler
pp 4594 - 4595; DOI:
10.1021/ic00348a003
PDF
d,l- and meso-Bis(.alpha.-mercaptobenzyl)dimethylsilane: new hindered bidentate ligands and a novel binuclear molybdenum complex formed therefrom
Jon Zubieta, Eric Block, Gabriel Ofori-Okai, and Kaluo Tang
pp 4595 - 4597; DOI:
10.1021/ic00348a004
PDF
Kinetics for pH-dependent complexation of aquated cis-diammineplatinum(II) with inosine and 1-methylinosine
Jorma Arpalahti
pp 4598 - 4602; DOI:
10.1021/ic00348a005
PDF
Nickel(III)-sulfur binding. Chemistry of the tris(xanthate) family
Suranjan Bhanja Choudhury, Debashis Ray, and Animesh Chakravorty
pp 4603 - 4611; DOI:
10.1021/ic00348a006
PDF
Hydroxide-induced synthesis of the superoxide ion from dioxygen and aniline, hydroxylamine, or hydrazine
Seungwon Jeon and Donald T. Sawyer
pp 4612 - 4615; DOI:
10.1021/ic00348a007
PDF
Phosphine analogs of cisplatin. Synthesis and x-ray structure of bis(.mu.-hydroxo)bis(bis(trimethylphosphine) platinum(II) dinitrate and its reactivity with 1-methylcytosine. X-ray structure of bis(.mu.-1-methylcytosinato-N3,N4)bis(bis(trimethylphosphine)platinum(II) dinitrate
Guendalina Trovo, Giuliano Bandoli, Umberto Casellato, Benedetto Corain, Marino Nicolini, and Bruno Longato
pp 4616 - 4621; DOI:
10.1021/ic00348a008
PDF
Acid properties of zinc(II) and cadmium(II) in complexation with macrocyclic oxo polyamine ligands
Eiichi Kimura, Tohru Koike, Takeshi Shiota, and Yoichi Iitaka
pp 4621 - 4629; DOI:
10.1021/ic00348a009
PDF
Structures and properties of dibridged (.mu.-oxo)diiron(III) complexes. Effects of the Fe-O-Fe angle
Richard E. Norman, Richard C. Holz, Stephane Menage, Lawrence Que, Jian H. Zhang, and Charles J. O'Connor
pp 4629 - 4637; DOI:
10.1021/ic00348a010
PDF
Solid-state and solution structure of (2,2'-bipyridine)(tetracarbonylcobalt)copper
Donald J. Darensbourg, Chi Shan Chao, Christopher Bischoff, and Joseph H. Reibenspies
pp 4637 - 4640; DOI:
10.1021/ic00348a011
PDF
Preparation of six lead(II) dialkoxides, x-ray crystal structures of [Pb(.mu.,.eta.1-OCH2CH2OMe)2].infin. and [Pb3(.mu.-O-tert-Bu)6], and hydrolysis studies
Subhash C. Goel, Michael Y. Chiang, and William E. Buhro
pp 4640 - 4646; DOI:
10.1021/ic00348a012
PDF
Preparation of soluble and volatile zinc dialkoxides. X-ray crystal structures of an (amido)zinc alkoxide and a homoleptic zinc enolate: {Zn(.mu.-OCEt3)[N(SiMe3)2]}2 and Zn(1,4,7-.eta.3-OCH:CHNMeCH2CH2NMe2)2
Subhash C. Goel, Michael Y. Chiang, and William E. Buhro
pp 4646 - 4652; DOI:
10.1021/ic00348a013
PDF
Synthesis, structure and physical properties of (.mu.-oxo)(.mu.-carboxylato)bis{(tris(2-pyridylmethyl)amine)chromium(III)} complexes
B. G. Gafford, R. E. Marsh, W. P. Schaefer, J. H. Zhang, C. J. O'Connor, and R. A. Holwerda
pp 4652 - 4657; DOI:
10.1021/ic00348a014
PDF
Synthesis and characterization of the new ruthenium tellurido clusters Ru4(CO)11(.mu.4-Te)2, Ru3(CO)6(PPh3)3(.mu.3-Te)2, Ru4(CO)10(PPh3)(.mu.4-Te)2 and Ru4(CO)9(.mu.-Ph2PCH2PPh2)(.mu.4-Te)2
Pradeep Mathur, B. H. S. Thimmappa, and Arnold L. Rheingold
pp 4658 - 4665; DOI:
10.1021/ic00348a015
PDF
Comparison of the [M(IV)(RR'dtc)3]+M(III)(RR'dtc)3 and [M(IV)(Et2dsc)3]+/M(III)(Et2dsc)3 (M = cobalt, rhodium, iridium; dtc = dithiocarbamate; dsc = diselenocarbamate) redox couples and the reactivity of the oxidation state (IV) complexes in solution and in the gas phase as studied by electrochemical and mass spectrometric techniques
Alan M. Bond, Ray Colton, and Desma R. Mann
pp 4665 - 4671; DOI:
10.1021/ic00348a016
PDF
Independence of the ethylene ligands in bis(.eta.2-ethene)rhodium(I) complexes
Eugene B. Wickenheiser and William R. Cullen
pp 4671 - 4676; DOI:
10.1021/ic00348a017
PDF
Role of ion pairs in anation reactions of (NH3)5CoXn+: capture of the thiocyanate ion in mixed-anion competition studies
W. G. Jackson, B. C. McGregor, and S. S. Jurisson
pp 4677 - 4683; DOI:
10.1021/ic00348a018
PDF
Ligand-scrambling reactions of cyano(trialkyl/triarylphosphine)gold(I) complexes: examination of factors influencing the equilibrium constant
Anne L. Hormann-Arendt and C. Frank Shaw
pp 4683 - 4687; DOI:
10.1021/ic00348a019
PDF
Effects of ring substituents, preferential solvation, and added amine on the trimer-dimer equilibrium in cyclic dialkylaluminium amide compounds
Frederick C. Sauls, Corinna L. Czekaj, and Leonard V. Interrante
pp 4688 - 4692; DOI:
10.1021/ic00348a020
PDF
Boron-nitrogen compounds. 126. N-triazolylboranes
J. Bai and K. Niedenzu
pp 4693 - 4696; DOI:
10.1021/ic00348a021
PDF
Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO)
Wolfgang Kaim and Volker Kasack
pp 4696 - 4699; DOI:
10.1021/ic00348a022
PDF
Electrogenerated chemiluminescence. 52. Binuclear iridium(I) complexes
Gary S. Rodman and Allen J. Bard
pp 4699 - 4702; DOI:
10.1021/ic00348a023
PDF
Reaction of formaldehyde with mer-(ethylenediamine)(glycylglycinato)nitrocobalt(III). Crystal structure of mer-(ethylenediamine)[N-((5,6-dihydro-5,5-bis(hydroxymethyl)-1,3-oxazin-4-yl)carbonyl)glycinato]nitrocobalt(III) trihydrate
Ljiljana Solujic, Bogdan Prelesnik, Rajna Herak, Slobodan Milosavljevic, John H. Nelson, and Aleksandar Nikolic
pp 4703 - 4707; DOI:
10.1021/ic00348a024
PDF
Environmental inorganic chemistry. 1. Electrochemistry of a water-soluble iron porphyrin and its exploitation for selective removal and concentration of environmentally hazardous materials via electrochemically modulated complexation
Carl A. Koval, Steven M. Drew, Richard D. Noble, and Jianhan Yu
pp 4708 - 4714; DOI:
10.1021/ic00348a025
PDF
Direct electrochemistry of the blue copper proteins pseudoazurin, plantacyanin, and stellacyanin
Takeshi Sakurai, Osamu Ikeda, and Shinnichiro Suzuki
pp 4715 - 4718; DOI:
10.1021/ic00348a026
PDF
Iron porphyrin models of peroxidase enzymes: catalytic activity, regeneration, and oxidative degradation of mesoferriheme
Fanny S. Woo, Mariella Cahiwat-Alquiza, and Henry C. Kelly
pp 4718 - 4723; DOI:
10.1021/ic00348a027
PDF
New hexaaza macrocyclic binucleating ligands. Oxygen insertion with a dicopper(I) Schiff base macrocyclic complex
Rached Menif, Arthur E. Martell, Philip J. Squattrito, and Abraham Clearfield
pp 4723 - 4729; DOI:
10.1021/ic00348a028
PDF
Products and kinetics of the oxidation of neutral dimeric iodo(N,N,N'N'-tetraalkyl diamine)copper(I) complexes [LCuI]2 by dioxygen in nitrobenzene
Mohamed A. El-Sayed, Geoffrey Davies, and Taher S. Kasem
pp 4730 - 4735; DOI:
10.1021/ic00348a029
PDF
Electron spin resonance studies of "FeO6" tris chelate complexes: models for the effects of zero-field splitting in distorted S = 5/2 spin systems
David Collison and Anne K. Powell
pp 4735 - 4746; DOI:
10.1021/ic00348a030
PDF
Photochemistry of copper(II) macrocyclic complexes bound to poly(acrylic acid): time-resolved observations in a picosecond-millisecond time domain and sequential biphotonic excitations
E. Baumgartner, S. Ronco, and G. Ferraudi
pp 4747 - 4750; DOI:
10.1021/ic00348a031
PDF
Luminescent and redox-reactive building blocks for the design of photochemical molecular devices: mono-, di-, tri-, and tetranuclear ruthenium(II) polypyridine complexes
Gianfranco Denti, Sebastiano Campagna, Luigina Sabatino, Scolastica Serroni, Mauro Ciano, and Vincenzo Balzani
pp 4750 - 4758; DOI:
10.1021/ic00348a032
PDF
Heteronuclear unbridged molybdenum-tungsten quadruply bonded complexes. Preparation and characterization of Cl2(PMe2Ph)2Mo-WCl2(PMe2Ph)(PPh3), Cl2(PMe2Ph)(PPh3)Mo-WCl2(PMe2Ph)2 and Mo-WCl4(PMe2Ph)4
F. Albert Cotton, Larry R. Falvello, Chris A. James, and Rudy L. Luck
pp 4759 - 4763; DOI:
10.1021/ic00348a033
PDF
Two- and four-coordinate gold(I) complexes of tris(2-(diphenylphosphino)ethyl)phosphine
Alan L. Balch and Ella Y. Fung
pp 4764 - 4768; DOI:
10.1021/ic00348a034
PDF
Tristrontium dialuminum hexaoxide: an intricate superstructure of perovskite
J. A. Alonso, I. Rasines, and J. L. Soubeyroux
pp 4768 - 4771; DOI:
10.1021/ic00348a035
PDF
Transition-metal complexes with sulfur ligands. 55. Nickel complexes with thiolato-thioether ligands including nitrogen and oxygen donors in S6, S5, OS4, NS4, and S4 donor sets. Syntheses, properties, and x-ray structure determinations of [Ni('S6')], [Ni('S5')], [Ni('OS4')]2, [Ni('S4-C5')]2, and [Ni('S4-C3')]
Dieter Sellmann, Stefan Funfgelder, Georg Pohlmann, Falk Knoch, and Matthias Moll
pp 4772 - 4778; DOI:
10.1021/ic00348a036
PDF
Structural investigations of nickel complexes with nitrogen and sulfur donor ligands
Gerard J. Colpas, Manoj Kumar, Roberta O. Day, and Michael J. Maroney
pp 4779 - 4788; DOI:
10.1021/ic00348a037
PDF
Reactions of mono(dinitrogen) complexes of molybdenum. Isolation and characterization of hydrazido(2-) and mono- and dihydride complexes. Crystal structure of MoBr[PhP(CH2CH2PPh2)2](Me2PCH2PMe2).cntdot.1/2C5H12
T. Adrian George, Lidun Ma, S. N. Shailh, Robert C. Tisdale, and Jon Zubieta
pp 4789 - 4796; DOI:
10.1021/ic00348a038
PDF
Preparation and reactions of diruthenium thiolate complexes [Cp*Ru(.mu.-SR)3RuCp*] (Cp* = .eta.5-pentamethylcyclopentadienyl; R = iso-Pr, Et, cyclohexyl, benzyl, Ph)
Somanath Dev, Yasushi Mizobe, and Masanobu Hidai
pp 4797 - 4801; DOI:
10.1021/ic00348a039
PDF
Synthesis, structure and characterization of chlorobis(diethyldithiocarbamato)((2-mercaptophenyl)imido)molybdenum(VI)
Martin Minelli, Mark R. Carson, Donald W. Whisenhunt, Wolfgang Imhof, and Gottfried Huttner
pp 4801 - 4805; DOI:
10.1021/ic00348a040
PDF
Steric control of tricoordination in univalent coinage metal complexes: the crystal structure of tris(cyclopentyldiphenylphosphine)silver(I) tetrafluoroborate
A. Baiada, F. H. Jardine, and R. D. Willett
pp 4805 - 4808; DOI:
10.1021/ic00348a041
PDF
Organic substituent effects in macrobicyclic (hexaamine)cobalt(III/II) complexes: a new method of obtaining polar substituent constants
Geoffrey A. Lawrance, Peter A. Lay, and Alan M. Sargeson
pp 4808 - 4816; DOI:
10.1021/ic00348a042
PDF
Mechanism of intramolecular rearrangements of (acetylacetonato)bis(4,4,4-trifluoro-1-phenyl-1,3-butanedionato)ruthenium(III)
Yoshimasa Hoshino, Ryouta Takahashi, Kunio Shimizu, Gen P. Sato, and Koichi Aoki
pp 4816 - 4820; DOI:
10.1021/ic00348a043
PDF
X-ray crystal structures of the 1,3,2-benzodithiazolyl dimer and 1,3,2-benzodithiazolium chloride sulfur dioxide solvate: comparison of the molecular and electronic structures of the 10-.pi.-electron C6H4S2N+ cation and the C6H4S2N.bul. radical and dimer and a study of the variable-temperature magnetic behavior of the radical
Edward G. Awere, Neil Burford, Robert C. Haddon, Simon Parsons, Jack Passmore, J. V. Waszczak, and Peter S. White
pp 4821 - 4830; DOI:
10.1021/ic00348a044
PDF
Molecular sieve VPI-5: a precursor to the aluminophosphate (AlPO4-8)
S. Prasad and I. Balakrishnan
pp 4830 - 4831; DOI:
10.1021/ic00348a045
PDF
Molecular structure of aquatricarbonyldichlororuthenium.cntdot.diglyme: hydrogen bonding of diglyme to coordinated water
Joseph J. Bergmeister, Brian E. Hanson, and Joseph S. Merola
pp 4831 - 4833; DOI:
10.1021/ic00348a046
PDF
Intermediates in the early events of heteropolymolybdate-catalyzed photodehydrogenations: the picosecond-nanosecond reactions of M(OH)6Mo6O18n-, where M = AlIII (n = 3), RhIII (n = 3), FeIII (n = 3), CrIII (n = 3), and NiII (n = 4)
B. Kraut and G. Ferraudi
pp 4834 - 4837; DOI:
10.1021/ic00348a047
PDF
Reaction of bis(trimethylphosphine)-tetraborane(8) with trimethylphosphine
Mitsuaki Kameda and Goji Kodama
pp 4837 - 4838; DOI:
10.1021/ic00348a048
PDF
Synthesis and characterization of nonacarbonyldi-.mu.3-telluridodiironruthenium and undecacarbonyldi-.mu.4-telluridodiirondiruthenium
Pradeep Mathur, Ipe J. Mavunkal, V. Rugmini, and Mary F. Mahon
pp 4838 - 4840; DOI:
10.1021/ic00348a049
PDF
Synthesis and characterization of cobalt(III) complexes containing .alpha.-diamine and carbinolamine derived from .alpha.-aminomalonate and ethylenediamine [Erratum to document cited in CA112(10):90371e]
Takahiko Kojima, Takeshi Usui, Tomoaki Tanase, Morio Yashiro, Sadao Yoshikawa, Reiko Kuroda, Shigenobu Yano, and Masanobu Hidai
pp 4840 - 4840; DOI:
10.1021/ic00348a050
PDF
Proton nuclear magnetic resonance studies of iron(II/III)-amide complexes. Spectroscopic models for nonheme iron proteins [Erratum to document cited in CA113(12):107833c]
Li June Ming, Randall B. Lauffer, and Lawrence Que
pp 4840 - 4840; DOI:
10.1021/ic00348a051
PDF
Synthesis and characterization of cationic technetium complexes of 1,2-bis(dimethylphosphino)ethane (DMPE). Structure determinations of trans-[TcV(DMPE)2(OH)(O)](F3CSO3)2, trans-[TcIII(DMPE)2Cl2]F3CSO3, and [TcI(DMPE)3]+ using x-ray diffraction, EXAFS, and technetium-99 NMR [Erratum to document cited in CA101(16):142794q]
Jean Luc Vanderheyden, Alan R. Ketring, Karen Libson, Mary Jane Heeg, Lee Roecker, Philip Motz, Robert Whittle, R. C. Elder, and Edward Deutsch
pp 4840 - 4840; DOI:
10.1021/ic00348a052
PDF

Issue 24


Heteronuclear NMR studies of cobalamins. 11. Nitrogen-15 NMR studies of the axial nucleotide and amide side chains of cyanocobalamin and dicyanocobamides
Kenneth L. Brown, Harold B. Brooks, Xiang Zou, Mark Victor, Anjan Ray, and Russell Timkovich
pp 4841 - 4844; DOI:
10.1021/ic00349a001
PDF
First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2
Sang Man Koo, R. Bergero, A. Salifoglou, and D. Coucouvanis
pp 4844 - 4846; DOI:
10.1021/ic00349a002
PDF
Reversible dismutation and coordination of bis(2,4,6-triisopropylphenyl) diselenide with iodine. A model study that relates to iodine intercalation between selenium chains
Wolf W. Du Mont, Andreas Martens, Siegfried Pohl, and Wolfgang Saak
pp 4847 - 4848; DOI:
10.1021/ic00349a003
PDF
Wavelength dependence of unquenchable photoaquation in the tris(1,3-diaminopropane)chromium(III) ion
Alexander David Kirk and A. Mohamed Ibrahim
pp 4848 - 4850; DOI:
10.1021/ic00349a004
PDF
An unusual trirhodium complex: dichlorodicarbonylrhodate(I) as a binucleating ligand
Ravi Kumar, Richard J. Puddephatt, and Frank R. Fronczek
pp 4850 - 4851; DOI:
10.1021/ic00349a005
PDF
Raman spectroscopy: a convenient probe of solid-liquid crystal-phase transitions in binuclear rhodium(II) n-alkanoates
Olivier Poizat, Dennis P. Strommen, Pascale Maldivi, Anne Marie Giroud-Godquin, and Jean Claude Marchon
pp 4851 - 4853; DOI:
10.1021/ic00349a006
PDF
Evidence for photoinduced heterolytic bond cleavage in iodotrimethylstannane
Edgar A. Mendoza and Harry D. Gafney
pp 4853 - 4854; DOI:
10.1021/ic00349a007
PDF
Energetics of intramolecular electron transfer in ruthenium-modified stellacyanin
Ole Farver and Israel Pecht
pp 4855 - 4858; DOI:
10.1021/ic00349a008
PDF
Direct cyclic voltammetry of three ruthenium-modified electron-transfer proteins
Fraser A. Armstrong, J. N. Butt, K. Govindaraju, J. McGinnis, R. Powls, and A. G. Sykes
pp 4858 - 4862; DOI:
10.1021/ic00349a009
PDF
Oxygen atom transfer reactions of cationic rhenium(III), rhenium(V), and rhenium(VII) triazacyclononane complexes
Rebecca R. Conry and James M. Mayer
pp 4862 - 4867; DOI:
10.1021/ic00349a010
PDF
Hydrogen-1 NOE and ligand field studies of copper-cobalt superoxide dismutase with anions
Lucia Banci, Alessandro Bencini, Ivano Bertini, Claudio Luchinat, and Mario Piccioli
pp 4867 - 4873; DOI:
10.1021/ic00349a011
PDF
Syntheses, structures, and properties of vanadium, cobalt, and nickel compounds with 2-mercaptophenol
Beisheng Kang, Linghong Weng, Hanqin Liu, Daxu Wu, Liangren Huang, Cenzhong Lu, Jinghua Cai, Xuetai Chen, and Jiaxi Lu
pp 4873 - 4877; DOI:
10.1021/ic00349a012
PDF
A novel iron-sulfur-thiolate basket cluster: synthesis, structure, and properties of Fe6S5(.mu.-SPh)(P-n-Bu3)4(SPh)2
Changneng Chen, Jinhua Cai, Qiutian Liu, Daxu Wu, Xinjian Lei, Kun Zhao, Beisheng Kang, and Jiaxi Lu
pp 4878 - 4881; DOI:
10.1021/ic00349a013
PDF
A unique bromo- and thioether-bridged tetranuclear mixed-valence copper(I)-copper(II) compound with the N,S-donor ligand 4-((ethylthio)methyl)-5-methylimidazole
E. Bouwman, Willem L. Driessen, J. Reedijk, C. Smykalla, J. M. M. Smits, P. T. Beurskens, F. Laschi, and P. Zanello
pp 4881 - 4886; DOI:
10.1021/ic00349a014
PDF
Infrared, magnetic, Moessbauer, and structural characterization of perrhenato(tetraphenylporphyrinato)iron.cntdot.toluene
LaNelle Ohlhausen, David Cockrum, Jay Register, Kent Roberts, Gary J. Long, Gregory L. Powell, and Bennett B. Hutchinson
pp 4886 - 4891; DOI:
10.1021/ic00349a015
PDF
Synthesis and properties of mixed-valence copper molecules (.mu.-Y)N4CuII2CUI2X4 (N = N,N-diethylnicotinamide; Y = 3,4,5,6-tetrachlorocatecholate; X = Cl, Br, I) and the products and kinetics of their reactions with dioxygen and nitrobenzene
Mohamed A. El-Sayed and Geoffrey Davies
pp 4891 - 4897; DOI:
10.1021/ic00349a016
PDF
Synthesis, characterization, and solution chemistry of a family of protein-binding inorganic complexes: bis(imidazole)(amino acid-N,N-diacetato)chromium(III)
Jeffrey R. Bocarsly, Michael Y. Chiang, Leshauna Bryant, and Jacqueline K. Barton
pp 4898 - 4907; DOI:
10.1021/ic00349a017
PDF
Tetracarbonylchloroethylidynechromium: electron deformation density revisited. Joint multipole model refinement and ab initio CASSCF study
Anne Spasojevic De Bire, Claudine Thieffry, Marc Benard, Nguyen Quy Dao, and Alain Strich
pp 4908 - 4915; DOI:
10.1021/ic00349a018
PDF
Split model description of the copper site distribution in the new layered (2D) copper vanadium phosphorus sulfide (CuIVIIIP2S6) phase
E. Durand, G. Ouvrard, M. Evain, and R. Brec
pp 4916 - 4920; DOI:
10.1021/ic00349a019
PDF
Five- and four-coordinate copper(II) complexes of 2,2'-bipyridine and phenylcyanamide anion ligands: crystal structures, cyclic voltammetry, and electronic absorption spectroscopy
Robert J. Crutchley, Rosemary Hynes, and Eric J. Gabe
pp 4921 - 4928; DOI:
10.1021/ic00349a020
PDF
A homoleptic uranium thiolate: synthesis, structure, and fluxional behavior of [Li(dme)]4[U(SCH2CH2S)4] and reaction with carbon disulfide
Kazuyuki Tatsumi, Ichiro Matsubara, Yoshihisa Inoue, Akira Nakamura, Roger E. Cramer, Ginger J. Tagoshi, James A. Golen, and John W. Gilje
pp 4928 - 4938; DOI:
10.1021/ic00349a021
PDF
Experimental evidence for comparable strength of phosphorus-sulfur and phosphorus-nitrogen p.pi.-bonding within the heteronaphthalenic framework: spectroscopic and structural studies of the 1,3,2-benzazathiaphospholium system as a cation and as neutral halides
Neil Burford, Anne I. Dipchand, Bruce W. Royan, and Peter S. White
pp 4938 - 4944; DOI:
10.1021/ic00349a022
PDF
Detailed hysteresis studies and nature of the spin-state transition in bis(1,10-phenanthroline-2-carbaldehyde phenylhydrazone)iron(II) complexes
E. Koenig, B. Kanellakopulos, B. Powietzka, and H. A. Goodwin
pp 4944 - 4949; DOI:
10.1021/ic00349a023
PDF
Site dilution of osmium polypyridine complexes in three electron-hopping conductive polymer films on electrodes by electrochemical copolymerization of osmium with ruthenium and with zinc complexes
Nigel A. Surridge, F. Richard Keene, Brent A. White, John S. Facci, Marvin Silver, and Royce W. Murray
pp 4950 - 4955; DOI:
10.1021/ic00349a024
PDF
Assignment of the valence molecular orbitals of (cyclopentadienyl)trimethylplatinum and (cyclooctadiene)dimethylplatinum using variable-energy photoelectron spectra
D. S. Yang, G. M. Bancroft, R. J. Puddephatt, K. H. Tan, J. N. Cutler, and J. D. Bozek
pp 4956 - 4960; DOI:
10.1021/ic00349a025
PDF
Solvent-dependent deuteron NMR spectra and solvatochromism in ligand field absorption bands for trans-[CrX2(3,2,3-tet)]+: correlation with the angular overlap model parametrization
Sumio Kaizaki and Hiroko Takemoto
pp 4960 - 4964; DOI:
10.1021/ic00349a026
PDF
Onium ions. 39. Nitrogen-15 NMR spectroscopic investigation of nitrous and nitric acids in sulfuric acid solutions of varying acidities
G. K. Surya Prakash, Ludger Heiliger, and George A. Olah
pp 4965 - 4968; DOI:
10.1021/ic00349a027
PDF
Synthesis, characterization, and reactions of polymer-bound dinitrogen complexes of molybdenum
T. Adrian George and Bharat B. Kaul
pp 4969 - 4974; DOI:
10.1021/ic00349a028
PDF
NMR studies of inversion and dithiophosphate methyl group exchange in dialkoxybis(O,O'-dimethyl dithiophosphato)titanium(IV) complexes. Evidence for a bond-rupture mechanism
Han Mou Gau and Robert C. Fay
pp 4974 - 4983; DOI:
10.1021/ic00349a029
PDF
Contrasting behaviors of phosphorus and arsenic in a polycyclic framework favoring pnicogen square pyramidality
R. V. Davis and J. G. Verkade
pp 4983 - 4990; DOI:
10.1021/ic00349a030
PDF
A novel cyclam appended with 3-hydroxypridine. An Ambident donor ligand comprising a pyridyl N and a pyridinolate O- donor
Eiichi Kimura, Yoshihiko Kotake, Tohru Koike, Mitsuhiko Shionoya, and Motoo Shiro
pp 4991 - 4996; DOI:
10.1021/ic00349a031
PDF
Kinetics and mechanism of the reactions between alkyl radicals and complexes of cobalt(III) and ruthenium(III)
Douglas G. Kelley, James H. Espenson, and Andreja Bakac
pp 4996 - 5000; DOI:
10.1021/ic00349a032
PDF
Modification of the reactivity of polyhydrides with Lewis acids. Synthesis and reactivity of {IrH5[P(iso-C3H7)3]2}2Cu(CF3SO3). X-ray crystal structure of {IrH2(MeCN)2[P(iso-C3H7)3]2}(BF4)
X. D. He, J. Fernandez-Baeza, B. Chaudret, K. Folting, and K. G. Caulton
pp 5000 - 5002; DOI:
10.1021/ic00349a033
PDF
The synthesis and crystal structure of a mixed-valence, digold(I)/gold(III), pyrazolato complex stable in aqua regia. The x-ray photoelectron study of homo- and heterovalent gold-pyrazolato trimers
Raphael G. Raptis and John P. Fackler
pp 5003 - 5006; DOI:
10.1021/ic00349a034
PDF
Practical syntheses of chelating bis(dioxaphospholane) ligands through chlorodioxaphospholane intermediates and demonstration of catalytic competence of bis(phosphite)rhodium cation
Donald J. Wink, Thomas J. Kwok, and Allen Yee
pp 5006 - 5008; DOI:
10.1021/ic00349a035
PDF
(1,4-Diazabutadiene)nickel(O) complex (2,6-Ipr2C6H3N:CHCH:NC6H3-2,6-iPr2)Ni(CO)2
Klaus R. Poerschke, Werner Bonrath, and Richard Mynott
pp 5008 - 5009; DOI:
10.1021/ic00349a036
PDF
Synthesis of functionalized asymmetrical bis(terpyridine)osmium(II) complexes under mild conditions
Jean Paul Collin, Stephane Guillerez, and Jean Pierre Sauvage
pp 5009 - 5010; DOI:
10.1021/ic00349a037
PDF
The ferrocene assumption in redox thermodynamics: implications from optical intervalence studies of ion pairing to ferrocenium
Joseph T. Hupp
pp 5010 - 5012; DOI:
10.1021/ic00349a038
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Issue 25


Ruthenium(II) phenolates. Synthesis and characterization of a novel four-membered metallacycle
Nilkamal Bag, Suranjan Bhanja Choudhury, Amitava Pramanik, Goutam Kumar Lahiri, and Animesh Chakravorty
pp 5013 - 5014; DOI:
10.1021/ic00350a001
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A bridged cobaltaborane complex: the first structural characterization of a transition metal-BH2 bond
David J. Elliot, Christopher J. Levy, Richard J. Puddephatt, David G. Holah, Alan N. Hughes, Vincent R. Magnuson, and Irene M. Moser
pp 5014 - 5015; DOI:
10.1021/ic00350a002
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Chlorination catalyzed by vanadium bromoperoxidase
Helena S. Soedjak and Alison Butler
pp 5015 - 5017; DOI:
10.1021/ic00350a003
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"Pressure-testing" Marcus-Hush theories of outer-sphere electron-transfer kinetics
Thomas W. Swaddle
pp 5017 - 5025; DOI:
10.1021/ic00350a004
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Synthesis of polyhydroxy carboxylates. 5. Metal ion catalyzed O-alkylation of ethylene glycol with maleate. A multinuclear NMR study of the lanthanide(III) complexes present in the reaction mixture of the lanthanide(III)-catalyzed reaction
Zhi Chen, Jeroen Van Westrenen, Herman Van Bekkum, and Joop A. Peters
pp 5025 - 5031; DOI:
10.1021/ic00350a005
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Oxidation of copper(II) bis(glycinate) by methyl free radicals in aqueous solutions. A pulse-radiolysis study
Mohamad Masarwa, Haim Cohen, Robert Glaser, and Dan Meyerstein
pp 5031 - 5035; DOI:
10.1021/ic00350a006
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Pentacyanoamminechromate(III). Synthesis, characterization, and photochemistry
Pietro Riccieri and Edoardo Zinato
pp 5035 - 5041; DOI:
10.1021/ic00350a007
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Photoinduced electron transfer by coordination chemical pathways across pyrite/electrolyte interfaces
B. Schubert and H. Tributsch
pp 5041 - 5046; DOI:
10.1021/ic00350a008
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Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn
Renate Gross-Lannert, Wolfgang Kaim, and Barbara Olbrich-Deussner
pp 5046 - 5053; DOI:
10.1021/ic00350a009
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A tetranuclear hydroxo-bridged copper(II) cluster of the cubane type. Preparation and structural and magnetic characterization of tetrakis[(2,2'-bipyridyl)hydroxocopper(II)] hexafluorophosphate
Jorunn Sletten, Astrid Soerensen, Miguel Julve, and Yves Journaux
pp 5054 - 5058; DOI:
10.1021/ic00350a010
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Synthesis and structural characterization of binuclear ruthenium aquo, hydroxy, and oxo complexes incorporating the anionic tripod ligand [(.eta.5-C5H5)Co{(CH3CH2O)2P:O}3]-
John M. Power, Kaspar Evertz, Larry Henling, Richard Marsh, William P. Schaefer, Jay A. Labinger, and John E. Bercaw
pp 5058 - 5065; DOI:
10.1021/ic00350a011
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Conformational studies on nickel, palladium, and platinum homobimetallic complexes based on a binucleating hexaphosphine ligand system
Suzanne E. Saum, Scott A. Laneman, and George G. Stanley
pp 5065 - 5074; DOI:
10.1021/ic00350a012
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Reactions of sulfur containing heterocumulenes with low-valent molybdenum and tungsten complexes. Oxidative cleavage of a head-to-tail carbon disulfide dimer in a molybdenum complex
Ernesto Carmona, Agustin Galindo, Angeles Monge, Miguel Angel Munoz, Manuel L. Poveda, and Caridad Ruiz
pp 5074 - 5080; DOI:
10.1021/ic00350a013
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Hexacoordinate phosphorus. 5. Synthesis and characterization of neutral phosphorus(V) compounds containing substituted bidentate amidino ligands derived from carbodiimides
Dietmar K. Kennepohl, Bernard D. Santarsiero, and Ronald G. Cavell
pp 5081 - 5087; DOI:
10.1021/ic00350a014
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Hexacoordinate phosphorus. 6. Synthesis and characterization of neutral six-coordinate phosphorus(V) compounds derived from 2-pyridinol and related heteroatomic pyridine ligands
Dietmar K. Kennepohl, A. Alan Pinkerton, Yoke Foo Lee, and Ronald G. Cavell
pp 5088 - 5096; DOI:
10.1021/ic00350a015
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Matrix-infrared spectra of structural isomers of the phosphorus oxysulfide P4S3O
Zofia Mielke, Lester Andrews, Kiet A. Nguyen, and Mark S. Gordon
pp 5096 - 5100; DOI:
10.1021/ic00350a016
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Absorption and magnetic circular dichroism spectroscopy of metal- and ring-oxidized porphyrins. Spectral characteristics of the one- and two-electron oxidation products of cobalt octaethylporphyrin
Zbigniew Gasyna and Martin J. Stillman
pp 5101 - 5109; DOI:
10.1021/ic00350a017
PDF
Proton magnetic relaxation dispersion in aqueous glycerol solutions of Gd(DTPA)2- and Gd(DOTA)-
Griselda Hernandez, Robert G. Bryant, and Michael F. Tweedle
pp 5109 - 5113; DOI:
10.1021/ic00350a018
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EPR and electrochemical study of nickel(III) complexes of bis(3,5-dichlorosalicylaldehyde) o-phenylenediimine. Evidence for adduct formation with pyridines
Baltazar De Castro and Cristina Freire
pp 5113 - 5119; DOI:
10.1021/ic00350a019
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Solution studies on the cuboidal mixed-metal complex molybdenum iron sulfido aqua ([Mo3FeS4(H2O)10]4+)
Paul W. Dimmock, Dominic P. E. Dickson, and A. Geoffrey Sykes
pp 5120 - 5125; DOI:
10.1021/ic00350a020
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Multinuclear (platinum-195, nitrogen-15, carbon-13) NMR studies of the reactions between cis-diaminediaquaplatinum(II) complexes and aminomalonate
Dan Gibson, Ayelet Rosenfeld, Haim Apfelbaum, and Jochanan Blum
pp 5125 - 5129; DOI:
10.1021/ic00350a021
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Mesomorphic properties of metallonematogens, bis[4-((4-alkoxybenzoyl)oxy)-N-(n-alkyl)salicyaldiminato]copper(II) complexes
Naomi Hoshino, Ryoichi Hayakawa, Tomoko Shibuya, and Yoshio Matsunaga
pp 5129 - 5131; DOI:
10.1021/ic00350a022
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Nitronium (trifluoroacetato)metalates. 1. Nitronium hexakis(trifluoroacetato)stannate(IV)
Mutasim I. Khalil
pp 5131 - 5133; DOI:
10.1021/ic00350a023
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Synthesis and characterization of heptarhenium carbido clusters with (.eta.2-olefin)iridium capping moieties
Linqing Ma, John R. Shapley, and Scott R. Wilson
pp 5133 - 5136; DOI:
10.1021/ic00350a024
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Issue 26


Unusual platinum hydrides with nitrogen ligands
Giovanni Minghetti, Maria Agostina Cinellu, Sergio Stoccoro, Giorgio Chelucci, and Antonio Zucca
pp 5137 - 5138; DOI:
10.1021/ic00351a001
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A triosmium cluster-siloxane cage complex. Synthesis and structure of HOs3(CO)10[(.mu.-O)Si7O10(C6H11)7]
Jia Chu Liu, Scott R. Wilson, and John R. Shapely
pp 5138 - 5139; DOI:
10.1021/ic00351a002
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Preparation and structural characterization of the bis[bis(trimethylsilyl)amido]chalcogenides of selenium and tellurium
Mar Bjoergvinsson, Herbert W. Roesky, Frank Pauer, Dietmar Stalke, and George M. Sheldrick
pp 5140 - 5143; DOI:
10.1021/ic00351a003
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Preparation and structural characterization of two isomers of the rhenium phosphine complexes of stoichiometry Re2Cl5(PR3)3, where R = Me or Et
F. Albert Cotton, Andrew C. Price, and K. Vidyasagar
pp 5143 - 5147; DOI:
10.1021/ic00351a004
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New synthetic routes for the preparation of niobium(III) and tantalum(III) triangular cluster compounds
Elizabeth Babaian-Kibala, F. Albert Cotton, and Maoyu Shang
pp 5148 - 5156; DOI:
10.1021/ic00351a005
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Triple-decker sandwich complexes of cobalt, rhodium, and ruthenium bridged by C2B3 or C3B2 rings: synthesis, structure, and electrochemistry
Achim Fessenbecker, Martin D. Attwood, Robert F. Bryan, Russell N. Grimes, Moses K. Woode, Martin Stephan, Ulrich Zenneck, and Walter Siebert
pp 5157 - 5163; DOI:
10.1021/ic00351a006
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Tetradecker LM(C3B2)Co(C2B3)CoCp sandwich complexes [LM = Cp*Co, Cp*Rh, or (cymene)Ru]. Designed synthesis and electronic properties
Achim Fessenbecker, Martin D. Attwood, Russell N. Grimes, Martin Stephan, Hans Pritzkow, Ulrich Zenneck, and Walter Siebert
pp 5164 - 5168; DOI:
10.1021/ic00351a007
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Synthesis and characterization of nickel(II) complexes of purine and pyrimidine bases. Crystal and molecular structure of trans-bis(cytosine-O2)bis(ethylenediamine)nickel(II) bis(tetraphenylborate). An unusual metal binding mode of cytosine
Gemma Cervantes, Juan J. Fiol, Angel Terron, Virtudes Moreno, Juan R. Alabart, Magdalena Aguilo, Montserrat Gomez, and Xavier Solans
pp 5168 - 5173; DOI:
10.1021/ic00351a008
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(.mu.-Oxo/hydroxo)bis(.mu.-carboxylato)diiron(III) and -dimanganese(III) complexes with capping tris(imidazol-2-yl)phosphine ligands
Feng Jung Wu, Donald M. Kurtz, Karl S. Hagen, Philip D. Nyman, Peter G. Debrunner, and Vivian A. Vankai
pp 5174 - 5183; DOI:
10.1021/ic00351a009
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Spectroscopic characterization of a series of europium(III) amino phosphonate complexes in solution
Richard C. Holz, Gretchen E. Meister, and William D. Horrocks
pp 5183 - 5189; DOI:
10.1021/ic00351a010
PDF
Action of sodium gold(I) thiomalate on erythrocyte membrane
W. Ewen Smith, John Reglinski, Shona Hoey, Donald H. Brown, and Roger D. Sturrock
pp 5190 - 5196; DOI:
10.1021/ic00351a011
PDF
Metal complexes of the antiinflammatory drug piroxicam
Renzo Cini, Gianluca Giorgi, Arnaldo Cinquantini, Claudio Rossi, and Michal Sabat
pp 5197 - 5200; DOI:
10.1021/ic00351a012
PDF
Anion-exchange reactions of layered double hydroxides
Martina Meyn, Klaus Beneke, and Gerhard Lagaly
pp 5201 - 5207; DOI:
10.1021/ic00351a013
PDF
Spin coupling in ferric porphyrin and chlorin .pi.-cation-radical complexes
Satoru Nakashima, Hiroaki Ohya-Nishiguchi, Noboru Hirota, Hiroshi Fujii, and Isao Morishima
pp 5207 - 5211; DOI:
10.1021/ic00351a014
PDF
Unusually strong antiferromagnetic coupling in unsymmetrical diiron(III).mu.-oxo complexes
Pedro Gomez-Romero, E. H. Witten, William Michael Reiff, and Geoffrey B. Jameson
pp 5211 - 5217; DOI:
10.1021/ic00351a015
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Preparation of an acid niobium phosphate and alkali-metal niobium phosphates, having NbOPO4.cntdot.H2O layers condensed with the phosphate group
Nobukazu Kinomura and Nobuhiro Kumada
pp 5217 - 5222; DOI:
10.1021/ic00351a016
PDF
Infrared spectra of tetraphosphorous decasulfide and its decomposition products in solid argon
Lester Andrews, Gregg G. Reynolds, Zofia Mielke, and Matthew McCluskey
pp 5222 - 5225; DOI:
10.1021/ic00351a017
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Stability and stereochemistry of tetrahedral nickel nitrosyl complexes: crystal and molecular structures of (R*,S*)-anti-[NiNCS(NO){1,2-C6H4(PMePh)2}] and (R*,S*)-anti-[NiNO{P(OMe)3][1,2-C6H4(PMePh)2}]PF6
A. F. M. Mokhlesur Rahman, Geoffrey Salem, Frederick S. Stephens, and S. Bruce Wild
pp 5225 - 5230; DOI:
10.1021/ic00351a018
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Role of the trigonal t2e2-nen single-ion configuration in d3d3 metal-metal .sigma.-bonded dimers
Robert Stranger
pp 5231 - 5237; DOI:
10.1021/ic00351a019
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Absorption and emission spectra of a single-crystal (maleonitriledithiolato)palladate(II) complex
Wolfgang Guentner, Guenter Gliemann, Horst Kunkely, Christian Reber, and Jeffrey I. Zink
pp 5238 - 5241; DOI:
10.1021/ic00351a020
PDF
Preparation and structural characterization of carbonylchlorocopper
Mikael Haakansson and Susan Jagner
pp 5241 - 5244; DOI:
10.1021/ic00351a021
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Hydrido phosphido derivatives of bis(cyclopentadienyl)molybdenum and -tungsten and the structure of [(.eta.5-Cp)2Mo(H)(.mu.-PPh2)Mn(CO)2(.eta.5-Cp)]
Christophe Barre, Marek M. Kubicki, Jean Claude Leblanc, and Claude Moise
pp 5244 - 5246; DOI:
10.1021/ic00351a022
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